Since only little is known in the field of Solid Oxide Fuel Cell (SOFC) operation about internal reforming of methane at present, the aim of this thesis study is to conduct a detailed investigation delivering the basis for further experimental and theoretical work. Also information is required if the concept of internal reforming has technical development potential. The thesis is arranged into two major parts being a thermodynamic investigation and an application of a suitable kinetic model. Pure methane tends to decompose at the high operation temperatures of the SOFC (about 950°C) thus forming solid carbon. Therefore it is necessary to include a fuel preparation process delivering H2 and CO that can be utilized by the SOFC. The fuel processing can either be carried out by steam reforming or partial oxidation. It is shown by a thermodynamic investigation that fuel processing by partial oxidation yields a fuel gas of inferior quality than fuel processing by steam reforming. The kinetic part contains the application of a model describing the chemical and electrochemical conversion occuring in the SOFC as detailed as possible at present. This model is used to investigate the thermal behaviour of an SOFC process referring to technical operation parameters. It is shown that internal reforming has technical development potential although a lot of care must be paid to the heat management. Particular operation conditions might exist where the highly endothermic steam reforming process could cause a breakdown of the complete fuel cell process due to its enormous local cooling effect.

No description available.

No description available.

Many wave energy convertors are designed to use either vertical (heave) or horizontal (surge) movements of waves. But the frequency response of small heaving buoys and oscillating water column devices shows that they are too stiff and so their resonance is at too short a period. A device moving in the horizontal (surge) direction has less restoring spring and so its resonance is at too long a period. It follows that a device that moved at some intermediate slope angle could have an intermediate value of hydrodynamic stiffness and so be resonant at a variable and desirable part of the wave spectrum. There have been two series of model tests in this work. The first used a simple free-floating model with no power take-off apparatus and with constraint achieved by means of a large inertia plate lying in the slope plane. The second used a rig that constrained the slope movement of the buoy head by means of hydrostatic bearings running on a guide rod set to the chosen slope angle. An external power take-off system was used to simulate a linear damper for absorbing the incident wave energy and control the motion of the model. This thesis firstly studies the potential of varying the slope angle as a way of tuning the natural period of the device to suit useful wave periods. Secondly, it studies the experimental and theoretical power capture ability of models with different slope angles in regular waves in the frequency domain. The hydrodynamic coefficients of the model were determined both experimentally and numerically based on linear hydrodynamic concepts. The power absorption of the models was calculated using the experimental data of the hydrodynamic coefficients and also measured directly. Some control of power take-off was also investigated. Some irregular wave tests were carried out for the 45 degrees slope angle case. The results show that it is feasible to alter the slope angle of the device as a way of tuning its natural period. However, in further studies of the power capture ability for different slope angles, the device shows a very wide bandwidth and high efficiency performance when it is set to 45 degrees slope angle. This suggests that to constrain the device to a 45 degrees slope angle is suitable for most of the sea states.

No description available.

No description available.

No description available.

No description available.

No description available.

No description available.