This paper links two applications of Extreme Value Theory (EVT) to analyze Taiwanese financial markets: 1. computation of Value at Risk (VaR) and Expected Shortfall (ES) 2. estimates of cross-market dependence under extreme events. Daily data from the Taiwan Stock Exchange Capitalization Weight Stock Index (TAIEX) and the foreign exchange rate, USD/NTD, are employed to analyze the behavior of each return and the dependence structure between the foreign exchange market and the equity market. In the univariate case, when computing risk measures, EVT provides us a more accurate way to estimate VaR. In bivariate case, when measuring extremal dependence, the results of whole period data show the extremal dependence between two markets is asymptotically independent, and the analyses of subperiods illustrate that the relation is slightly dependent in specific periods. Therefore, there is no significant evidence that extreme events appeared in one market (the equity market or the foreign exchange market) will affect another in Taiwan.