The use of steel fiber reinforced concrete (SFRC hereafter) is becoming more and more common. Building codes and recommendations are gradually including the positive effect of fibers on mechanical properties of concrete. How to take advantage of the higher ductility and energy absorption capacity of SFRC to reduce anchorage lengths when using fibers is not a straightforward issue. Fibers improve bond performance because they confine reinforcement (playing a similar role to that of transverse reinforcement). Their impact on bond performance of concrete is really important in terms of toughness/ductility. The study of previous literature has revealed important points of ongoing discussion regarding different issues, especially the following: a) whether the effect of fibers on bond strength is negligible or not, b) whether the effect of fibers on bond strength is dependent on any other factors such as concrete compressive strength or concrete cover, c) quantifying the effect of fibers on the ductility of bond failure (bond toughness). These issues have defined the objectives of this thesis. A modified version of the Pull Out Test (POT hereafter) has been selected as the most appropriate test for the purposes of this research. The effect of a number of factors on bond stress¿slip curves has been analyzed. The factors considered are: concrete compressive strength (between 30 MPa and 50 MPa), rebar diameter (between 8 mm and 20 mm), concrete cover (between 30 mm and 5 times rebar diameter), fiber content (up to 70 kg/m3), and fiber slenderness and length. The experimental program has been designed relying on the principles of statistical Design Of Experiments. This has allowed to select a reduced number of combinations to be tested without any bias or loss of accuracy. A total of 81 POT specimens have been produced and tested. An accurate model for predicting the mode of bond failure has been developed. It relates splitting probability to the factors considered. It has been proved that increasing fiber content restrains the risk of splitting failure. The favorable effect of fibers when preventing splitting failures has been revealed to be more important for higher concrete compressive strength values. Higher compressive strength values require higher concrete cover/diameter ratios for splitting failure to be prevented. Fiber slenderness and fiber length modify the effect of fiber content on splitting probability and therefore on minimum cover/diameter ratios required to prevent splitting failures. Two charts have been developed for estimating the minimum cover/ diameter ratio required to prevent splitting. Predictive equations have been obtained for estimating bond strength and areas under the bond stress¿slip curve as a function of the factors considered. Increasing fiber content has a slightly positive impact on bond strength, which is mainly determined by concrete compressive strength. On the contrary, fibers have a very important effect on the ductility of bond failure, just as well as concrete cover, as long as no splitting occurs. Multivariate analysis has proved that bond stress corresponding to the onset of slippage behaves independently from the rest of the bond stress¿slip curve. The effect of fibers and concrete compressive strength on bond stress values corresponding to the onset of slips is mainly attributable to their influence on the material mechanical properties. On the contrary, the effect of fibers and concrete cover on the rest of the bond stress¿slip curve is due to their structural role. / García Taengua, EJ. (2013). Bond of Reinforcing Bars to Steel Fiber Reinforced Concrete (SFRC) [Tesis doctoral]. Universitat Politècnica de València. https://doi.org/10.4995/Thesis/10251/32952

Since World War II, the military has sought methods for rapid stabilization of weak soils for support of its missions worldwide. Over the past 60 years, cement and lime have consistently been found to be among the most effective stabilizers for road and airfield applications, although recent developments show promise using nontraditional stabilizers. The purpose of this research is to determine the most effective stabilizers and dosage rates of stabilizers to increase the strength of soft clay soils (initial CBR = 2) within 72 hours for contingency airfields to support C-17 and C-130 aircraft traffic. Pavement design charts for various aircraft loading conditions were generated using the Pavement-Transportation Computer Assisted Structural Engineering Program, which was developed by the Engineering Research and Development Center to determine ranges of required strength and thickness for an underlying subbase layer and a top base layer, such as stabilized soil, crushed-aggregate, or aluminum matting. From laboratory studies, the required design strengths for many loading conditions were achieved by treating clay with 2%-4% pelletized quicklime for the underlying subbase layer, and treating clay with 2%-4% pelletized quicklime, 1% RSC15 fibers, and 11% Type III cement for the top base layer. While the base layer requires a minimum thickness of six inches, the required subbase layer thickness is often quite large and may be difficult to construct. However, newly developed construction equipment currently used for subgrade stabilization on civilian projects should be able to stabilize the soil down to these large required depths and make construction possible. / Master of Science

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No description available.

