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Effects of Thermal Gradient and Cyclic Oxidation on the Delamination and Lifetime of High Temperature Protective Coatings

Thermal barrier coatings have been widely used to provide thermal protection to components in the hot section of gas turbines. This research focuses on two influencing factors on coating behavior: thermal gradient and cyclic oxidation.
The delamination mechanics under thermal gradient is analyzed, taking thermally grown oxide into consideration. Coatings experience thermal gradients at different stages during actual service flight. One is due to engine power shut down when landing and the other due to internal cooling of the substrate. Thermally grown oxide (TGO) also acts as a critical factor in delamination mechanics. The induced stress gradient and corresponding energy release rate for interface delamination and shallower delamination are presented. Mechanism maps that explain the criteria for preventing delamination from developing and propagating are established. Three cooling trajectories are envisaged to analyze the variation in the possibility of delamination.
Multilayer coatings used in components of the hot section of aero turbine engines also experience cyclic temperature variation during flight cycles. As experiment conditions vary and coating performance is improved, the time required to run through the test of coating failure can be both time-consuming and prohibitive. Therefore, protocols providing prediction of quantified coating behavior are in demand to shorten life-time tests. Curves of mass change are obtained from quantifying scale growth and loss by different models such as Cyclic Oxidation Spall Program (COSP). A modification is made by combining COSP and a mechanic based model to obtain critical parameters for lifetime prediction from short time experiment. The time for coatings to reach peak temperature during cycling is discovered to influence prominently on modeling results. Predictions for several coating compositions and cycling conditions are consistent with the data from the existing experiments of the coating system.

Identiferoai:union.ndltd.org:uottawa.ca/oai:ruor.uottawa.ca:10393/38334
Date26 October 2018
CreatorsDong, Shuhong
ContributorsLiang, Ming, Chen, Kuiying
PublisherUniversité d'Ottawa / University of Ottawa
Source SetsUniversité d’Ottawa
LanguageEnglish
Detected LanguageEnglish
TypeThesis
Formatapplication/pdf

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