The value of Remote Condition Monitoring for the real-time evaluation of the structural integrity of critical components is undeniable. Fibre-reinforced polymer composites are a class of materials which offer significant advantages over conventional metal alloys used for manufacturing load bearing structures in cases where weight and/or energy consumption need to be kept to a minimum, for example automotive and aerospace applications. This is due to the excellent strength to weight ratio that FRPCs exhibit. However, their strongly anisotropic microstructure of poses significant challenges for Non-Destructive Evaluation of the actual structural health of components made from such materials. Acoustic Emission is a passive condition monitoring technique based on the detection of elastic stress waves emitted when damage evolves in a structure. Conventional piezoelectric AE sensors need to be surface-mounted as their embedding in FRPCs is impractical. Fibre Optic Acoustic Emission Sensors (FOAES) offer a distinct advantage since they are light weight, have small size and can be effectively embedded in composite laminates. Moreover, they can be multiplexed with the entire structure being monitored more effectively. This study has focused in the evaluation of the manufacturing process and characterisation of FOAES. Comparison of their performance with conventional commercial sensors was carried out.

Super-resolution mapping is becoming an increasing important technique in remote sensing for land cover mapping at a sub-pixel scale from coarse spatial resolution imagery. The potential of this technique could increase the value of the low cost coarse spatial resolution imagery. Among many types of land cover patches that can be represented by the super-resolution mapping, the prediction of patches smaller than an image pixel is one of the most difficult. This is because of the lack of information on the existence and spatial extend of the small land cover patches. Another difficult problem is to represent the location of small patches accurately. This thesis focuses on the potential of super-resolution mapping for accurate land cover mapping, with particular emphasis on the mapping of small patches. Popular super-resolution mapping techniques such as pixel swapping and the Hopfield neural network are used as well as a new method proposed. Using a Hopfield neural network (HNN) for super-resolution mapping, the best parameters and configuration to represent land cover patches of different sizes, shapes and mosaics are investigated. In addition, it also shown how a fusion of time series coarse spatial resolution imagery, such as daily MODIS 250 m images, can aid the determination of small land cover patch locations, thus reducing the spatial variability of the representation of such patches. Results of the improved HNN using a time series images are evaluated in a series of assessments, and demonstrated to be superior in terms of mapping accuracy than that of the standard techniques. A novel super-resolution mapping technique based on halftoning concept is presented as an alternative solution for the super-resolution mapping. This new technique is able to represent more land cover patches than the standard techniques.

The object of this thesis is to form an understanding of the origin of the problems associated with proton-exchanged waveguides, and to investigate possible solutions. Chapter 1 gives a brief introduction to the properties of lithium niobate, and discusses the methods available for fabricating optical waveguides in the bulk material, with particular emphasis on waveguide fabrication by the proton-exchange process. Some of the devices which have been fabricated by proton-exchange are discussed. The problems associated with proton-exchanged waveguides are reviewed. Chapter 2 deals with the physical and chemical characterisation of proton-exchanged waveguides fabricated using neat benzoic acid melts. The extent of proton-exchange is determined as a function of fabrication time and temperature using optical waveguide prism-coupler measurements, infrared absorption spectroscopy, and atomic absorption spectroscopy. Chapter 3 is concerned with the problem of waveguide mode-index stability. Using a hydrogen isotopic-exchange reaction, the extent of which is obsrved via infrared absorption spectroscopy, information on the (room-temperature) mobility of protons within the guiding layer is obtained for waveguides fabricated using neat benzoic acid melts. The recently reported process of fabricating waveguides in lithium niobate by deuterium-exchange is investigated. The behaviour of proton-exchanged and deuterium-exchanged waveguides with respect to reaction with atmospheric water vapour is investigated, and the optical properties of deuterium-exchanged waveguides are studied. In Chapter 4, a study of annealed and dilute-melt proton-exchanged waveguides is presented. It is shown, using prism-coupler measurements and infrared absorption spectroscopy, that ennealed and dilute-melt waveguides can have very similar optical properties, depending on the amount of annealing and the lithium benzoate mole-fractions used. The extent of proton-exchange is determined with time (between 215oC and 235oC) for dilute-melt waveguides produced using lithium benzoate mole-fractions of up to 1.1%. Isotopic-exchange in annealed and dilute-melt waveguides is also investigated, both at room-temperature and at temperatures commonly used for annealing. A possible explanation for the poor optical properties of (neat-melt) proton-exchanged waveguides is given. Chapter 5 deals with a study of propagation losses (using the two-prism method) and the electro-optic effect in x- and z-cut proton-exchanged waveguides. Measurements of r33 (in proton-exchanged waveguides) and r22 (in titanium-indiffused waveguides) are carried out using an external interferometric method designed by the author. The results of Chapter 4 are used to establish a method by which losses below 0.5dB/cm and a substantially restored electro-optic effect can be achieved (using a combination of dilute-melt fabrication with post-exchange annealing). Prior to the waveguide measurements, the bulk electro-optic effect is investigated for congruent, incongruent, MgO-doped, and annealed (high-temperature) crystals. Finally, in Chapter 6, a summary of the thesis is presented, and suggestions for future work are given.

