Mainz, Universiẗat, Diss., 2001.

Thesis (Ph. D.)--Auburn University, 2008. / Abstract. Vita. Parts of this dissertation have been published as: Na₂[UO₂(IO₃)₄(H₂O)] (Ch. 2: Bray, T.H.; et al., Inorg. Chem., 2006, 45, 8251-8257.), An(IO₃)₄(An = Np, Pu) and Np(IO₃)₄·nH2O (Ch. 3: Bray, T.H.; et al., Inorg. Chem., 2007, 46, 3663-3668.), Pu(SeO₃)₂ (Ch. 4: Bray, T.H.; et al., J. Solid State Chem., 2008, 181, 493-498.), NpFPO₄ and Cs₂Np₂F₇PO₄ (Ch. 5: Bray, T.H.; et al., J. Solid State Chem., 2007, 180, 70-74.), [C₆H₁₄N₂][(UO₂)₄(HPO₄)₂PO₄)₂(H₂O)]·H₂O (Ch. 6: Bray, T.H.; et al., "Synthesis and Structure of [C6H14N2][(UO2)4(HPO4)2(PO4)2(H2O)]·H₂O: An Expanded Open-Framework Amine-Bearing Uranyl Phosphate," In press: Journal of Solid State Chemistry April 24, 2008.), and Np(CH₃PO₃)(CH₃PO₃H)(NO₃)(H₂O)·H₂O (Ch. 7: Bray, T.H.; et al., Inorg. Chem., 2007, 46, 10959-10961.). Includes bibliographical references.

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Radium needles that were once implanted into tumours as a cancer treatment are now obsolete and constitute a radioactive waste problem, as their half-life is 1600 years. The reduction of radium by photonuclear transmutation by bombarding Ra-226 with high-energy photons from a medical linac has been investigated. The irradiated needles would then be processed to remove the Ac-225, which can then be used for .Targeted Alpha Therapy. (TAT) of cancer. This project has the potential to slowly reduce obsolete radioactive material, and displace future expensive importation of Ac-225 from Russia, Germany (Institute for Transuranium Elements - ITU) and the US in the years ahead. This thesis progresses through a number of stages and begins by providing a background to the usefulness of Ac-225 as an alpha emitter, some of the equipment used in the experimental work such as linear accelerators and detectors, as well as the initialisation of a process whereby a reliable source of high-grade radium is secured, suitable equipment obtained, followed by a series of experiments leading to the production of the desired product, actinium and bismuth. The second stage of this study involved the formulation of a theoretical model in which the bremsstrahlung photon spectrum at 18 MV linac electron energy is convoluted with the corresponding photonuclear cross sections of Ra- 226. This enabled the total integrated yield of Ra-225 and its daughter product Ac-225 to be obtained. The third stage of this study ties the theoretical and experimental work together by presenting the results of a number of experiments performed on radium sources. These experiments were performed over a period of about three years using a variety of detectors in a hospital setting. These experiments, as presented in this thesis, demonstrate that Ac-225 can be produced in small quantities by a medical linac or in commercial quantities by the use of a high-powered linac or cyclotron, thereby, ensuring a reliable supply of Ra-225 for TAT and also reducing the radium waste product. / Doctor of Philosophy

Friedrich Giesel entdeckte im Jahre 1902 das Actinium nach Fällung mit Lanthan aus einer Pechblendelösung. Er hatte den Namen Emanium vorgeschlagen, da es stark emanierte. Lange Zeit wurde nur Andre-Louis Debierne als Entdecker des Actiniums akzeptiert, da er 1904 behauptet hatte, dass die von ihm im Jahr 1900 gefundene von ihm Actinium genannte radioaktive Substanz mit den chemischen Eigenschaften des Thoriums, die hauptsächlich das Thoriumisotop 230Th enthielt, mit dem Emanium von Giesel identisch gewesen sei. In dem Beitrag werden die Entdeckungen von Debierne und Giesel und der Weg bis zur Anerkennung von Giesel als Entdecker vorgestellt. / Friedrich Giesel discovered actinium in 1902 after co precipitation with lanthanum from a solution of pitchblende. He had suggested to name it emanium, because of its emanating properties. But for a long time only Andre-Louis Debierne was accepted as discoverer of actinium, because in 1904 he has explained, that the radioactive substance found by him in 1900, with chemical properties of thorium, named actinium, and mainly consisting of the thorium isotope 230Th, has been identical with the emanium of Giesel. The discoveries of Giesel and Debierne are explained as well as the steps on the way of acceptance of Giesel as discoverer of actinium.

