University of Technology, Sydney. Faculty of Engineering. / This research has analysed the economy-wide impacts of carbon tax as a policy option to reduce the rate of growth of carbon-dioxide emissions from the electricity sector in Australia. These impacts are analysed for energy and non energy sectors of the economy. An energy-oriented Input–Output framework, with ‘flexible’ production functions, based on Translog and Cobb-Douglas formulations, is employed for the analysis of various impacts. Further, two alternative conceptions of carbon tax are considered in this research, namely, based on Polluter Pays Principle (PPP) and Shared Responsibility Principle (SRP). In the first instance, the impacts are analysed, for the period 2005–2020, for tax levels of $10 and $20 per tonne of CO2, in a situation of no a-priori limit on CO2 emissions. The analysis shows that CO2 emissions from the electricity sector, when carbon tax is based on PPP, would be 211 and 152 Mt, for tax levels of $10 and $20, respectively (as compared to 250 Mt in the Base Case scenario, that is, the business-as-usual-case). The net economic costs, corresponding with these tax levels, expressed in present value terms, would be $27 and $49 billion, respectively, over the period 2005-2020. These economic costs are equivalent to 0.43 and 0.78 per cent of the estimated GDP of Australia. Further, most of the economic burden, in this instance, would fall on the electricity sector, particularly coal-fired electricity generators – large consumers of direct fossil fuel. On the other hand, in the case of a carbon tax based on SRP, CO2 emissions would be 172 and 116 Mt, for tax levels of $10 and $20, respectively. The corresponding net economic costs would be $47 (0.74 per cent of GDP) and $84 (1.34 per cent of GDP) billion, respectively, with significant burden felt by the commercial sector – large consumers of indirect energy and materials whose production would contribute to CO2 emissions. Next, the impacts are analysed by placing an a-priori limit on CO2 emissions from the electricity sector – equivalent to 108 per cent of the 1990 level (that is, 138 Mt), by the year 2020. Two cases are analysed, namely, early action (carbon tax introduced in 2005) and deferred action (carbon tax introduced in 2010). In the case of early action, the analysis suggests, carbon tax of $25 and $15, based on PPP and SRP, respectively, would be required to achieve the above noted emissions target. The corresponding tax levels in the case of deferred action are $51 and $26, respectively. This research also shows that the net economic costs, in the case of early action, would be $32 billion (for PPP) and $18 billion (for SRP) higher than those in the case of deferred action. However, this research has demonstrated, that this inference is largely due to the selection of particular indicator (that is, present value) and the relatively short time frame (that is, 2005–2020) for analysis. By extending the time frame of the analysis to the year 2040, the case for an early introduction of carbon tax strengthens. Overall, the analysis in this research suggests that an immediate introduction of carbon tax, based on SRP, is the most attractive approach to reduce the rate of growth of CO2 emissions from the electricity sector and to simultaneously meet economic and social objectives. If the decision to introduce such a tax is deferred, it would be rather difficult to achieve not only environmental objectives but economic and social objectives as well.

Thesis (Ph. D.)--University of Texas at Austin, 2006. / Vita. Includes bibliographical references.

Thesis (Ph. D.)--Ohio State University, 1982. / Includes bibliographical references (leaves 150-157). Available online via OhioLINK's ETD Center.

Given an amino acid sequence with the £\-carbon 3D coordinates on its backbone, the all-atom protein backbone reconstruction problem (PBRP) is to rebuild the 3D coordinates of all atoms (N, C and O atoms) on the backbone. In this thesis, we propose a method for solving PBRP based on the homology modeling. First, we extract all consecutive 4-residue fragments from all protein structures in PDB. Each fragment is identified by its second, third and fourth residues. Thus, the fragments are classified into 8000 residue groups. In each residue group, the fragments with similar structures are clustered together. And one typical fragment is used to represent one cluster. These typical fragments form our fragment library. Then, we find out possible candidates in the fragment library to reconstruct the backbone of the target protein. To test the performance of our method, we use two testing sets of target proteins, one was proposed by Maupetit et al. [20] and the other is a subset extracted from CASP7. We compare the experimental results of our method with three previous works MaxSprout, Adcock¡¦s method, and SABBAC proposed by Maupetit et al.. The reconstruction accuracy of our method is comparable to these previous works. And the solution of our method is more stable than the previous works in most target proteins. The time efficiency of our method is also satisfactory.

