?rea de concentra??o: Qu?mica org?nica. / Data de aprova??o retirada da vers?o impressa do trabalho. / Palavras-chave ausentes no Resumo/Abstract. / Submitted by Jos? Henrique Henrique (jose.neves@ufvjm.edu.br) on 2017-08-04T17:58:56Z No. of bitstreams: 2 myrlene_oliveira_ottone.pdf: 35150534 bytes, checksum: f6a5ce4d99508eed910f62e1d6984580 (MD5) license_rdf: 0 bytes, checksum: d41d8cd98f00b204e9800998ecf8427e (MD5) / Approved for entry into archive by Rodrigo Martins Cruz (rodrigo.cruz@ufvjm.edu.br) on 2017-08-14T13:58:08Z (GMT) No. of bitstreams: 2 license_rdf: 0 bytes, checksum: d41d8cd98f00b204e9800998ecf8427e (MD5) myrlene_oliveira_ottone.pdf: 35150534 bytes, checksum: f6a5ce4d99508eed910f62e1d6984580 (MD5) / Made available in DSpace on 2017-08-14T13:58:08Z (GMT). No. of bitstreams: 2 license_rdf: 0 bytes, checksum: d41d8cd98f00b204e9800998ecf8427e (MD5) myrlene_oliveira_ottone.pdf: 35150534 bytes, checksum: f6a5ce4d99508eed910f62e1d6984580 (MD5) Previous issue date: 2016 / Coordena??o de Aperfei?oamento de Pessoal de N?vel Superior (CAPES) / O SiO2-SO3H ? um catalisador heterog?neo, sintetizado a partir de areia de constru??o e carbonato de s?dio, o qual, vem se mostrando eficaz nas s?nteses org?nicas. No presente trabalho, esse catalisador foi usado na s?ntese de ?steres benz?licos e fen?licos, realizada em apenas uma ?nica etapa, com rendimentos entre 80 e 95%. E devido a esse alto rendimento, foi tamb?m realizado rea??es de cetaliza??es, utilizando glicerol, 2,2-dimetil-1,3-propandiol e 1,1,1-hidroximetil-propanol e diversas cetonas. As rea??es com o glicerol apresentaram rendimentos baixos, por ser uma esp?cie muito polar e interagir com os poros da s?lica, evitando a colis?o com as mol?culas de cetonas. Diante desses resultados, foi poss?vel produzir um catalisador heterog?neo que al?m de diminuir o impacto ambiental, carrega caracter?sticas ben?ficas e eficientes para s?ntese org?nica, poss?vel se tonar eficaz para futuras rotas sint?ticas. / Disserta??o (Mestrado) ? Programa de P?s-Gradua??o em Qu?mica, Universidade Federal dos Vales do Jequitinhonha e Mucuri, 2016. / The SiO2 - SO3H is a heterogeneous catalyst synthesized from building sand and sodium carbonate. It has proven to be effective for organic syntheses. In study the catalyst was used in the synthesis of benzyl esters and phenolics and the yields between 80 and 95%. And the high yield was also performed cetaliza??es reactions using glycerol, 2,2- dimethyl- 1,3- propandiol and 1,1,1 -hydroxymethyl- propanol and various ketones. The reactions with glycerol had low yield justified very polar species and interact with the pores of silica, avoiding collision with ketone molecules. These results it was possible to produce a heterogeneous catalyst in addition to reducing environmental impact, carries beneficial and efficient features for organic synthesis. It can be effective tonar for future synthetic routes.