<p>Tailings are a fine-grained waste product produced during the metal recovery process. Tailings consist mostly of different silicates but also sulfides (e.g. pyrite), since 100 % metal recovery is not possible. Freshly processed tailings are deposited in large impoundments. If the mine tailings in the impoundments are exposed to water and oxygen, the sulfides will oxidize and release acidity and metals such as Fe, Cu, Zn, and Pb. The sulfide mineral oxidation reactions are catalyzed by sulfur and iron oxidizing bacteria (principally <i>Acidithiobacillus ferrooxidans</i>) that oxidize ferrous iron to ferric iron, which then oxidizes pyrite. When the leachate produced by this process discharges from the impoundment, it is called acid mine drainage, which may lead to the pollution of adjacent streams and lakes.</p><p>The intention with this thesis is to investigate and quantify mineral weathering processes and element release rates occurring in water-saturated and soil-covered sulfidic mine tailings. The study was performed in different batch and column experiments in room temperature and in the laboratory. The batch experiments were conducted for ca. three months and investigated: a) microbial and abiotic sulfide oxidation in freshly processed tailings under oxic conditions at pH 2-3 and pH 8, b) microbial oxidation of pure pyrite grains at pH 2-3 under different oxygen concentrations ranging from anoxic to oxic conditions. The column experiments, consisting of unoxidized tailings in water-saturated columns, were conducted for up to three years. In these experiments, an oxygen-saturated solution was continually pumped into the column inlet, and investigated: a) differences in oxidation rates between tailings of two different grain sizes, b) factors affecting element discharge rates, acid neutralization, and sulfide oxidation, c) the effect of ions released in a soil cover on release rates in the tailings.</p><p>Sulfide oxidation processes within the batch experiments were limited by surface kinetics. The microbial oxidation of pure pyrite at atmospheric conditions produced the most rapid rate, while the microbial oxidation of pure pyrite at anoxic conditions was slower by 1.8 orders of magnitude. Microbial and abiotic oxidation of pyrite in freshly-processed tailings resulted in pyrite oxidation rates that were intermediate between these two extremes. The results from the microbial experiments with pure pyrite indicated a positive correlation between the concentration of dissolved oxygen, ferric iron and bacterial cells (at a total cell concentration > 10⁶ cells/mL and a dissolved oxygen concentration ≥ 13.2 µM), which implies an interdependence of these factors. The results from these batch experiments support the indirect mechanism for microbial oxidation by the ferric oxidation pathway. Pyrite oxidation rates estimated from the batch experiments may be comparable with oxidation rates in the unsaturated zone and at the groundwater table in a tailings impoundment.</p><p>Acid neutralization reactions in the column experiments resulted in the release of base cations to the column leachate. Calcite was the most important neutralizing mineral despite that it was only present in minor amounts in the tailings. It was confirmed that acidity forced the calcite dissolution. Element release rates in the column experiments were controlled by the availability of dissolved oxygen, which was a function of the water flow rate into the column. These column experiments also showed that the results are comparable with results from field studies, justifying the use of column experiments to study processes within tailings impoundments.</p>

Tailings are a fine-grained waste product produced during the metal recovery process. Tailings consist mostly of different silicates but also sulfides (e.g. pyrite), since 100 % metal recovery is not possible. Freshly processed tailings are deposited in large impoundments. If the mine tailings in the impoundments are exposed to water and oxygen, the sulfides will oxidize and release acidity and metals such as Fe, Cu, Zn, and Pb. The sulfide mineral oxidation reactions are catalyzed by sulfur and iron oxidizing bacteria (principally Acidithiobacillus ferrooxidans) that oxidize ferrous iron to ferric iron, which then oxidizes pyrite. When the leachate produced by this process discharges from the impoundment, it is called acid mine drainage, which may lead to the pollution of adjacent streams and lakes. The intention with this thesis is to investigate and quantify mineral weathering processes and element release rates occurring in water-saturated and soil-covered sulfidic mine tailings. The study was performed in different batch and column experiments in room temperature and in the laboratory. The batch experiments were conducted for ca. three months and investigated: a) microbial and abiotic sulfide oxidation in freshly processed tailings under oxic conditions at pH 2-3 and pH 8, b) microbial oxidation of pure pyrite grains at pH 2-3 under different oxygen concentrations ranging from anoxic to oxic conditions. The column experiments, consisting of unoxidized tailings in water-saturated columns, were conducted for up to three years. In these experiments, an oxygen-saturated solution was continually pumped into the column inlet, and investigated: a) differences in oxidation rates between tailings of two different grain sizes, b) factors affecting element discharge rates, acid neutralization, and sulfide oxidation, c) the effect of ions released in a soil cover on release rates in the tailings. Sulfide oxidation processes within the batch experiments were limited by surface kinetics. The microbial oxidation of pure pyrite at atmospheric conditions produced the most rapid rate, while the microbial oxidation of pure pyrite at anoxic conditions was slower by 1.8 orders of magnitude. Microbial and abiotic oxidation of pyrite in freshly-processed tailings resulted in pyrite oxidation rates that were intermediate between these two extremes. The results from the microbial experiments with pure pyrite indicated a positive correlation between the concentration of dissolved oxygen, ferric iron and bacterial cells (at a total cell concentration &gt; 106 cells/mL and a dissolved oxygen concentration ≥ 13.2 µM), which implies an interdependence of these factors. The results from these batch experiments support the indirect mechanism for microbial oxidation by the ferric oxidation pathway. Pyrite oxidation rates estimated from the batch experiments may be comparable with oxidation rates in the unsaturated zone and at the groundwater table in a tailings impoundment. Acid neutralization reactions in the column experiments resulted in the release of base cations to the column leachate. Calcite was the most important neutralizing mineral despite that it was only present in minor amounts in the tailings. It was confirmed that acidity forced the calcite dissolution. Element release rates in the column experiments were controlled by the availability of dissolved oxygen, which was a function of the water flow rate into the column. These column experiments also showed that the results are comparable with results from field studies, justifying the use of column experiments to study processes within tailings impoundments.

