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Switchable and Memorable Adhesion of Gold-Coated Microspheres with Electrochemical Modulation

Switchable adhesives using stimuli-responsive systems have many applications, including transfer printing, climbing robots, and gripping in pick and place processes. Among these adhesives, electroadhesive surface can spontaneously adjust their adhesion in response to an external electric field. However, electroadhesives usually need high voltage (e.g. kV) and the adhesion disappears upon turning off the signal. These limitations make them complicated and costly. In this research, we demonstrated a gold-coated silica microsphere (GCSM) with highly switchable and memorable adhesion triggered by a relatively small voltage (<30 V). In the experiment, a silica microsphere with a diameter of 15 μm was glued to a tipless atomic force microscope (AFM) cantilever. The nanoscale thick gold coating was sprayed on the surface of the microsphere by a sputter coater. AFM was used to explore the tunable adhesion with an external voltage at different relative humidity (RH). The results revealed that when applying a positive electrical bias at high RH, the adhesive force increased dramatically while it decreased to almost zero after applying a negative potential. Even if the bias was turned off, the adhesive force state could still be kept and erased on demand by simply applying a negative voltage. The adhesive force can be altered repeatedly by an alternative electrical bias. This adhesion modulated by the external electrical signals is attributed to the electrochemical effect of the nanoscale-thick gold coating, where an oxide layer can be formed and thus becomes positively charged when applying a positive voltage, and counter electric field cancel out the applied negative voltage to decrease the adhesion force.

Identiferoai:union.ndltd.org:unt.edu/info:ark/67531/metadc1808444
Date05 1900
CreatorsWang, Jie (Materials scientist)
ContributorsXia, Zhenhai, 1963-, Mukherjee, Sundeep, Li, Xiao (Materials scientist)
PublisherUniversity of North Texas
Source SetsUniversity of North Texas
LanguageEnglish
Detected LanguageEnglish
TypeThesis or Dissertation
Formatvii, 48 pages : illustrations (some color), Text
RightsPublic, Wang, Jie, Copyright, Copyright is held by the author, unless otherwise noted. All rights Reserved.

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