Friedrich Giesel entdeckte im Jahre 1902 das Actinium nach Fällung mit Lanthan aus einer Pechblendelösung. Er hatte den Namen Emanium vorgeschlagen, da es stark emanierte. Lange Zeit wurde nur Andre-Louis Debierne als Entdecker des Actiniums akzeptiert, da er 1904 behauptet hatte, dass die von ihm im Jahr 1900 gefundene von ihm Actinium genannte radioaktive Substanz mit den chemischen Eigenschaften des Thoriums, die hauptsächlich das Thoriumisotop 230Th enthielt, mit dem Emanium von Giesel identisch gewesen sei. In dem Beitrag werden die Entdeckungen von Debierne und Giesel und der Weg bis zur Anerkennung von Giesel als Entdecker vorgestellt. / Friedrich Giesel discovered actinium in 1902 after co precipitation with lanthanum from a solution of pitchblende. He had suggested to name it emanium, because of its emanating properties. But for a long time only Andre-Louis Debierne was accepted as discoverer of actinium, because in 1904 he has explained, that the radioactive substance found by him in 1900, with chemical properties of thorium, named actinium, and mainly consisting of the thorium isotope 230Th, has been identical with the emanium of Giesel. The discoveries of Giesel and Debierne are explained as well as the steps on the way of acceptance of Giesel as discoverer of actinium.

Thesis (Ph.D) -- University of Western Sydney, 2007. / A thesis submitted to the University of Western Sydney, College of Health and Science, School of Engineering, in satisfaction of the requirements for the degree of Doctor of Philosophy. Includes bibliography.

Universiẗat, Diss., 2001--Mainz.

Resonant ionization laser ion sources are applied worldwide to increase purity and intensity of rare isotopes at radioactive ion beam facilities. Especially for heavy elements the laser wavelengths required for efficient resonant laser ionization are not only element dependent, but also vary to small degrees from isotope to isotope. Since the first operation of an actinide target at ISAC-TRIUMF in 2008, the demand for neutron-rich isotopes far away from stability has steadily increased. Those isotopes often have very low production rates so that often only a few ions per second are released. In order to study isotope shifts and hyperfine structure of silver, actinium and astatine, in-source resonant ionization spectroscopy in combination with radioactive decay detection has been applied. Despite the Doppler limited resolution, it has the advantage that it is ultra-sensitive and the atomic spectrum for the nuclear ground and isomeric states can be investigated individually. An isobaric separation has been demonstrated for 115-119Ag, where the hyperfine structure of one state showed a splitting of 22 GHz to 38 GHz while for the other state only a single peak spectrum can be resolved. For astatine and actinium, the main interest is to measure and study the optical isotope shift, which is for the first excitation step for neutron-rich isotopes in the order of IS_FES≈±3.7GHz/u for both elements, as these observables give insight into nuclear moments and shape. In addition, also the isotope shift of the second excitation step for astatine has been measured to IS_SES,At≈-1.7GHz/u. Laser spectroscopy on astatine has mainly been performed on the neutron-deficient isotopes 199,205At due to high count rates and low isobaric contamination. With the results obtained it is possible to extrapolate the required wavelength for ionizing and delivering the isotopes 221-225At which are of interest to e.g. electric dipole moment studies. / October 2017