Capillary electrochromatography (CEC) is a rapidly developing liquid chromatographic technique in which electroosmotic flow (EOF) is used to propel mobile phase through the chromatographic column. The use of EOF results in reduced band dispersion when compared with pressurised flow, but narrow capillaries are required to avoid dispersion due to heating that arises from the required application of high electrical potentials. Measurement of UV absorbance in these narrow capillaries is therefore relatively insensitive, demanding improved detection methods. This work presents an alternative strategy that is based on the combination of ion trap accumulation with time-of-flight mass spectrometry. Electrospray is most often used to transfer analytes from solution to the gas phase, concomitant with ionisation, when interfacing CEC to mass spectrometry. The small volumetric flow rates encountered in CEC, however, raise the possibility of other types of interface being effective. The work presented here describes the development of a novel interface in which a pulsed IR laser is used to vaporise chromatographic eluent, followed by ionisation using a pulsed UV laser. Vaporisation and ionisation both occur within the ion trap to remove the possibility of transmission losses. Ionisation laser wavelength is varied to impart a degree of selectivity. The presence of vaporised solvent and analyte ions inside the trap offers the possibility of performing ion-molecule chemistry. In developing this instrument, the electrochromatographic column was separated from the interface by an electrically grounded junction and a transfer capillary. To preserve chromatographic efficiency, the fluid dynamics of this junction between the column and the transfer capillary were investigated both computationally and experimentally. Simulations of the fluid dynamics of the junction are presented. In order to test the interface without the intermittent, chromatographic, delivery of analyte, a continuous leak inlet was employed. The performance of the instrument was evaluated with polycyclic aromatic hydrocarbons because they are important environmental pollutants and because they are amenable to laser ionisation at 266 nm. Expressed as a number of theoretical plates per metre, an average chromatographic efficiency of 95,000 was obtained with a test mixture that consisted of acenaphthene, biphenyl, fluorene, naphthalene and phenanthrene. Furthermore, using the leak inlet, naphthalene was detected as a 100 nM solution in acetonitrile.

The Large Hadron Collider started operation this year, 2008. LHCb is a precision heavy-flavour experiment at this collider. The precision of LHCb is greatly aided by the LHCb Ring Imaging Cherenkov system for the separation and identification of charged hadrons. This system uses pixel Hybrid Photon Detectors, an innovative new technology for single photon imaging. The simulation and testing of these photon detectors are reported and discussed. The photodetectors were measured to have reached or exceeded the specifications in key areas. In particular, the detector quantum efficiencies far exceed expectations, by a relative 27 %. The precision of LHCb will be used to examine CP-violation and rare decays of B-mesons. A key part of the physics programme will be a measurement of the CP-violating flavour specific asymmetry in neutral B-meson mixing. This asymmetry is expected to be very small in the Standard Model, of order 10-4, however it is very sensitive to new physics, which can increase the asymmetry dramatically. We present an improved event selection and a novel method to control systematics. This will enable us to make a world-leading measurement of this parameter in one nominal year of data taking (2 fb-1).

This thesis considers the theory and calculations of image formation mechanisms for various modes of three-dimensional imaging in aberration-corrected scanning transmission electron microscopy. Discrete tomography is used to determine and refine the three-dimensional structure of molecular nanowire bundles. The structure determination is expedited by the use of annular dark-field imaging, an incoherent imaging mode which provides directly interpretable images. The development of spherical aberration correctors and the subsequent reduction in probe sizes, including the depth of field, has made optical depth sectioning a feasible technique. The localisation in three dimensions of substitutional impurity atoms in zone-axis imaging is discussed. Both the channelling of the probe and the pre-focussing effect of the atomic column play an important role in determining the depth response of the impurity atom. Interband scattering within a sample is shown to be influential in imaging crystals containing dislocations and optical depth sectioning is explored as a possible option for overcoming surface relaxation effects in the imaging of screw dislocations end-on. The possibility of extending the optical depth sectioning approach using aberration-corrected scanning confocal electron microscopy is discussed. The coherent and incoherent imaging modes, involving elastically and inelastically scattered electrons respectively, are investigated.

