No description available.

No description available.

No description available.

No description available.

No description available.

The possibility of using demolished concrete waste as aggregate in fresh concrete in the production of prestressed concrete beams is checked in this research. As opposed to the use for road foundations or as fill-in material the use of the Recycled Aggregate (RA) for concrete structures requires more tests and processing of results. In fact to be able to use a material for construction it is essential to assess more than just its compressive strength. After the physical and chemical characteristics of the RA and the properties of both the wet and hardened Recycled Aggregate Concrete (RAC) have been determined, it is important to check if the mathematical models and numerical correlation normally used for design of ordinary concrete (such as mix-design procedure, design codes, non-linear analysis) are suitable for RAC. For this reason the main task of this investigations has been to ensure that RAC has satisfactory mechanical performance for structural use and later to guarantee a consistency of the results using methods checked for RAC. A mix-design procedure suitable for RAC to attain the desired workability and the target strength was the first step. Tests on durability of RA and RAC have been performed and the results reported. Finally three 15.0 metres span prestressd beams cast with different percentages of RA (one with 100% of RA, one with 100% of Natural Aggregate NA, and one with 50% of RA and 50% of NA) have been tested. The results show that it is practicable to make prestressed concrete elements using concrete made with Recycled Aggregate and that these elements can have satisfactory and predictable mechanical performance.

There are many important environmental issues involved in the construction and use of buildings which are either undergoing or require further research. The lack of detailed embodied energy assessments models has been identified and limits possible environmental analysis. This study examines the current state of research into the environmental impact of frame materials, assesses the quality and range of data available, sets up a new framework for evaluation of materials and uses several example structures to assess the environmental impact This has been achieved by, firstly, studying the environment related literature available concerning the frame of the building, separate from other considerations, to provide a clear understanding of the processes involved. Second, data is extracted from the literature and processed to provide a homogenous approach and level field from which frame analysis can take place. Gaps in the available data are identified. Third, the identified gaps are filled using data derived from sources ranging from manufacturers' literature to direct analysis of on site activities. Fourth, a model has been created to assess the environmental impact of the building frame. The factors assessed within the remit of environmental impact are: embodied energy, embodied CO2 and transportation hours. The embodied energy includes the primary energy for all raw materials, transportation, office overheads and contractor operations. These are calculated from the winning of raw materials, through manufacture, to demolition and recycling. Embodied CO2 encompasses the same range of data, but with respect to the CO2 transportation hours estimate the time spend on the road by vehicles involved in the embodied energy and CO2 calculations. Finally data from several buildings has been used, to evaluated the environmental merits of each with respect to each other and to other buildings for which calculations have been performed. Conclusions have been draw and. further work suggested.

This project has been undertaken for Hamworthy Hydraulics Limited. Its objective was to design and develop a controller package for a variable displacement, hydraulic pump for use mainly on mobile earth moving machinery. A survey was undertaken of control options used in practice and from this a design specification was formulated, the successful implementation of which would give Hamworthy an advantage over its competitors. Two different modes for the controller were envisaged. One consisted of using conventional hydro-mechanics and the other was based upon a microprocessor. To meet short term customer prototype requirements the first section of work was the realisation of the hydro-mechanical system. Mathematical models were made to evaluate controller stability and hence aid their design. The final package met the requirements of the specification and a single version could operate all sizes of variable displacement pumps in the Hamworthy range. The choice of controller options and combinations totalled twenty-four. The hydro-mechanical controller was complex and it was realised that a micro-processor system would allow all options to be implemented with just one design of hardware, thus greatly simplifying production. The final section of this project was to determine whether such a design was feasible. This entailed finding cheap, reliable transducers, using mathematical models to predict electro-hydraulic interface stability, testing such interfaces and finally incorporating a micro-processor in an interactive control loop. The study revealed that such a system was technically possible but it would cost 60% more than its hydro-mechanical counterpart. It was therefore concluded that, in the short term, for the markets considered, the hydro-mechanical design was the better solution. Regarding the micro-processor system the final conclusion was that, because the relative costs of the two systems are decreasing, the electro-hydraulic controller will gradually become more attractive and therefore Hamworthy should continue with its development.

