The effects of low pH, AI, organic and phenolic acids on the growth of naturally occurring plant species were determined. The amelioration of Al toxicity by Si and organic acids was also investigated. Plants were grown from seeds in nutrient solutions simulating the ionic composition of soil solutions from five soil types ranging from acidic peat to calcareous soil. Soil solutions were extracted and analysed using centrifugation, with and without an immiscible displacent (1,1, I-trichloroethane), at both low (4000 rpm) and high speed (12000 rpm). Races of Holcus lanatus L. and Betula pendula Roth. from acidic soils (FM and SMM) grew better in low pH solutions (pH< 4.0). In acid-sensitive races Ca absorption was inhibited at low pH. Races of B.pendula from strongly to moderately acidic soils (FM, SMM, KP) were AI-tolerant and effectively excluded Al from shoots. Root elongation and leaf expansion were inhibited by all Al concentrations in races from calcareous soils (KR). Low concentrations of Al stimulated growth in some races of B.pendula (2 and 5 mg Al lˉ¹) and Anthoxanthum odoratum L. (1.3 and 2.7 mg Al lˉ¹). Al (25 and 35 mg lˉ¹) inhibited root and shoot growth in H.lanatus. Si (1500 and 2500 µM Si(OH)₄) addition to nutrient solutions alleviated AI-damage and restored nutrient uptake to values similar to those in plants grown with neither Al or Si. The ameliorative effects of Si were possibly achieved through AI/Si co-deposition in the root cell walls and maintenance of Golgi activity. Si at 1500 µM was beneficial but inhibited growth at 2500 µM. Al and hydroxyaluminosilicates at pH 5.6 were not toxic. Formic and tartaric acid ameliorated Al toxicity by reducing its availability. These organic acids on their own stimulated growth in H.lanatus and Deschampsia flexuosa (L.) Trin. Phenolic acids stimulated growth of H.lanatus in acidic solutions (pH 4.0) but not near-neutral solutions, particularly in races from soils high in phenolics. Addition of plant residue to acidic peats increased the growth of races from calcareous and acidic mineral soils.

Seedbanks provide many ecosystem services that support wildlife and regulate soil function. The fate of arable seeds is vital in shaping the aboveground composition of plant communities in agroecosystems. Understanding seed fate informs seedbank dynamics with multi-species interactions, as well as safeguarding arable biodiversity and food security. While many seed fate pathways are well known, the role of myxospermy in temperate agricultural soils is rarely addressed. Mucilage released by myxospermous seeds can modify the soil physical, hydraulic and microbial environment surrounding the seed. The principle biophysical mechanisms underlying the redistribution of weed seeds in eroded soils are unknown. It is possible that myxospermy delivers crucial services at the field scale, such as soil stability and water retention. However, modifications of the soil physical environment have been investigated using only a single-species approach and are often tested with extracted mucilage rather than seeds in-situ. As multiple taxa produce myxospermous seeds, the effects of a single species cannot be generalised. As seeds co-exist in the soil as multi-species communities, a multi-species approach is needed to further understand the functionality of seed mucilage and their implications for soil, relative to the wider seedbank. This thesis focussed on examining the mechanisms responsible for the adhesive interactions between soil and myxospermous seeds and discusses the ecological function and behaviour at the soil particle scale.

Evaporation and transpiration from the soil and plant, respectively, have received increasing attention from those who work with water supply, irrigation, and drainage.

Knowledge of the stress-strain relationship of the compacted soils in tension is of importance for understanding of cracking that occurs in earth structures, in particular embankment dams and landfill barriers. Understanding the correlation between tensile properties and traditional soil parameters and soil suction is essential in identifying problems associated with desiccation induced cracking. A series of extensive laboratory experiments were performed on three different soils from existing embankment dams. This thesis concentrated on the investigation of tensile strength in relation to the type of soil, compaction water content, compaction density ratio, rate of loading, soil suction, moisture retention characteristics and the effect of drying and wetting. Stress-strain behaviour and tensile properties indicated a dependence on soil type and compaction criteria. The plasticity index, clay content and type of mineral has shown a significant influence on tensile strength. Compaction dry of optimum resulted in an increase in strength. Compaction wet of optimum showed a decrease in strength and small increase in strain at failure. Higher compaction effort resulted in higher tensile strength, tensile stiffness and brittle stress-strain behaviour. Difference in loading rate revealed response time for initial tensile deformation as well as sustainable duration up to failure point. The effect of soil suction plays an important role in drying during which specimens exhibited a considerable strength increase. The magnitude of strength increase may have been contributed by a combination of suction, air entry value and compaction density. The effect of wetting could cause decreasing in suction and thus a reduction in strength. Based on the findings, it was concluded that the desiccation-induced may not necessarily occur due to an associated increase in tensile strength. However, an increase in tensile strength is likely to be accompanied by an increase in shrinkage. Therefore, desiccation-induced cracking is related to the interaction between moisture loss, change in soil suction, tensile stress and shrinkage.

