Molecular beam scattering experiments are used to investigate the extent of thermal accommodation of Ne, CD4, ND3, and D2O in collisions with long chain CH3, NH2, and OH terminated self-assembled monolayers (SAMs) on gold. Surface rigidity, internal degrees of freedom of the impinging gas, and potential energy surface well depths have been explored as a way to predict the outcome of a gas-surface collision. Ne is used to assess the mechanical rigidity of the SAMs. The order of rigidity is CH3 < NH2 ~ OH. The NH2 and OH terminated SAMs are more rigid due to the intermolecular hydrogen bonding structure at the gas-surface interface. Despite the hydrogen bonding nature of the NH2 and OH terminated SAMs CD4, ND3, and D2O are extensively thermally accommodated on the surfaces, therefore surface rigidity is no solely responsible for energy transfer dynamics. It was found that the number of degrees of freedom do not predict how extensively a gas will thermally accommodate on a surface capable of hydrogen bonding. A qualitative correlation between increasing potential energy well depths and the extent of thermal accommodation has been established as a result of these scattering experiments. / Master of Science

Paraphrase sparsity is an issue that complicates the training process of question answering systems: syntactically diverse but semantically equivalent sentences can have significant disparities in predicted output probabilities. We propose a method for generating an augmented paraphrase corpus for the visual question answering system to make it more robust to paraphrases. This corpus is generated by concatenating two sequence to sequence models. In order to generate diverse paraphrases, we sample the neural network using diverse beam search. We evaluate the results on the standard VQA validation set. Our approach results in a significantly expanded training dataset and vocabulary size, but has slightly worse performance when tested on the validation split. Although not as fruitful as we had hoped, our work highlights additional avenues for investigation into selecting more optimal model parameters and the development of a more sophisticated paraphrase filtering algorithm. The primary contribution of this work is the demonstration that decent paraphrases can be generated from sequence to sequence models and the development of a pipeline for developing an augmented dataset. / Master of Science

Reinforced concrete (RC) moment frames comprise a significant portion of the built environment in areas with seismic hazards. The beam-to-column joints of these frames are key components that have a significant impact on the structure's behavior. Modern detailing provides sufficient strength within these joints to transfer the forces between the beams and the columns during a seismic event, but existing structures built with poor detailing are still quite prevalent. Identifying the need and extent of retrofits to ensure public safety through nondestructive means is of primary importance. Existing models used to analyze the performance of RC beam-to-column joints have either been developed for modern, well-detailed joints or are simplified so that they do not capture a broad range of phenomena. The present study is aimed to extend a modeling technique based on the nonlinear truss analogy to the analysis of RC beam-to-column joints under cyclic loads. Steel and concrete elements were arranged into a lattice truss structure with zero-length bond-slip springs connecting them. A new steel model was implemented to more accurately capture the constitutive behavior of reinforcing bars. The joint modeling approach captured well the shear response of the joint. It also provided a good indication of the distribution of forces within the joint. The model was validated against three recently tested beam-column subassemblies. These tests represented the detailing practice of poorly-detailed RC moment frames. The analytical results were in good agreement with the experimental data in terms of initial stiffness, strength and damage pattern through the joint. / Master of Science

In the field of optical fiber sensors, one of the most versatile structures is the Fabry-Perot interferometer. This thesis will present a novel sensor based on an Intrisnic Fabry-Perot Inferferometer (IFPI) cavity to measure axial acceleration, refractive index, and temperature. The sensor structure is based on previous work done by R. Wang at the Center for Photonics Technology. This work suggests its flexibility in many different roles with a sensitivity to axial acceleration of 70 pm/unit of acceleration, to refractive index of 60 nm/Refractive Index Unit, and to temperature of 7.8 pm/°C. Future work is also discussed in measuring tangential acceleration with direction using a PM fiber as the lead-in and observing the reflections on the slow and fast axes. / Master of Science