Ions trapped in Paul traps provide a system which has been shown to exhibit most of the properties required to implement quantum information processing. In particular, a two-dimensional array of ions has been shown to be a candidate for the implementation of quantum simulations. Microfabricated surface geometries provide a widely used technology with which to create structures capable of trapping the required two-dimensional array of ions. To provide a system which can utilise the properties of trapped ions a greater understanding of the surface geometries which can trap ions in two-dimensional arrays would be advantageous, and allow quantum simulators to be fabricated and tested. In this thesis I will present the design, set-up and implementation of an experimental apparatus which can be used to trap ions in a variety of different traps. Particular focus will be put on the ability to apply radio-frequency voltages to these traps via helical resonators with high quality factors. A detailed design guide will be presented for the construction and operation of such a device at a desired resonant frequency whilst maximising the quality factor for a set of experimental constraints. Devices of this nature will provide greater filtering of noise on the rf voltages used to create the electric field which traps the ions which could lead to reduced heating in trapped ions. The ability to apply higher voltages with these devices could also provide deeper traps, longer ion lifetimes and more efficient cooling of trapped ions. In order to efficiently cool trapped ions certain transitions must be known to a required accuracy. In this thesis the 2S1/2 → 2P1/2 Doppler cooling and 2D3/2 → 2D[3/2]1/2 repumping transition wavelengths are presented with a greater accuracy then previous work. These transitions are given for the 170, 171, 172, 174 and 176 isotopes of Yb+. Two-dimensional arrays of ions trapped above a microfabricated surface geometry provide a technology which could enable quantum simulations to be performed allowing solutions to problems currently unobtainable with classical simulation. However, the spin-spin interactions used in the simulations between neighbouring ions are required to occur on a faster time-scale than any decoherence in the system. The time-scales of both the ion-ion interactions and decoherence are determined by the properties of the electric field formed by the surface geometry. This thesis will show how geometry variables can be used to optimise the ratio between the decoherence time and the interaction time whilst simultaneously maximising the homogeneity of the array properties. In particular, it will be shown how the edges of the geometry can be varied to provide the maximum homogeneity in the array and how the radii and separation of polygons comprising the surface geometry vary as a function of array size for optimised arrays. Estimates of the power dissipation in these geometries will be given based on a simple microfabrication.

Trapped ions are currently one of the most promising architectures for realising the quantum information processor. The long lived internal states are ideal for representing qubit states and, through controlled interactions with electromagnetic radiation, ions can be manipulated to execute coherent logic operations. In this thesis an experiment capable of trapping Yb+ ions, including 171Yb+, is presented. Since ion energy can limit the coherence of qubit manipulations, characterisation of an ion trap heating rate is vital. Using a trapped 174Yb+ ion a heating rate consistent with previous measurements of other ion species in similar ion traps is obtained. This result shows abnormal heating of Yb+ does not occur, further solidifying the suitability of this species for quantum information processing. Efficient creation, and cooling of trapped ions requires exact wavelengths for the ionising, cooling and repump transitions. A simple technique to measure the 1S0 ↔ 1P1 transition wavelengths, required for isotope selective photoionisation of neutral Yb, is developed. Using the technique new wavelengths, accurate to 60 MHz, are obtained and differ from previously published results by 660 MHz. Through a simple modification the technique can also predict Doppler shifted transition frequencies, which may be required in non-perpendicular atom-laser interactions. Using trapped ions, the 2S1=2 ↔ 2P1/2 Doppler cooling and 2D3/2 ↔ 2D[3/2]1/2 repump transitions are also measured to a greater accuracy than previously reported. Many experiments require wavelengths which can only be obtained using complex expensive laser systems. To remedy this a simple cost effective laser is developed to enable laser diodes to be operated at sub zero temperatures, extending the range of obtainable wavelengths. Additional diode modulation capabilities allow for the manipulation of atoms and ions with hyperfine structures. The laser is shown to be suitable for manipulating Yb+ ions by cooling a diode from 372 nm to 369 nm and simultaneously generating 2.1 GHz frequency sidebands. Coherent manipulation such as arbitrary qubit rotations, motional coupling and ground state cooling, are required for trapped ion quantum computing. Two photon stimulated Raman transitions are identified as a suitable technique to implement all of these requirements and an investigation into implementing this technique with 171Yb+ is conducted. The possibility of exciting a Raman transition via either a dipole or quadrupole transitions in 171Yb+ is analysed, with dipole transitions preferred because quadrupole transitions are found to be too demanding experimentally. An inexpensive setup, utilising a dipole transition, is designed and tested. Although currently limited the setup shows potential to be an inexpensive, high fidelity method of exciting a Raman transition.