The problem of cavity expansion in unsaturated soils is investigated. A unified constitutive model for unsaturated soils is presented in a critical state framework using the concepts of effective stress and bounding surface plasticity theory. Consideration is given to the effects of suction and particle crushing in the definition of the critical state. A simple isotropic elastic rule is adopted. A loading surface and bounding surface of the same shape are defined using simple and versatile functions. A limiting isotropic compression line exists, towards which the stress trajectories of all isotropic compression load paths approach. A non-associated flow rule is assumed for all soil types. Isotropic hardening/softening occurs due to changes in plastic volumetric strains as well as suction for some unsaturated soils, enabling account of the phenomenon of volumetric collapse upon wetting. Results of isotropic compression tests, oedometric compression tests and drained and undrained triaxial compression tests performed on Kurnell (quartz) sand in saturated and unsaturated states and subjected to stresses sufficient to cause particle crushing are presented and used to calibrate the model. The model is also calibrated using results reported in the literature for triaxial tests performed on saturated and unsaturated speswhite kaolin and three load paths. For both soils the model leads to a much improved fit between simulation and experiment compared to that for models based on conventional plasticity theory. The model is implemented into a cavity expansion analysis using the similarity technique, extended for application to unsaturated soils. Cylindrical and spherical cavities are considered, as are drained and undrained conditions. Cavity expansion results for the bounding surface model and conventional plasticity models are compared for saturated conditions. Substantial differences highlight the importance of adopting a model that accurately describes stress-strain behaviour. Cavity expansion results for the bounding surface model and saturated and unsaturated conditions are also compared. Substantial differences, particularly in the limit pressure, highlight the major influence of suction and the importance of accounting for this when using cavity expansion theory to interpret results of the cone penetration and pressuremeter tests.

Title page, contents and abstract only. The complete thesis in print form is available from the University Library. / Thesis (Ph.D.)--University of Adelaide, Dept. of Soil Science,1993

"November 2002. / Includes bibliographical references (leaves 258-275) / xxi, 275 leaves, [8 p.] : ill. (some col.), plates (col.) ; 30 cm. / Title page, contents and abstract only. The complete thesis in print form is available from the University Library. / Thesis (Ph.D.)--University of Adelaide, School of Earth and Environmental Sciences, 2003

Airborne hyperspectral imagery has the potential to overcome the spectral and spatial resolution limitations of multispectral satellite imagery for monitoring salinity at both regional and farm scales. In particular, saline areas that have good cover of salt tolerant plants are difficult to map with multispectral satellite imagery. Hyperspectral imagery may provide a more reliable salinity mapping method because of its potential to discriminate halophytic plant cover from non - halophytes. HyMap and CASI airborne imagery ( at 3m ground resolution ) and Hyperion satellite imagery ( at 30 resolution ) were acquired over a 140 sq km dryland agricultural area in South Australia, which exhibits severe symptoms of salinity, including extensive patches of the perennial halophytic shrub samphire ( Halosarcia pergranulata ), sea barley grass ( Hordeum marinum ) and salt encrusted pans. The HyMap and Hyperion imagery were acquired in the dry season ( March and February respectively ) to maximise soil and perennial vegetation mapping. The optimum time of year to map sea barley grass, an annual species, was investigated through spectral discrimination analysis. Multiple reflectance spectra were collected of sea barley grass and other annual grasses with an ASD Fieldspec Pro spectrometer during the September spring flush and in November during late senescence. Comparing spectra of different species in November attempted to capture the spectral differences between the late senescing sea barley grass and other annual grasses. Broad NIR and SWIR regions were identified where sea barley grass differs significantly from other species in November during late senescence. The sea barley grass was therefore shown to have the potential to be discriminated and mapped with hyperspectral imagery at this time and as a result the CASI survey was commission for November. Other salinity symptoms were characterised by collecting single field and laboratory spectra for comparison to image derived spectra in order to provide certainty about the landscape components that were to be mapped. Endmembers spectra associated with saltpans and samphire patches were extracted from the imagery using automated endmember generation procedures or selected regions of interest and used in subsequent partial unmixing. Spectral subsets were evaluated for their ability to optimise salinity maps. The saltpan spectra contained absorption features consistent with montmorillonite and gypsum. A single gypsum endmember from one image strip successfully mapped saltpans across multiple images strips using the 1750 nm absorption feature as the input to matched filter unmixing. The individual spectra of green and red samphire are dominated by photosynthetic vegetation characteristics. The spectra of green samphire, often seen with red tips, exhibit peaks in both green and red wavebands whereas the red samphire spectra only contain a significant reflectance peak in the visible red wavelength region. For samphire, Mixture Tuned Matched Filtering using image spectra, containing all wavelength regions, from known samphire patches produced the most satisfactory mapping. Output salinity maps were validated at over 100 random sites. The HyMap salinity maps produced the most accurate results compared to CASI and Hyperion. HyMap successfully mapped highly saline areas with a good cover of samphire vegetation at Point Sturt without the use of multitemporal imagery or ancillary data such as topography or PIRSA soil attribute maps. CASI and Hyperion successfully mapped saltpan, however, their samphire maps showed a poor agreement with field data. These results suggest that perennial vegetation mapping requires all three visible, NIR and SWIR wavelength regions because the SWIR region contains important spectral properties related to halophytic adaptations. Furthermore, the unconvincing results of the CASI sea barley grass maps suggests that the optimal sensor for mapping both soil and vegetation salinity symptoms are airborne sensors with high spatial and spectral resolution, that incorporate the 450 to 1450 nm wavelength range, such as HyMap. This study has demonstrated that readily available software and image analysis techniques are capable of mapping indicators of varying levels of salinity. With the ability to map symptoms across multiple image strips, airborne hyperspectral imagery has the potential for mapping larger areas covering sizeable dryland agriculture catchments, closer in extent to single satellite images. This study has illustrated the advantage of the hyperspectral imagery over traditional soil mapping based on aerial photography interpretation such as the NLWRA Salinity 2000 and the PIRSA soil landscape unit maps. The HyMap salinity maps not only improved mapping of saline areas covered with samphire but also provided salinity maps that varied spatially within saline polygons. / Thesis (Ph.D.)--School of Earth and Environmental Sciences, 2006.

Thesis (M. A.)--Inter-American Institute of Agricultural Science of the OAS, 1963. / Includes bibliographical references.

Thesis (Ph. D.)--Ohio State University, 2007. / Title from first page of PDF file. Includes bibliographical references (p. 198-210).