Non-destructive testing is an important field of research in many areas of industry and science. This field covers methods that test some property of an object while not impacting its future usefulness. This project is specifically interested in a method of NDE called Laser Doppler Vibrometry (LDV), which uses light to probe the motion of an object's surface. This thesis presents research into the possibility of developing a full-field LDV camera capable of measuring the vibration at a number of points across an object simultaneously. The approach chosen was to develop a single processing element which contained a light detector as well as the processing required to produce an output signal proportional to the vibration of the surface imaged by the element. This processing element, or pixel, could then be used to produce a full-field LDV camera capable of imaging an object's surface to provide vibration amplitude and frequency for a number of points across the whole surface simultaneously Some early work was carried out measuring the vibration of a piezoelectric target with a CMOS camera and the results were compared with theory. The method of processing chosen is called zero-crossing demodulation and a circuit was designed and simulated using this method. This circuit was then laid-out and a CMOS chip was fabricated with the pixel on it. The circuit was designed such that the different parts of it could be tested separately using electrical signals, and a number of electrical tests were performed to check how well the operation of the fabricated pixel compared with simulation. Using a laser interferometer the pixel was finally tested with real vibrating objects and compared with a commercial LDV.

Optical microresonators can form the basis of all-optical switching and control devices. The presented study is an exploration of the Transmission Line Modelling (TLM) method as a suitable candidate for designing optical microresonators. Chalcogenide glasses were identified as promising materials, with which to fabricate optical microresonators. The study presents the formulation of TLM in two dimensions to model nonmagnetic dielectric materials and a suitable computationally efficient yet flexible software design. Some methods for extracting spectral properties of resonators are compared and the modified difference Prony method was identified as a suitable tool to extract resonant frequencies and Q factors from a limited time signal. When applying TLM to microresonators of sub-wavelength dimensions it was understood that the method of discretisation plays an important role in accurately modelling microresonators. Two novel methods of discretisations -the same area method and the anti-aliasing method- were used to improve the accuracy significantly compared to existing mesh refinement techniques. Perfect matched layers (PMLs) were implemented to improve reflections from domain truncation using several methods. A Convolutional PML(CPML) was identified as the best, but it does not reach the efficiency of PMLs in the Finite Difference Time Domain (FDTD) method. Several frequency dependent refractive index models were proposed and implemented in TLM. A Tauc-Lorentz model was identified as the best fit to the experimental refractive index of three chalcogenide glasses, but a Sellmeier model with one term and a coefficient was efficient for TLM implementation. The main concern in the use of these models within TLM was shown to be the error arising due to mesh dispersion. Kerr nonlinear models were formulated and implemented in TLM and the models applied to the study of a waveguide junction. Compared to an equivalent implementation in a time domain beam propagation method, TLM models better represent the waveguide junction reflections.

The instrumentation and the developments presented in this thesis aim to address the challenges associated with in-service non-destructive testing of aeroengine components, imposed by severe restrictions on component accessibility. In-service non-destructive testing (NDT) is essential to ensure early detection of service-induced damage and prevent catastrophic failures of such safety-critical aeroengine components as turbine/compressor blades and disks, increasing the safety of operations and dramatically reducing the cost of engine changes. The main concern during their inspection is detection of fatigue cracking, typically initiated on the surface of the part. The application of inspection techniques used during overhaul to on-wing testing is restricted both by the complex, spatially-confined access to the components and the inaccessibility of the high-stress concentration surfaces in the full engine assembly. Two routinely-used techniques providing a solution to these challenges are the use of endoscopes for access and surface acoustic waves to inspect parts of the assembly. CHOTs are optically-activated ultrasonic transducers located on the surface of a sample, that use laser illumination to remotely generate and detect ultrasound, providing a non-contact wireless alternative to conventional piezoelectric transducers (PZTs). The benefits of optical activation are paired with fibre-optic light delivery in an endoscopic pulser -- a simple portable ultrasonic inspection system with flexible instrumentation, beneficial for testing hard-to-reach components in locations with limited access or hazardous environments. This thesis presents the instrumentation of the endoscopic pulser and the development of the self-adhesive portable CHOTs (SA CHOTs) to complement its potential field application by enabling transducer delivery to components in-service and application to large and curved parts, previously limited by laboratory-based direct on-sample CHOT fabrication. The developed transducers overcome frequent barriers for industrial adaptation of fully-optical inspection systems presented by the sample surface conditions such as reflectivity and roughness. The NDT capabilities of the CHOTs endoscopic pulser are demonstrated by performing detection of machined slots on controlled aluminium samples and representative industrial parts using 4--5 MHz surface acoustic waves. System capabilities for active structural health monitoring (SHM) as well as inspection of samples in motion are demonstrated. Although in its present configuration the size of the endoscope exceeds practical access requirements, the potential of the system for further development and miniaturisation is discussed.