No description available.

Modern mines require systems that quickly deliver backfill to support the rock mass surrounding underground openings. Cemented Paste Backfill (CPB) is one such backfilling method, but concerns have been raised about CPB’s liquefaction susceptibility especially when the material has just been placed, and if it is exposed to earthquakes or large mining induced seismic events. Conventional geotechnical earthquake engineering for surface structures is now relatively advanced and well accepted, and so the objective of this thesis is to consider how that framework might be extended to assess the liquefaction potential of CPB. Seismic records were analyzed for earthquakes and for large mining induced events. Important seismological trends were consistent for rockbursts and earthquakes when the signals were recorded at distances as proximate as one kilometre, suggesting that the conventional earthquake engineering approach might plausibly be adapted for such design situations. For production blasts and for more proximate locations to rockbursts, much higher frequencies dominate and therefore new design methods may be required. Monotonic triaxial tests conducted on normally consolidated uncemented mine tailings demonstrated that the material is initially contractive up to a phase transition point, beyond which dilation occurs. Most importantly the material never exhibits unstable strain softening behaviour in compression, and only temporary or limited liquefaction in extension. The addition of 3% binder results in initial sample void ratios that are even higher than their uncemented counterparts, and yet the material friction is slightly enhanced when tested at 4 hours cure. These results suggest that the flow liquefaction phenomenon commonly associate with undrained loose sand fills will not occur with paste backfill. Cyclic triaxial test results analyzed in terms of number of cycles to failure for a given cyclic stress ratio exhibited a trend consistent with previous tests on similar materials. However, the addition of 3% binder and testing at 4 hours cure resulted in an order of magnitude larger number of cycles to failure – a surprising and dramatic increase, suggesting good resistance of the material to cyclic mobility. Future research is recommended to build on these results and develop more robust methods for liquefaction assessment of CPB.

Modern mines require systems that quickly deliver backfill to support the rock mass surrounding underground openings. Cemented Paste Backfill (CPB) is one such backfilling method, but concerns have been raised about CPB’s liquefaction susceptibility especially when the material has just been placed, and if it is exposed to earthquakes or large mining induced seismic events. Conventional geotechnical earthquake engineering for surface structures is now relatively advanced and well accepted, and so the objective of this thesis is to consider how that framework might be extended to assess the liquefaction potential of CPB. Seismic records were analyzed for earthquakes and for large mining induced events. Important seismological trends were consistent for rockbursts and earthquakes when the signals were recorded at distances as proximate as one kilometre, suggesting that the conventional earthquake engineering approach might plausibly be adapted for such design situations. For production blasts and for more proximate locations to rockbursts, much higher frequencies dominate and therefore new design methods may be required. Monotonic triaxial tests conducted on normally consolidated uncemented mine tailings demonstrated that the material is initially contractive up to a phase transition point, beyond which dilation occurs. Most importantly the material never exhibits unstable strain softening behaviour in compression, and only temporary or limited liquefaction in extension. The addition of 3% binder results in initial sample void ratios that are even higher than their uncemented counterparts, and yet the material friction is slightly enhanced when tested at 4 hours cure. These results suggest that the flow liquefaction phenomenon commonly associate with undrained loose sand fills will not occur with paste backfill. Cyclic triaxial test results analyzed in terms of number of cycles to failure for a given cyclic stress ratio exhibited a trend consistent with previous tests on similar materials. However, the addition of 3% binder and testing at 4 hours cure resulted in an order of magnitude larger number of cycles to failure – a surprising and dramatic increase, suggesting good resistance of the material to cyclic mobility. Future research is recommended to build on these results and develop more robust methods for liquefaction assessment of CPB.

