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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
1

Pyrolytic study of para-methoxystyrylarenes, 2-azidocyclohexanone and 6-arylfulvenes

Chu, Li-Tse 22 July 2005 (has links)
1. FVP of para-methoxystyrylarenes (5a-c) all gave the corresponding phenol products 21a-c. FVP of 5a and 5c also gave tricyclic products 22 and 23, respectively, which all included indene structure. But FVP of 5b gave naphthalene by ring opening of the furan. 2. FVP of 2-azidocyclohexanone (70) gave four products 83-86, and product 84 was a new compound. We provided a method to synthesize a new tricyclic product by one step. 3. Pyrolytic study of five 6-arylfulvenes (78-82). The products from FVP of 78-82 and mechanisms to account for their products will be discussed. FVP of compounds 79 and 80 gave naphthalene (96) and indene (97), respectively, by elimination of either a S or a CO molecule.

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