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Synthesis of trimethylsilyl-substituted pentacyclo(5.4.0.0²,⁶.0³,¹º.0⁵,⁹)undecanes and chloro-substituted pentacyclo(5.4.0.0²,⁶.0³,¹º.0⁵,⁹)undecane

As part of a continuing study of the synthesis and chemistry of new, substituted pentacyclo(5.4.0.0²,⁶.0³,¹º.0⁵,⁹)undecanes, the following compounds have been synthesized: 1: X=O, Y=SiMe_3; 2: X=CH_2, Y=SiMe_3; 3: X=O, Y=Cl; 6: X=OAc, Y=H; 8: X=OC(O)Ph, Y=H; 9: X=OSO_2Ph, Y=H; 11: X=OH, Y=H; 12: X=OMe, Y=H; 14: X=CHSiMe_3, Y=SiMe_3; 15: X=OH, Y=Cl; 16: X=OAc, Y=Cl; 17: X=OMe, Y=Cl. An important objective of this work is to prepare new polycyclic cage compounds which can be utilized as intermediates for the synthesis of new, substituted tricyclopentanoid natural products (triquinanes) and related systems. Compounds 1-4 were identified as target molecules in this connection.

Identiferoai:union.ndltd.org:unt.edu/info:ark/67531/metadc504217
Date08 1900
CreatorsHuang, Chunmin
ContributorsMarchand, Alan P., Jones, Paul R.
PublisherNorth Texas State University
Source SetsUniversity of North Texas
LanguageEnglish
Detected LanguageEnglish
TypeThesis or Dissertation
Format48 leaves : ill., Text
RightsPublic, Huang, Chunmin, Copyright, Copyright is held by the author, unless otherwise noted. All rights reserved.

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