Forest structure is the complex 3D arrangement of all components within the forest architecture. This includes stems, foliage, branches (the components of trees) but also includes non-tree components such as understorey shrubs and herbs. Understanding the structural components of forests is critical when considering forest ecosystems. The structure of a forest can affect functional and compositional characteristics such as productivity and species richness with structure being an important factor influencing animal-habitat associations. Structural characteristics of forests include the size distribution and spatial organisation of trees, and the horizontal and vertical density of objects within the understorey. Trees are the dominant feature of any forest, but the understorey is also very important when considering forest characteristics. Examining the links between the spatial distribution of understorey material and ecological parameters, such as diversity and productivity, has an important role in ecological studies. There are multiple field survey techniques that can be applied when collecting data for a forest survey. For a technique to be an effective survey tool it should be readily quantifiable, repeatable, cost-effective, easily assessed, ecologically meaningful and where possible not contain observer bias. Traditional methods of forest survey are very common as they offer reliable, low cost estimations of forest structural parameters such as diameter, height and understorey cover. Recent developments within 3D data collection using terrestrial laser scanning (TLS) have allowed foresters and ecologists to reproduce the structural parameters collected during traditional forest surveys. These developments have shown the usefulness of 3D data collection in assessing forest structure, but have focused on replicating existing forest metrics rather than developing new ones. For TLS to reach its full potential within the field of forest ecology, new metrics and indices need to be developed specifically for laser scan analysis. This study developed and tested new methods of forest survey, concentrating on understorey vegetation, using commercially available TLS. Results showed that these new techniques can provide novel structural assessments of the understorey layers of forests for use in forest ecology surveys, not available through traditional methods. Using a new index describing the vertical component of forest understorey, it was shown how the relationship between deer browsing and forest structure can be identified through feature extraction from laser scanning. The method developed required minimal manual processing and was applied to large data sets. The structural changes between high and low deer density sites were also observed through the creation of an understorey density profile. This method, specifically targeted at the lower layers of the understorey, successfully identified structural change at the decimetre level. Using microtopography estimates from understorey point clouds it was shown how understorey complexity corresponded with vegetation surfaces extracted through TLS. This suggests that correlation between understorey structure (and therefore habitat type) and the microtopography of vegetation surfaces may be used for detailed assessment of understorey structural characteristics utilising TLS. In addition to the development of novel analysis methods, new techniques for acquiring TLS data of forest understorey were examined. The use of a standardised methodology for temporal surveying, utilising a common digital terrain model and fixed ground control, as developed here, provides a framework from which further data can be acquired. This approach offers a relatively quick, efficient, non-destructive assessment of temporal change within forests. A novel method of forest survey utilising handheld mobile laser scanning (HMLS) was also tested, showing its potential to complement static TLS surveying by providing increased survey coverage and allowing point cloud processing to be considered for areas which are otherwise difficult to access.

