Cellulose whiskers (CWs) obtained from naturally occuring cellulose are nano-inclusions which show a lot of promise as mechanical reinforcements in polymers. Typically, a relatively high content is added to realize improvement in effective mechanical behavior. This enhancement in modulus is usually followed by a modest increase in strength but generally the ductility and toughness decrease. Our approach is to use small concentrations of CWs so as not to detrimentally affect processability, toughness and ductility. By aligning the small concentrations, we target the same kind of improvement in modulus and strength as reported in the literature, but at much smaller volume contents. In this work, we investigate the effect of AC electric field on the alignment of dispersed nanoscale CW in a polymer. Polyvinyl acetate (PVAc) is used as the model polymer because of the good interaction between CWs and PVAc. A low concentration of 0.4wt% was used for the study. Two dispersion methods, namely basic and modified, were developed. The basic method led to micron scale dispersion. Using the modified method, CWs were individually dispersed in PVAc with average lengths and diameters of 260 nm and 8 nm respectively yielding an aspect ratio of approximately 30. The behavior of CWs (alignment and chain formation) under an applied electric field was found to be a function of applied electric field magnitude, frequency and duration. Following alignment, the CW/PVAc nanocomposites are thermally dried in the presence of electric field to maintain the aligned microstructure. Improvements in dielectric constant and mechanical properties were observed for the aligned cases as compared to random case and pure PVAc. The optimal electric field magnitude, frequency and duration for the alignment and chain formation were found to be 200Vpp/mm, 50 KHz for duration of 20 minutes for the microcomposite and 250Vpp/mm, 10KHz for a duration of 1hr for the nanocomposite. At 0.4wt% concentration, 21% increase in dielectric constant for the optimal nanocomposite case. Above Tg, a 680% improvement in elastic modulus at 0.4wt% concentration for the optimal nanocomposite case. The reason for the significant reinforcement is attributed to alignment (rotation and chain formation) and chain-chain interaction (3D network formation and hydrogen bonding).

This dissertation investigates the emulsification of aqueous liquid in immiscible organic liquid in various microfluidic environments, and addresses both experimental characterization and theoretical interpretation of the dynamics and design guidelines, as well as an application of microfluidic emulsification in fabrication of disk-like colloidal particle suspensions for studying its sedimentation behavior. In an attempt to understand the dynamics of drop formation in flow-focusing microfluidic channels, especially for an explanation of a transition from unique drop size to bimodal oscillating drop sizes as observed in the experiments, numerical simulation is developed to use the volume-of-fraction method to model the drop formation, and the simulation results help to interpret the transition in the theory of saddle-node transition in drop formation, as well as show the importance of selecting proper orifice length in flow-focusing microfluidic channel design. The electric technique for controlling of microfluidic emulsification is explored by a detailed study on low-frequency alternating-current electro-flow-focusing (EFF) emulsification in microfluidic channels. It is found that the droplet size variation is not a monotonic function of the electric field as in the case of direct-current EFF emulsification, which originates from the relaxation oscillation of the flow rate through the Taylor cone, and a power-law droplet size distribution was obtained at the voltage ramping-up stage. This emulsification process was modeled in analog to the charge accumulation and release in a resistor-capacitor electric circuit with an adjustable resistor, and the simulated data exhibit good agreement with the experiments. As an application of the microfluidic emulsification, a method of fabricating disk-like wax colloidal particle suspensions using electrospray is reported. Based on this technique, the first measurement of the hindrance function for sedimentation and creaming of disk-shaped colloids via the analytical centrifugation is reported. Disks align with the external flow right above the volume fraction of a few percent and this effect is extremely sensitive to the aspect ratio of disks. Due to this alignment effect, disk sedimentation/creaming demonstrate distinct trends in dilute and semi-dilute region.