The nature and kinetics of electrode reactions and processes occurring for four lightweight anode systems which have been utilised in reinforced concrete cathodic protection systems have been studied. The anodes investigated were flame sprayed zinc, conductive paint and two activated titanium meshes. The electrochemical properties of each material were investigated in rapidly stirred de-oxygenated electrolytes using anodic potentiodynamic polarisation. Conductive coating electrodes were formed on glass microscope slides, whilst mesh strands were immersed directly. Oxygen evolution occurred preferentially for both mesh anodes in saturated Ca (OH)2/CaC12 solutions but was severely inhibited in less alkaline solutions and significant current only passed in chloride solutions. The main reactions for conductive paint was based on oxygen evolution in all electrolytes, although chlorides increased the electrical activity. Self-corrosion of zinc was controlled by electrolyte composition and the experimental set-up, chlorides increasing the electrical activity. Impressed current cathodic protection was applied to 25 externally exposed concrete slabs over a period of 18 months to investigate anode degradation mechanisms at normal and high current densities. Specimen chloride content, curing and reinforcement depth were also variables. Several destructive and non-destructive methods for assessing the performance of anodes were evaluated including a site instrument for quantitative "instant-off- potential measurements. The impact of cathodic protection on the concrete substrate was determined for a number of specimens using appropriate methods. Anodic degradation rates were primarily influenced by current density, followed by cemendtious alkalinity, chloride levels and by current distribution. Degradation of cementitious overlays and conductive paint substrates proceeded by sequential neutralisation of cement phases, with some evidence of paint binder oxidation. Sprayed zinc progressively formed an insulating layer of hydroxide complexes, which underwent pitting_ attack in the presence of sufficient chlorides, whilst substrate degradation was minimal. Adhesion of all anode systems decreased with increasing current density. The influence of anode material on the ionic gradients which can develop during cathodic protection was investigated. A constant current was passed through saturated cement paste prisms containing calcium chloride to central cathodes via anodes applied or embedded at each end. Pore solution was obtained from successive cut paste slices for anion and cation analyses. Various experimental errors reduced the value of the results. Characteristic S-shaped profiles were not observed and chloride ion profiles were ambiguous. Mesh anode specimens were significantly more durable than the conductive coatings in the high humidity environment. Limited results suggested zinc ion migration to the cathode region. Electrical data from each investigation clearly indicated a decreasing order of anode efficiency by specific anode material.

This study has investigated the inclusion of pulverised fuel ash (PFA) and blast furnace slag (BFS) into hardened cement pastes (HCP) in retarding the ingress of chloride ions and oxygen molecules from the external environment. The influence of environmental factors such as drying and carbonation on the pore structure and diffusional properties of OPC, OPC/30%PFA and OPC/65%BFS hardened pastes was investigated. Specimens were desorbed from a saturated surface dry condition to a near constant weight at 65% relative humidity (RH) while others were simultaneously exposed to a 65% RH atmosphere and a carbon dioxide atmosphere of up to 5% by volume until there were fully carbonated. The presence of the interfacial zone at the cement paste-aggregate interface was critically reviewed and identified. The influence of the interfacial zone on porosity and chloride ingress in assumed periodic composites of glass bead mortars was also studied. The investigations have demonstrated the following: (a) The use of fly ash and slag in blended cement pastes has resulted in a marked reduction in capillary porosity and rate of chloride ingress. (b) The ratio of oxygen to chloride diffusion coefficients increased from values close to 1 in permeable pastes, to values of around 15 in low-permeability blended fly ash and slag pastes. This supports the view that the diffusion of chloride ions is retarded by the surface charge of the hydrated cement gel in low-permeability pastes. (c) Compared with plain OPC pastes, the carbonation of blended fly ash and slag pastes resulted in a marked increase in the coarse capillary porosity and a corresponding increase in the oxygen and chloride diffusion rates.