Recently, a new class of sensors has emerged which have scalar outputs derived from distributed measurements over a significant gauge length; these sensors are known as distributed-effect sensors. The most familiar example of a distributed-effect sensor is the piezoelectric laminate PVDF film; other examples include holographic sensors and modal domain optical fiber sensors. Optical fiber sensors are particularly attractive for smart structure and materials applications because they have low mass, are flexible, and can be easily embedded in a variety of materials. Distributed-effect sensors can be fabricated with spatially varying sensitivity to the distributed measurand and act as spatial filters. The spatial variation in the sensor sensitivity, known as the sensor's weighting function, determines the measurement provided by the spatial filter. Spatial filters can be configured to measure a variety of structural parameters, such as modal amplitudes and traveling waves, that can not be measured directly using point sensors. The mathematical model of the sensor is described and incorporated into a state-space model of a flexible structure. Several criteria are described in this dissertation for selecting the weighting functions of distributed-effect sensors for structural control laws. The weighting function realized in the fabrication of a distributed-effect sensor may differ from the desired weighting function, causing the output of the manufactured sensor to differ from the desired measurement. In order to design reliable structural control laws, the nature and effects of errors in the implemented weighting functions of distributed-effect sensors must be understood. This dissertation describes several causes of errors in distributed-effect sensor weighting functions. Errors in the weighting functions of distributed-effect sensors are integrated into the mathematical models of the sensors, and the effects of these errors on the sensor outputs are examined. / Ph. D.

A novel bidirectional decomposition of exact solutions to the scalar wave equation has been shown to form a natural basis for synthesizing localized wave (LW) solutions that describe localized, slowly decaying transmission of energy in free space. In this work, we demonstrate the existence of LW solutions in optical fiber waveguides operated in the linear regime. In this sense, these solutions are fundamentally different from the non-linear, soliton-based communication systems. Despite the dielectric waveguiding constraints introduced by the fiber, solutions that resemble the free-space solutions can be obtained with broad bandwidth source spectra. As with the free-space case, these optical waveguide LW solutions propagate over very long distances, undergoing only local variations. Four different source modulation spectra that give rise to solutions similar to Focus Wave Modes (FWM’s), splash pulses, the scalar equivalent of Hillion’s spinor modes and the Modified Power Spectrum (MPS) pulses are considered. A detailed study of the MPS pulse is performed, practical issues regarding source spectra are addressed, and distances over which such LW solutions maintain their non-decaying nature are quantified. Present day state-of-the-art technology is not capable of meeting requirements that will make practical implementation of LW solution-based fiber optic systems a reality. We address futuristic technology issues and briefly describe efforts that could lead to efficient LW solution-based fiber optic systems. / Ph. D.

ln the last several years, considerable attention has been paid to the study of dispersion-flattened single-mode fibers which offer a high transmission capacity with low losses through a wide range of wavelengths. However, the existing designs are sensitive to bending and manufacturing tolerances, and are not truly single-mode at most wavelengths of interest. To remedy these problems a new series of broadband dispersion-flattened truly single-mode fiber designs are proposed. These fibers have both dispersion-shifted and dispersion-flattened features with low splice and bend losses. Results demonstrating a total dispersion of ±0.97 ps/km-nm over the entire spectral range between 1.31 μm to 1.66 μm are presented. Such dispersion-flattening is achieved while simultaneously maintaining a mode-field radius of 3 μm to 5 μm in the dispersion-flattened wavelength range. The most significant achievement is that the proposed muIti-clad fiber design is strictly single-mode and splice and bend losses are smaller than those of double-clad, triple-clad, and quadruple-clad fibers with the same value of dispersion. Ultralow dispersion fibers, whose chromatic dispersion and the first and second-order derivatives of the chromatic dispersion are zero at 1.5 μm or 1.55 μm, are described. This effectively increases the laser emission tolerance. Ultralow dispersion fibers open the way to wavelength multiplexing with currently available inexpensive multifrequency lasers, either in local or long distance networks. These fibers also have low splice and bend losses compared to double-clad, triple-clad, and quadruple-cIad fibers. An inverse waveguide synthesis program, which can trace multiple objective functions and optimize multiple parameters simultaneously, is developed. An objective function is applied, for the first time, to optimize the dispersion-flattened single-mode fiber index profile with respect to: (1) minimum dispersion, (2) the wavelengths of zero-dispersion, (3) maximum width of dispersion-flattened window, (4) maximum layer index difference less than 0.8%, and (5) layer thickness larger than 3.5 μm. The accuracy of chromatic dispersion calculations in dispersion-flattened fibers is evaluated. lt has been shown that the accuracy of approximate methods is influenced not only by the index differences, but also by their derivatives with respect to wavelength. The matrix method and direct numerical integration of the wave equation are used to compute the mode propagation constants, cutoff frequencies, field distributions, mode-field radius, and splice loss, and carry out production tolerance analysis for multi-clad step-index fibers and graded-index fibers, respectively. Detailed analysis and optimized fiber data are presented. / Ph. D.