With piezoceramic materials, it is possible to harvest power from vibrating structures. It has been proven that micro- to milliwatts of power can be generated from vibrating systems. We develop definitive, analytical models to predict the power generated from a cantilever beam and cantilever plate. Harmonic oscillations and random noise will be the two different forcing functions used to drive each system. The predictive models are validated by being compared to experimental data. A parametric study is also performed in an attempt to optimize the cantilever beam system's power generation capability. / Master of Science

Yes / A printed dipole antenna integrated with a duplex RF switch used for mobile base station antenna beam steering is presented. A coplanar waveguide to coplanar strip transition was adopted to feed the printed dipole. A novel RF switch circuit, used to control the RF signal fed to the dipole antenna and placed directly before the dipole, was proposed. Simulated and measured data for the CWP-to-CPS balun as well as the measured performance of the RF switch are shown. It has demonstrated the switch capability to control the beam in the design of beam steering antenna array for mobile base station applications.

This thesis mainly aims at application of principles of engineering technology in the field of molecular beam epitaxy (MBE). MBE is a versatile technique for growing epitaxial thin films of semiconductors and metals by impinging molecular beams of atoms onto a heated substrate under ultra-high vacuum (UHV) conditions. Here, a LabVIEW® (laboratory virtual instrument engineering workbench) software (National Instruments Corp., http://www.ni.com/legal/termsofuse/unitedstates/usH) program is developed that would form the basis of a real-time control system that would transform MBE into a true-production technology. Growth conditions can be monitored in real-time with the help of reflection high energy electron diffraction (RHEED) technique. The period of one RHEED oscillation corresponds exactly to the growth of one monolayer of atoms of the semiconductor material. The PCI-1409 frame grabber card supplied by National Instruments is used in conjunction with the LabVIEW software to capture the RHEED images and capture the intensity of RHEED oscillations. The intensity values are written to a text file and plotted in the form of a graph. A fast Fourier transform of these oscillations gives the growth rate of the epi-wafer being grown. All the data being captured by the LabVIEW program can be saved to file forming a growth pedigree for future use. Unattended automation can be achieved by designing a control system that monitors the growth in real-time and compares it with the data recorded from the LabVIEW program from the previous growth and adjusts the growth parameters automatically thereby growing accurate device structures.