The use of Mid-infrared (mid-IR) imagers has great potential for a number of applications in gas sensing and medical diagnostics, but so far for many of those non-defence fields it has been significantly limited by their high price tag. One of the reasons behind the great cost of mid-IR imagers is that most of them need to operate at cryogenic temperatures. Thanks to more than half a century of research, state-of-the-art mid-IR photodetectors have finally achieved premium detection performance without the need for cryogenic cooling. Some of them have even demonstrated very promising results, suggesting room temperature operation is on the horizon. As a result, the cost associated with cooling equipment has been significantly suppressed. However, most mid-IR imagers are still based on hybrid technologies needing a great number of die-level process steps and being prone to connection failure during thermal cycles. The high manufacturing cost this entails is also preventing a wider diffusion of mid-IR imagers. Currently, there is still a lack of an effective monolithic approach able to achieve low-cost mass production of mid-IR imagers in the same way as monolithic integration has been widely used for imagers working at visible wavelengths. This thesis presents a novel monolithic approach for making mid-IR imagers based on co-integration of mid-IR photodetectors with GaAs-based MESFETs on the same chip. The initial focus of the project was the development of the fabrication steps for delivery of prototype devices. In order to achieve monolithic fabrication of pixel devices made in either indium antimonide (InSb) or indium arsenide antimonide (InAsSb) on a gallium arsenide (GaAs) substrate, various highly controllable etch processes, both wet and dry etch based, were established for distinct material layers. Moreover, low temperature annealed Ohmic contacts to both antimonide-based materials and GaAs were used. The processing temperatures used never exceeded 180˚C, preventing degradation of photodetector performance after fabrication of transistors, thus avoiding well-known thermal issues of InSb fabrication. Furthermore, an intermediate step based on polyimide was developed to provide a smoothing section between the lower MESFET and upper photodetector regions of the pixel device. The polyimide planarisation enabled metal interconnects between the fabricated devices regardless of the considerable etch step ( > 6 µm) created after multiple mesa etches. Detailed electrical and optical measurements demonstrated that the devices were sensitive to mid-IR radiation in the 3 to 5 µm range at room temperature, and that each pixel could be isolated from its contacts by switching off the co-integrated MESFET. Following the newly developed fabrication flow, InSb-based mid-IR imaging arrays (in two sizes, 4×4 and 8×8) are presented here for the first time, with pixel addressing achieved by monolithically integrated GaAs MESFETs. By demonstrating real-time imaging results obtained from these array devices at room temperature, implementation of a new type of monolithic focal plane array for mid-IR imaging has been confirmed. The device is suitable for further scaling (up to 64×64 pixel and beyond) and potential commercialisation. More importantly, the monolithic approach developed in this work is very flexible, as a number of III-V materials with mid-IR detecting capabilities can be grown on GaAs substrates, meaning alternative semiconductor layer structures could also be investigated in the near future.

Silicon compatible light sources have been referred to as the \holy grail" for Si photonics. Such devices would give the potential for a range of applications; from optical interconnects on integrated circuits, to cheap optical gas sensing and spectroscopic devices on a Si platform. Whilst numerous heterogeneous integration schemes for integrating III-V lasers with Si wafers are being pursued, it would be far easier and cheaper to use the epitaxial tools already in complementary-metal-oxide-semiconductor (CMOS) lines, where Ge and SiGe chemical vapour deposition is used in a number of advanced technology nodes. Germanium is an effcient absorber, but a poor emitter due to a band-structure which is narrowly indirect, but by only 140 meV. Through the application of strain, or by alloying with Sn, the Ge bandstructure can be engineered to become direct bandgap, making it an effcient light emitter. In this work, silicon nitride stressor technologies, and CMOS compatible processes are used to produce levels of tensile strain in Ge optical micro-cavities where a transition to direct bandgap is predicted. The strain distribution, and the optical emission of a range of Ge optical cavities are analyzed, with an emphasis on the effect of strain distribution on the material band-structure. Peak levels of strain are reported which are higher than that reported in the literature using comparable techniques. Furthermore, these techniques are applied to GeSn epi-layers and demonstrate that highly compressive GeSn alloys grown pseudomorphically on Ge virtual substrates, can be transformed to direct bandgap materials, with emission >3 m wavelength { the longest wavelength emission demonstrated from GeSn alloys. Such emission is modeled to have a good overlap with methane absorption lines, indicating that there is huge potential for the such technologies to be used for low cost, Si compatible gas sensing in the mid-infrared.

The design parameters and the construction of a pulsed solid state laser are described. Q-switching techniques are reviewed and a novel form of the exploding film Q-switch is decribed. This Q-switch was capable of generating high power giant pulses which were comparable with those obtained using conventional dye-stuff switches. Techniques for generating ultrashort optical pulses are reviewed and in particular the author's procedures for generating mode locked pulses in ruby are described. The successful use of a random stack mirror circumvented the damage problem which besets thin film dielectric mirrors in the presence of mode locked pulses. The construction and use of random stack mirrors with lasers operating in various modes were also investigated. Spatially modulated structures defined to 0.2 were thermally etched on thin metallic films and such structures were found to he duplicated on the substrate. Assessments of such structures for applications to the manufacture of optical diffraction gratings and grid polarizers have also been made. The hologram of the laser cavity, recorded in gold film, was found to he capable of instant 'read out'.Spatially modulated thin films have been deposited onglass substrates by a process in which the condensation of the film material was inhibited by the intense electromagnetic fields within the cavity of a giant pulse ruby laser. Such an inhibitive process constitutes a new phenomenon, discovered by the author and roported very recently in Nature.