A lot of mine waste rock and tailings arise from all mining processes and have to be stored in an appropriate way. Tailings are deposited in impoundments retained by tailings dams. The objective of tailings dams is to retain the slurry from the mining process and in that way prevent spill into the surroundings that might be harmful for the environment. Tailings dams are often constructed as staged embankments so that construction costs and demand of materials are spread more evenly over the period of deposition. The objective of this thesis has been to compile information about and evaluate events at Swedish tailings dams and also to develop a collective database for all Swedish mining companies for all tailings dams and all events that occur at tailings dams. Information about 60 events at Swedish tailings dams has been gathered and evaluated. The evaluation has been performed by comparison between and analysis of individual parameters and also by use of a multivariate statistical method called PLS. The statistical analysis shows a decrease in the numbers of events during the last five years, which indicates improved dam safety within the mining industry. The analysis also shows that severe events and the human factor might be related when it comes to the initiating cause of the event. Further relations between the parameters and the severity of the events can be seen from the PLS-analysis, for example that low and short tailings dams to a greater extent are subjected to severe events. To be able to draw more reliable conclusions further studies with a more complete basic data are needed. This work has shown a need of a collective database within the Swedish mining industry for tailings dams and occurring events at tailings dams so that more complete basic data could be obtained for future studies. A structure for such a database has been developed in Microsoft Access 2000. The aim of the database is to facilitate feedback within the mining industry and to gather comprehensive data for future statistical evaluations. / Vid alla gruvprocesser skapas stora mängder restprodukter i form av gråberg och anrikningssand som måste tas om hand på lämpligt sätt. Anrikningssanden deponeras tillsammans med vatten från gruvprocessen i magasin omgärdade av dammvallar, s.k. gruvdammar. Gruvdammar har som syfte att hålla kvar anrikningssand och vatten och måste vara stabila så att de skyddar omgivningen från utsläpp av anrikningssand som skulle kunna vara skadligt för miljön. En gruvdamm byggs ofta upp i etapper eftersom byggkostnaderna och behovet av dammfyllnadsmaterial då sprids över tiden. Syftet med arbetet har varit att sammanställa och utvärdera händelser vid svenska gruvdammar samt att utforma ett för gruvindustrin gemensamt dammregister och felrapporteringssystem. 60 händelser vid svenska gruvdammar har sammanställts och utvärderats. Utvärderingen har genomförts dels genom att enskilda parametrar jämförts och analyserats och dels med hjälp av den multivariata analysmetoden PLS. Den statistiska analysen visar på en minskning i antal händelser under de senaste fem åren, vilket tyder på ett förbättrat dammsäkerhetsarbete inom gruvindustrin. Analysen har kunnat uppvisa ett samband mellan allvarliga händelser och den mänskliga faktorn när det gäller vad det är som initierat händelserna. Genom PLS-analysen har ytterligare samband mellan de undersökta parametrarna och allvarlighetsgraden av händelserna kunnat utläsas, bl.a. visar analysen att låga och korta dammar i större utsträckning drabbas av allvarliga händelser jämfört med höga och långa dammar. För att säkra slutsatser ska kunna dras krävs dock vidare studier med ett mer komplett statistiskt underlag. Examensarbetet har påvisat ett behov av ett branchgemensamt damm- och felrapporteringsregister för att ett mer komplett underlag ska kunna erhållas i framtiden. En färdig databasstruktur för ett sådant dammregister och felrapporteringsregister för svenska gruvdammar har utformats. Databasen är uppbyggd i Microsoft Access 2000 och är tänkt att underlätta erfarenhetsåterföring inom branschen samt att ge ett underlag för framtida statistiska undersökningar.