The rolling of an aircraft about its fuselage produces centrifugal forces which affect the stiffness of the wings. A number of previous studies explain the effect of centrifugal stiffening in rotating beams and consequently on the frequencies of the beam. Multiple cases of the rotating beam are explored in this thesis to investigate effects of mass distribution and boundary conditions on the frequencies of centrifugally stiffened beams. It is found that for a uniform beam with all degrees of freedom free on both ends, the rigid modes of the beam are affected and are no longer zero when it is stiffened from centrifugal forces. This thesis aims to set up a model to investigate the stiffening effects using the mAEWing2 aircraft. A preliminary analysis is done for the mAEWing2 aircraft and the roll rate, control surface deflection and angle of attack are identified as the parameters to be studied. For a given angle of attack and control surface deflection, the centrifugal forces in the aircraft in steady roll are determined using trim analysis. These are used to pre-stress the model for modal analysis. It is found that in mAEWing2 aircraft in steady roll maneuvers, the centrifugal stiffening effect on the natural frequencies is not significant. It emphasizes the need to conduct a sensitivity analysis to include centrifugal stiffening in the dynamic analysis while designing an aircraft. This, along with some de-stiffening due to gravity loads might be important for the future N+3 aircraft with their high aspect ratio large wingspans. / MS / Structural analysis is mainly concerned with determining the behavior of a structure when subjected to a disturbance. The natural response of a structure to some disturbance is termed as free vibration of the structure. The term vibration describes repetitive motion that can be observed in a structure and is influenced by its material and structural properties. These vibrations may cause fatigue in the structure and the performance of the structure may be adversely affected. Consequently it becomes necessary to study and eliminate these vibrations. The vibration characteristics of a system are described by its natural frequencies and mode shapes. Natural frequencies of a structure are the frequencies at which the structure naturally tends to vibrate if it is subjected to a disturbance. The deformed shape of the structure vibrating at one of its specific natural frequencies of vibration is termed its normal mode shape. In the case of a rotating beam, the centrifugal force acts axially along the length of the beam. When the rotating beam deflects upwards, the centrifugal force creates a downward bending moment, reducing its net deflection. The ratio of force to displacement increases, increasing the stiffness of the rotating beam. This effect is called the stiffening effect. There is a large volume of literature that presents the effect of stiffening on the natural frequencies of a rotating beam model, for various boundary conditions. Such a stiffening analysis has also been done for the blades of a turbine and turbo fans. In addition, there are models available for analyzing the aerodynamic model of an aircraft in roll, considering stability derivatives of the aircraft. However, there are gaps in the available literature in analyzing an aircraft in roll from the perspective of structural analysis. The rolling of an aircraft about its fuselage produces centrifugal forces which affect the stiffness of the wings. A number of previous studies explain the effect of centrifugal stiffening in rotating beams and consequently on the frequencies of the beam. Multiple cases of the rotating beam are explored in this thesis to investigate effects of mass distribution and boundary conditions on the frequencies of centrifugally stiffened beams. It is found that for a uniform beam with all degrees of freedom free on both ends, the rigid modes of the beam are affected and are no longer zero when it is stiffened from centrifugal forces. This further motivates the need for investigating the effect of centrifugal stiffening in spinning spacecraft and aircraft in rapid roll maneuvers. This thesis further aims to set up a model to investigate the stiffening effects using the mAEWing2 aircraft. A preliminary analysis is done for the mAEWing2 aircraft and the roll rate, control surface deflection and angle of attack are identified as the parameters to be studied. For a given angle of attack and control surface deflection, the centrifugal forces in the aircraft in steady roll are determined using trim analysis. These are used to pre-stress the model for modal analysis. It is found that in the mAEWing2 aircraft in steady roll maneuvers the stiffening effect on the frequencies is not significant. It emphasizes the need to conduct a sensitivity analysis to include centrifugal stiffening in the dynamic analysis while designing an aircraft. This, along with some de-stiffening due to gravity loads might be important for the future N+3 aircraft with their high aspect ratio large wingspans.

The recent earthquakes in Christchurch have made it clear that issues exist with current RC frame design in New Zealand. In particular, beam elongation in RC frame buildings was widespread and resulted in numerous buildings being rendered irreparable. Design solutions to overcome this problem are clearly needed, and the slotted beam is one such solution. This system has a distinct advantage over other damage avoidance design systems in that it can be constructed using current industry techniques and conventional reinforcing steel. As the name suggests, the slotted beam incorporates a vertical slot along part of the beam depth at the beam-column interface. Geometric beam elongation is accommodated via opening and closing of these slots during seismically induced rotations, while the top concrete hinge is heavily reinforced to prevent material inelastic elongation. Past research on slotted beams has shown that the bond demand on the bottom longitudinal reinforcement is increased compared with equivalent monolithic systems. Satisfying this increased bond demand through conventional means may yield impractical and economically less viable column dimensions. The same research also indicated that the joint shear mechanism was different to that observed within monolithic joints and that additional horizontal reinforcement was required as a result. Through a combination of theoretical investigation, forensic analysis, and database study, this research addresses the above issues and develops design guidelines. The use of supplementary vertical joint stirrups was investigated as a means of improving bond performance without the need for non-standard reinforcing steel or other hardware. These design guidelines were then validated experimentally with the testing of two 80% scale beam-column sub-assemblies. The revised provisions for bond within the bottom longitudinal reinforcement were found to be adequate while the top longitudinal reinforcement remained nominally elastic throughout both tests. An alternate mechanism was found to govern joint shear behaviour, removing the need for additional horizontal joint reinforcement. Current NZS3101:2006 joint shear reinforcement provisions were found to be more than adequate given the typically larger column depths required rendering the strut mechanism more effective. The test results were then used to further refine design recommendations for practicing engineers. Finally, conclusions and future research requirements were outlined.

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