A fundamental study of the correlations between ion energy, substrate temperature, and plasma density with hydrogen content, percent sp2 bonding, optical gap, and refractive index of hydrogenated amorphous carbon (a-C) films is presented. A strong dependency between the ion energy used during deposition and the film’s microstructure is shown. Moreover, it is revealed that the optical properties of the a-C films are controlled by the concentration and size of sp2 clusters in the film. Through N2 mixing in the source gas, room-temperature nitrogen doped polymeric-like a-C films were demonstrated for the first time. X-ray Photoelectron Spectroscopy revealed an increase in the Fermi level of these films with increased nitrogen content. A proof-of-concept a-C based transparent heat mirror (THM) was demonstrated. It was shown that a-C acts as an oxygen-free protective barrier and anti-reflective coating for Ag films in the THM, increasing the transmission in the visible region by 10-20%.

A fundamental study of the correlations between ion energy, substrate temperature, and plasma density with hydrogen content, percent sp2 bonding, optical gap, and refractive index of hydrogenated amorphous carbon (a-C) films is presented. A strong dependency between the ion energy used during deposition and the film’s microstructure is shown. Moreover, it is revealed that the optical properties of the a-C films are controlled by the concentration and size of sp2 clusters in the film. Through N2 mixing in the source gas, room-temperature nitrogen doped polymeric-like a-C films were demonstrated for the first time. X-ray Photoelectron Spectroscopy revealed an increase in the Fermi level of these films with increased nitrogen content. A proof-of-concept a-C based transparent heat mirror (THM) was demonstrated. It was shown that a-C acts as an oxygen-free protective barrier and anti-reflective coating for Ag films in the THM, increasing the transmission in the visible region by 10-20%.

University of Macau / Faculty of Science and Technology / Department of Civil and Environmental Engineering

Accumulation of CO2 in the atmosphere has triggered research on topics related to causes, effects, and solutions to potential problems associated with global warming. The present research was conducted to determine if grassland plant communities can be managed to promote sequestration of carbon in the soil, potentially mitigating the effects of increasing atmospheric CO2. The effects of shrub invasion or heavy livestock grazing on peak standing crop of phytomass, root mass and soil organic carbon content were therefore studied. These studies were complimented by a study of the decomposition rates of leaves and roots of snowberry and grasses. The effects of snowberry encroachment on peak standing crop of aboveground phytomass, and soil organic carbon content (SOC) were also studied. Total aboveground phytomass in the snowberry community was more than triple that of the ecotone and was 6-times greater than that of the grassland community. Similarly, the mass of large roots was greatest in the snowberry community (1.2 kg m-2, SE= 0.19), intermediate in the ecotone (0.5 kg m-2, SE= 0.08), and least in the grassland (0.1 kg m-2, SE= 0.04). Conversely, the mass of fine and medium roots was not different (P>0.05) among the three communities, averaging 0.7 kg m-2 in all communities (SE= 0.03, 0.07, 0.49 in snowberry, ecotone and grassland, respectively). Greater aboveground phytomass did not correspond with greater SOC in the snowberry community. Soil organic carbon in the upper 50 cm averaged 8.3 (SE= 0.7), 7.9 (SE= 1.0), and 7.9 (SE= 0.7) kg m-2 in snowberry, ecotone, and grassland communities, respectively. Peak standing crop of aboveground phytomass averaged 157 g m-2 (SE= 27) and 488 g m-2 (SE= 48) in grazed and ungrazed grassland, respectively. Conversely, grazing had no affect on root mass. The mass of fine roots averaged 0.9 kg m-2 (SE= 0.04) and 0.8 kg m-2 (SE= 0.06) in grazed and ungrazed grassland, respectively, while that of medium roots averaged 0.6 kg m-2 (SE= 0.07) in both grazing treatments. Total SOC in the upper 50 cm of soil was not affected (P>0.05) by livestock grazing, averaging 5.5 kg m-2 (SE= 0.7) in grazed and 6.8 kg m-2 (SE= 0.9) in ungrazed grassland. Livestock grazing also had no effect (P>0.05) on SOC at the 0-3, 3-10, 10-20, 20-30, and 30-40 cm depths. The SOC in fine- and coarse-textured soils averaged 7.6 kg m-2 (SE= 0.8) and 5.1 kg m-2 (SE=0.7), respectively. Differences existed between decomposition of roots and leaves for graminoids and snowberry. On a monthly basis decomposition was 0.6 to 0.8 % greater in leaves than roots. The decomposition of roots and leaves ranged from 2.2 to 5.0 % month-1. Decay rate constants for leaves ranged from 0.45 yr-1 (SE= 0.03) to 0.71 yr-1 (SE= 0.02) while those of roots ranged from 0.34 yr-1 (SE= 0.03) to 0.47 yr-1 (SE= 0.04). The decomposition of roots and leaves did not correspond with macroclimatic or regional climate data nor with initial C:N content of the plant material. In summary, invasion of snowberry into grassland does not appear to conflict with goals related to maintenance of SOC in Mixed Prairie. Current grazing management regimes also appear to be consistent with goals related to maintenance of existing SOC. Soil texture had a greater effect on SOC than management of the plant community. Decomposition of leaves and roots appeared to be controlled by many interacting factors such as plant organ type, collection year, study year (climate) and physical and/or chemical characteristics of the site.