The effect of anodization in NaOH, H₂SO₄, and amine salts on the surface chemistry of carbon fibers was examined by x-ray photoelectron spectroscopy (XPS). The surfaces of carbon fibers after anodization in NaOH and H₂SO₄ were examined by scanning transmission electron microscopy (STEM). angular dependent XPS, ultraviolet (UV) absorption spectroscopy of the anodization bath, secondary ion mass spectrometry, and polar/dispersive surface energy analysis. Hercules AS-4, Dexter Hysol XAS, and Union Carbide T-300 fibers were examined by STEM, angular dependent XPS, and breaking strength measurement before and after commercial surface treatment. The fibers from the three companies were anodized to create similar surface chemistry on each fiber. XPS was used to compare the surface chemistry after anodization. Adhesion of carbon fibers to polysulfone, polycarbonate, and polyetherimide was studied using the fiber critical length test. Oxygen and nitrogen were added to the fiber surfaces by anodization in amine salts. Analysis of the plasmon peak in the carbon 1s signal indicated that H₂SO₄ anodization affected the morphological structure of the carbon fiber surface. UV absorption spectra of the anodization bath, SIMS, and angular dependent XPS indicate that NaOH anodization removes amorphous carbon from the fiber. The oxygen and nitrogen content on the fiber surfaces were affected by commercial surface treatment. The Union Carbide fiber had much lower oxygen content after laboratory anodization than the Hercules or Dexter Hysol fibers. The breaking strength of all three fibers was increased by anodization. Laboratory anodization resulted in better fiber/matrix adhesion than the commercial surface treatment for the Hercules and Dexter Hysol fibers. Fiber/matrix adhesion was better for the commercially treated Union Carbide fiber than for the laboratory treated fiber. The work of adhesion of carbon fibers to thermoplastic resins was calculated using the geometric mean relationship. A correlation was observed between the dispersive component of the work of adhesion and the interfacial adhesion. / Ph. D. / incomplete_metadata

The present study was initiated to evaluate the pulmonary inflammatory and fibrotic responses induced by single and repeated exposures to glass fibers. Single and repeated intratracheal injections of glass fibers induced an acute inflammatory response which progressed to a chronic inflammatory and fibrotic response. Mice exposed to glass fibers in single or repeated doses demonstrated elevated numbers of eosinophils, neutrophils and macrophages and increases in cell-free protein in lung lavage fluid at five days post-exposure. These parameters, in addition to relative lung/body weight ratios and lung tissue hydroxyproline levels, were elevated in comparison to saline control animals at five weeks post-exposure. Although repeated exposures to glass fibers did not potentiate the cellular inflammatory response, they did induce a marked infiltration of eosinophils, a response not observed with either asbestos or silica exposures. These observations suggest that glass fibers may be more toxic to the lungs than previously thought.