Extensive research conducted over the last decade has demonstrated the great potential of phytostabilization for the reclamation of abandoned mine tailing piles. The right combination of plant species and soil amendments can facilitate the growth of a permanent vegetative cover on the tailings that will help minimize the mobilization of metal-bearing particles by means of wind dispersion and water erosion. Despite previous research efforts, the diversity and potential role of microbial populations inhabiting the root zone of the plants on the stabilization of the metal(loid) contaminants remains mostly unresolved. The study presented in this dissertation represents one of the first comprehensive efforts aimed to understand the ecology and dynamics of microbial communities colonizing both bulk and rhizosphere tailings during phytostabilization as an initial step towards elucidating the role of microbes in the stabilization of metal(loid) contaminants during the remediation treatment. This study was divided into two main projects: (1) the first aimed to monitor the temporal variations in functional and taxonomic diversity of prokaryotic populations in acid-generating metalliferous mine tailings during phytostabilization to determine how they respond to and/or influence changes in environmental parameters and to identify key patterns in their composition that may serve as bioindicators of soil health and the success of the remediation treatment; and (2) the second aimed to expand our understanding of the dynamics of root-associated bacterial, fungal and archaeal communities during mine tailing phytostabilization and how the dynamic behavior of the communities correspond to the growth of plants, the addition of soil amendments, and fluctuations in environmental conditions. The results presented here demonstrate that different microbial groups respond differently to changes in environmental conditions during phytostabilization, suggesting that by monitoring the behavior of specific microbial groups in the systems (as bioindicators) we may be able to assess the effectiveness of the remediation treatment. Furthermore, the results from the taxonomic and functional analysis of the microbial communities served as the basis for the development of a model that explains the ecology and distribution of dominant microbial groups in the tailings that may significantly contribute to the oxidation of iron-sulfides, the production of acid mine drainage, and to facilitate plant establishment and survival during phytostabilization.

The first part of the thesis investigates the enhancement of fly ash-based geopolymer with alkali pretreated sweet sorghum fiber. The unconfined compression, splitting tensile and flexural tests were conducted to investigate the mechanical properties of geopolymer composite. The results indicate that the inclusion of sweet sorghum fiber slightly decreases the unconfined compressive strength (UCS), however, the splitting tensile and flexural strengths as well as the post-peak toughness increase with the fiber content up to 2% and then decrease thereafter. A durability test program containing 10 wet/dry cycles was performed to evaluate the long-term performance of the geopolymer composite related to wet/dry cycling. The results indicate that both the UCS and the splitting tensile strength of the geopolymer composite progressively decrease with the number of wet/dry cycles. The second part of the thesis investigates the utilization of biopolymers to stabilize MT for dust control. First, a fall cone method was adopted to evaluate the Atterberg limits and undrained shear strength of MT stabilized with biopolymers. The results indicate that the inclusion of biopolymers increases both the liquid limit and the undriained shear strength of MT. Two new equations are proposed for predicting the undrained shear strength of MT based on liquid limit and water content, and liquidity index. Second, an experimental program including moisture retention, wind tunnel and surface strength tests was performed to evaluate the effectiveness of biopolymer stabilization for dust control. The results indicate that biopolymers are effective in enhancing the moisture retention capacity, improving the dust resistance, and increasing the surface strength of MT. Third, a durability test program containing 10 wet/dry cycles was applied to MT samples treated with biopolymer solutions of different concentrations. The results show that the dust resistance of MT samples progressively decreases with the number of wet/dry cycles. Finally, experimental and numerical studies on the unconfined compressive strength (UCS) of MT stabilized with biopolymer were carried out. It is found that inclusion of biopolymer into MT favors the increase of adhesion between MT particles and thus the increase of the UCS of MT.

No description available.

Three experiments were conducted to examine restoration of disturbed land in Arizona. The first experiment attempted to revegetate abandoned farmland by direct seeding native seeds and using various soil preparation techniques, amendments, and weeding of Salsola iberica. Only irrigation and weeding had a significant effect on seed germination and canopy cover. Irrigation increased plant cover on plots, but weeds dominated the cover. A seedbank study conducted near the end of the second growing season found the soil was dominated by weeds and contained few viable native seeds. The results illustrate the difficulty of establishing native plants on abandoned desert farmland due to the dominance of weedy species, the presence of salts in the soil, and the lack of adequate soil moisture.The second experiment, a lysimeter study, tested the efficacy of different evapotranspiration (ET) soil cover designs for stabilization of acidic copper mine tailing piles. The study evaluated the effectiveness of capillary barriers (CB) to contain the waste found in tailings and different plants to revegetate the piles. The ET covers reduced infiltration of water into tailings. Copper concentrations increased significantly in plant tissue grown on the ET covers compared to plants grown in the greenhouse. Plants did not exhibit signs of phytotoxicity and concentrations were below levels toxic to all domestic animals except sheep. The CB did not reduce water infiltration into the tailings or upward migration of copper into the soil cover. Vegetation is vital to an effective ET cover. A mix of transplanted shrubs and seeded grasses and forbs establish long-term, sustainable vegetation.The third experiment examined the influence of biosolids on the bacterial communities within mine tailings by bacterial counts and bacterial diversity. The diversity of neutral copper mine tailings two weeks after biosolid application was compared with that of desert soil via cloning and sequencing of PCR amplified community 16S rRNA. Culturable heterotrophic plate counts (HPC) increased following biosolid addition. Total direct counts exceeded HPC by approximately two orders of magnitude. Overall, biosolid-amended tailings contained large numbers of bacteria diverse in nature and with many of the traits of normal desert soil bacterial communities.