This thesis is concerned with the design and realisation of components for a new state of the art 94GHz Electron Spin Resonance (ESR) spectrometer capable of operating in both pulsed and CW modes. The complete spectrometer is designed to provide phase coherent 1kW peak power sub-nanosecond π/2 pulses having variable duration and repetition rate. The mm-wave response of a paramagnetic sample to these pulses is detected with a superheterodyne detector. Such a system would offer a step change in performance, promising unprecedented resolution and sensitivity. These aims should be compared with the performance of commercial (Bruker) instruments capable of delivering 200mW 30ns π/2 pulses. For this type of system, both the long term (thermal) and short term (phase) stability of oscillators and sources employed are extremely important. Consideration of phase noise, frequency, tunability and power output shows that multiplied sources offer substantial benefits compared to fundamental sources. A delay line discriminator method of phase noise measurement, suitable for use with the low frequency oscillators is described and implemented. This is extended to 94GHz using a down convertor with a quasi-optically stabilised Gunn oscillator. These tools are used to select an optimum oscillator-multiplier combination to produce a low noise 94GHz source. Anew method of pulse generation, which has produced +23dBm peak power 250ps rectangular and 115ps Gaussian envelope phase coherent pulses, is described. These are believed to be the shortest phase coherent pulses at 94GHz available. This system will be used to provide ns pulses suitable for amplification to 1kW using a Klystron amplifier. A heterodyne detector has been constructed which employs the same oscillator/multiplier techniques identified above to produce the required local oscillator signal. It is demonstrated that by careful consideration of multiplication factors a system employing one variable and one fixed oscillator allows all the signals required in the spectrometer to maintain phase coherence. It is demonstrated that the complete demodulator responds to pulses on a ns time scale and has a noise temperature of 737K.

No description available.

No description available.

The Sun is of fundamental importance to life on earth and is studied by scientists from many disciplines. It exhibits phenomena on a wide range of observable scales, timescales and wavelengths and due to technological developments there is a continuing increase in the rate at which solar data is becoming available for study which presents both opportunities and challenges. Two satellites recently launched to observe the sun are STEREO (Solar TErrestrial RElations Observatory), providing simultaneous views of the SUN from two different viewpoints and SDO (Solar Dynamics Observatory) which aims to study the solar atmosphere on small scales and times and in many wavelengths. The STEREO and SDO missions are providing huge volumes of data at rates of about 15 GB per day (initially it was 30 GB per day) and 1.5 terabytes per day respectively. Accessing these huge data volumes efficiently at both high spatial and high time resolutions is important to support scientific discovery but requires increasingly efficient tools to browse, locate and process specific data sets. This thesis investigates the development of new technologies for processing information contained in multiple and overlapping images of the same scene to produce images of improved quality. This area in general is titled Super Resolution (SR), and offers a technique for reducing artefacts and increasing the spatial resolution. Another challenge is to generate 3D images such as Anaglyphs from uncalibrated pairs of SR images. An automated method to generate SR images is presented here. The SR technique consists of three stages: image registration, interpolation and filtration. Then a method to produce enhanced, near real-time, 3D solar images from uncalibrated pairs of images is introduced. Image registration is an essential enabling step in SR and Anaglyph processing. An accurate point-to-point mapping between views is estimated, with multiple images registered using only information contained within the images themselves. The performances of the proposed methods are evaluated using benchmark evaluation techniques. A software application called the SOLARSTUDIO has been developed to integrate and run all the methods introduced in this thesis. SOLARSTUDIO offers a number of useful image processing tools associated with activities highly focused on solar images including: Active Region (AR) segmentation, anaglyph creation, solar limb extraction, solar events tracking and video creation.

In this thesis the control of ultrafast (10⁻¹³ s) optical pulses used for metrological applications has been investigated. Two different measurement set-ups have been considered, both based around the `pump-probe' technique, where an optical pulse is divided into two parts, one to `pump' or excite a physical system of interest, the other to `probe' or measure the outcome. In both cases the measurement uses electro-optic sampling (EOS), where an electric field is measured by detecting changes in the optical probe pulse polarisation after interaction with the field. In the first study, a method for wavelength metrology in the terahertz (THz) region has been demonstrated by producing an optical pulse shaper and genetic algorithm to control pump pulses and so indirectly influence the THz spectra they generate. In the second study an OPO (optical parametric oscillator) has been developed to provide ultrafast optical pulses for the generation of < 100 fs electrical pulses for metrology using quantum interference control (QUIC). QUIC electrical signals have been demonstrated successfully by charge accumulation measurements and the QUIC electrical pulse temporally measured using EOS, though the low signal levels due to power restrictions mean the QUIC electrical pulse is unsuitable for metrology at this time. Finally, a portable optical pulse measurement device based around frequency-resolved optical gating (FROG) has been designed, built and tested. This has been shown to be capable of retrieving amplitude and phase information in both the temporal and spectral domains for optical pulses as short as 20 fs duration. The ability to characterise shaped pulses also has been demonstrated successfully, with the requirements for full automation identified.