Carbon dioxide is one of the major greenhouse gases being cycled by forests. Mature boreal forests are often carbon sinks, however, following disturbance, forests can become carbon sources. Three forest sites in central Saskatchewan burned in 1977 (F77 site), 1989 (F89 site), and 1998 (F98 site) were studied using eddy covariance to obtain measurements of the energy, carbon, and water budgets. Latent heat flux density increased gradually over time at F98 but remained lower than F77 and F89. Weekly net ecosystem production was lower at F98 than at F77 and F89. F77 lost 40 g C m-2 and 79 g C m-2 in 2004 and 2005, respectively. F89 gained 177 g C m-2, 113 g C m-2, and 88 g C m-2 in 2003, 2004, and 2005, respectively. F98 lost 5 g C m-2, 17 g C m-2, and 52 g C m-2 during these three years, respectively. / May 2007

Stable carbon isotope fractionation during methanogenesis is affected by the availability of substrates. The effects of different substrates on methanogen biomass, total lipid extract, biomarkers and methane under both abundant and limiting substrate conditions were studied. Methanosarcina barkeri was grown with methanol, acetate, trimethylamine (TMA) and H2/CO2, and carbon isotope fractionation in methane production was greatest with methanol, followed by H2/CO2, TMA and acetate. In contrast, biomass was isotopically lightest in M.barkeri grown on methanol, followed by TMA, H2/CO2 and acetate. Generally, fractionation was greater in cultures grown with abundant substrate availability as compared to those supplied with limiting substrate. During autotrophic growth, fractionation was greatest during slower growth for both methane and biomass production. The results of these fractionation studies under controlled laboratory conditions can be applied to the interpretation of isotopic signatures for methane and methanogen biomarkers, and ecological processes, in marine environments. Several hypersaline springs off the western shore of Lake Winnipegosis, MB support unique microbial mat communities. These low temperature springs contain water with a mean salinity as high as 6.1%. Studies were undertaken to contrast the anaerobic microbial communities of these springs, specifically the methanogens and sulphate-reducing bacteria (SRB), and their contributions to biogeochemical cycling in these mats. Comparisons of lipid profiles revealed changes in the proportions of the dominant fatty acids related to the amount of mat growth. Cultures of SRB and methanogens were established with six different substrates. Methanogenic cultures grew best on TMA and methanol, but could use formate, H2/CO2 and glycine betaine as well. In contrast, H2/CO2 was the preferred substrate of the SRB enrichment cultures, which were also able to use formate, but not TMA, the breakdown product of the compatible solute glycine betaine. Maximum methane production occurred at 5% salinity. The lipid composition of the mats, including methanogen biomarkers, and the results of the enrichments on different substrates and at different salinities, suggest that methanogenesis in these springs is supported by compatible solutes whereas sulphate reduction is linked to availability of hydrogen and formate. / February 2005