Thesis (PhD)--Stellenbosch University, 2011. / ENGLISH ABSTRACT: The concept of broadband coherent supercontinuum (SC) generation in all-normal dispersion (ANDi) fibers in the near-infrared, visible and ultraviolet (UV) spectral regions is introduced and investigated in detail. In numerical studies, explicit design criteria are established for ANDi photonic crystal fiber (PCF) designs that allow the generation of flat and smooth ultrabroad spectral profiles without significant fine structure and with excellent stability and coherence properties. The key benefit of SC generation in ANDi fibers is the conservation of a single ultrashort pulse in the time domain with smooth and recompressible phase distribution. In the numerical investigation of the SC generation dynamics self-phase modulation and optical wave breaking are identified as the dominant nonlinear effects responsible for the nonlinear spectral broadening. It is further demonstrated that coherence properties, spectral bandwidth and temporal compressibility are independent of input pulse duration for constant peak power. The numerical predictions are in excellent agreement with experimental results obtained in two realizations of ANDi PCF optimized for the near-infrared and visible spectral region. In these experiments, the broadest SC spectrum generated in the normal dispersion regime of an optical fiber to date is achieved. The exceptional temporal properties of the generated SC pulses are verified experimentally and their applicability for the time-resolved study of molecular dynamics in ultrafast transient absorption spectroscopy is demonstrated. In an additional nonlinear pulse compression experiment, the SC pulses obtained in a short piece of ANDi PCF could be temporally recompressed to sub-two cycle durations by linear chirp compensation. Numerical simulations show that even shorter pulse durations with excellent quality can be achieved by full phase compensation. The concept is further extended into the UV spectral regime by considering tapered optical fibers with submicron waist diameter. It is shown that coherent SC spectra with considerable spectral power densities in the usually hard to reach wavelength region below 300 nm can be generated using these freestanding photonic nanowires. Although technological difficulties currently prevent the fabrication of adequate nanofibers, the concept could be experimentally verified by coherent visible octave-spanning SC generation in tapered suspended core fibers with ANDi profile. The work contained in this thesis therefore makes important contributions to the availability and applicability of fiber-based broadband coherent SC sources with numerous high-impact applications in fundamental science and modern technology. / AFRIKAANSE OPSOMMING: Die konsep van breëband koherente superkontinuum (SK) in alles-normaal dispersiewe (ANDi) vesels in die naby-infrarooi, sigbare en ultraviolet (UV) spektrale gebiede word voorgestel en in detail ondersoek. In numeriese studies word eksplisiete ontwerpskriteria vasgestel vir ANDi fotoniese kristal vesel (FKV) ontwerpe wat dit moontlik maak om plat en gladde ultra-breë spektrale profiele te genereer sonder noemenswaardige fynstruktuur en met uitstekende stabiliteit en koherensie eienskappe. Die sleutel voordeel van SK genering in ANDi vesels is die behoud van ’n enkele ultrakort puls in tyd met ’n gladde en saamdrukbare fase distribusie. In die numeriese ondersoek van die SK generering is die dinamika van fase selfmodulering geïdentifiseer as die dominante nie-lineêre effek wat verantwoordelik is vir die nie-lineêre spektrale verbreding. Daar word voorts aangetoon dat die koherensie eienskappe, spektrale bandwydte en saamdrukbaarheid in tyd onafhanklik is van die inset pulsduur vir konstante drywing. Die numeriese voorspellings stem uitstekend ooreen met die eksperimentele resultate wat verkry is met twee ANDi FKVÕs wat optimeer is vir die naby-infrarooi en sigbare spektrale gebied. In hierdie eksperimente is die breedste SK spektrum gegenereer wat tot hede in die normaal dispersiewe regime met ’n optiese vesel behaal is. Die besondere eienskappe van die genereerde SK pulse is eksperimenteel bevestig en die toepasbaarheid vir tyd opgelosde studie van molekulêre dinamika is gedemonstreer. In ’n addisionele nie-lineêre puls kompressie eksperiment is SK pulse verkry in ’n kort stuk ANDi FKV wat in tyd saamgedruk kon word tot sub-twee siklus tydsduur deur liniêre tjirp kompensering. Numeriese simulasies toon aan dat selfs korter pulse met uitstekende kwaliteit behaalbaar is met volledige fase kompensasie. Die konsep is verder uitgebrei na die UV spektrale gebied deur ’n koniese vesel te beskou met sub-mikron diameter. Daar is aangetoon dat koherente SK spektra met noemenswaardige spektrale drywing in die golflengte gebied onder 300 nm, wat gewoonlik as moeilik toeganklik beskou word, bereik kan word deur hierdie vrystaande fotoniese nano-vesels aan te wend. Alhoewel tegnologiese probleme die vervaardiging van voldoende nano-vesels verhinder, kon die konsep eksperimenteel bewys word deur koherente sigbare oktaafspannende SK te genereer in koniese gesuspendeerde kern vesels met ’n ANDi profiel aan te wend. Die werk wat in die tesis vervat is, maak dus belangrike bydraes tot die beskikbaarheid en toepasbaarheid van vesel gebaseerde breëband koherente SK bronne met verskeie hoë impak toepassings in fundamentele wetenskap en moderne tegnologie.