Artificial intelligence techniques have been widely used for prediction in various areas of sciences and engineering. In the thesis, applications of AI techniques are studied to predict the dilution of industrial outfall discharges. The discharge of industrial effluents from the outfall systems is broadly divided into two categories on the basis of density. The effluent with density higher than the water receiving will sink and called as negatively buoyant jet. The effluent with density lower than the receiving water will rise and called as positively buoyant jet. The effluent discharge in the water body creates major environmental threats. In this work, negatively buoyant jet is considered. For the study, ANFIS model is taken into consideration and incorporated with algorithms such as GA, PSO and FFA to determine the suitable model for the discharge prediction. The training and test dataset for the ANFIS-type models are obtained by simulating the jet using the realizable k-ε turbulence model over a wide range of Froude numbers i.e. from 5 to 60 and discharge angles from 20 to 72.5 degrees employing OpenFOAM platform. Froude number and angles are taken as input parameters for the ANFIS-type models. The output parameters were peak salinity (Sm), return salinity (Sr), return point in x direction (xr) and peak salinity coordinates in x and y directions (xm and ym). Multivariate regression analysis has also been done to verify the linearity of the data using the same input and output parameters. To evaluate the performance of ANFIS, ANFIS-GA, ANFIS-PSO, ANFIS-FFA and multivariate regression model, some statistical parameters such as coefficient of determination (R2), root mean squared error (RMSE), mean absolute error (MAE) and average absolute deviation in percentage are determined. It has been observed that ANFIS-PSO is better in predicting the discharge characteristics.