As part of a continuing study of the synthesis and chemistry of new, substituted pentacyclo(5.4.0.0²，⁶.0³，¹º.0⁵，⁹)undecanes, the following compounds have been synthesized: 1: X=O, Y=SiMe_3; 2: X=CH_2, Y=SiMe_3; 3: X=O, Y=Cl; 6: X=OAc, Y=H; 8: X=OC(O)Ph, Y=H; 9: X=OSO_2Ph, Y=H; 11: X=OH, Y=H; 12: X=OMe, Y=H; 14: X=CHSiMe_3, Y=SiMe_3; 15: X=OH, Y=Cl; 16: X=OAc, Y=Cl; 17: X=OMe, Y=Cl. An important objective of this work is to prepare new polycyclic cage compounds which can be utilized as intermediates for the synthesis of new, substituted tricyclopentanoid natural products (triquinanes) and related systems. Compounds 1-4 were identified as target molecules in this connection.
| Identifer | oai:union.ndltd.org:unt.edu/info:ark/67531/metadc504217 |
| Date | 08 1900 |
| Creators | Huang, Chunmin |
| Contributors | Marchand, Alan P., Jones, Paul R. |
| Publisher | North Texas State University |
| Source Sets | University of North Texas |
| Language | English |
| Detected Language | English |
| Type | Thesis or Dissertation |
| Format | 48 leaves : ill., Text |
| Rights | Public, Huang, Chunmin, Copyright, Copyright is held by the author, unless otherwise noted. All rights reserved. |
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