A variable temperature 1H, 13C, and 6Li NMR study of n-propyl-6Li-lithium showed five different aggregates, similar to that in the literature as (RLi)n, n= 6, 8, 9, 9, 9. There were also a number of additional new species, identified as lithium hydride containing aggregates. Unexpectedly, a series of 13C{1H} 1-D NMR experiments with selective 6Li decoupling showed evidence for 13C-6Li spin-spin coupling between the previously reported (RLi)n aggregates and various hydride species.
| Identifer | oai:union.ndltd.org:unt.edu/info:ark/67531/metadc3350 |
| Date | 12 1900 |
| Creators | Davis, James W. |
| Contributors | Thomas, Ruthanne D., Richmond, Michael |
| Publisher | University of North Texas |
| Source Sets | University of North Texas |
| Language | English |
| Detected Language | English |
| Type | Thesis or Dissertation |
| Format | Text |
| Rights | Public, Copyright, Davis, James W., Copyright is held by the author, unless otherwise noted. All rights reserved. |
Page generated in 0.2324 seconds