published_or_final_version / abstract / toc / Physics / Master / Master of Philosophy

Thesis (M. Phil.)--University of Hong Kong, 2005. / Title proper from title frame. Also available in printed format.

Thesis (M.S.)--West Virginia University, 2007. / Title from document title page. Document formatted into pages; contains v, 36 p. : ill. (some col.). Includes abstract. Includes bibliographical references (p. 21).

A gas phase kinetic model for the CF���/O��� microwave discharge plasma and afterglow of our laboratory has been developed. A reaction pathway identifying the major chemical reactions is proposed. The rate coefficients of the electron impact dissociation reactions are determined at three different plasma powers using both published electron molecule collision cross section data and plug flow analysis of data collected in our system. Agreement between calculated and experimental rate coefficients is better than 20%. Fluid simulations of a two-dimensional mathematical model were performed using computational fluid dynamics. It is found that the model reproduced qualitatively the general trends of the experimental data. The effects of plasma power, feed gas composition, residence time and pressure on the product distribution of the system are studied. CF��� conversion increases with power and residence time. The variation of CF��� conversion and carbon containing species distribution falls into two regimes. In the oxygen rich regime (below 25 mole % CF��� in the feed), CO��� is found to be the major product of CF��� decomposition; homogeneous recombination reactions between atomic oxygen and the free radicals are found to be the dominant mechanism in the afterglow region resulting in high CF��� conversions. Homogeneous reactions convert CO to CO���. In the CF��� rich regime (above 50 mole % CF���), COF��� is found to be the major product of CF��� decomposition. Recombination reactions of CF��� with atomic fluorine dominate in the afterglow region and limit conversion. Lowering pressures result in increased conversion of CF��� and increased concentration of the carbon containing species. / Graduation date: 1998

Thesis (Ph.D.)--University of Missouri-Columbia, 2006. / The entire dissertation/thesis text is included in the research.pdf file; the official abstract appears in the short.pdf file (which also appears in the research.pdf); a non-technical general description, or public abstract, appears in the public.pdf file. Title from title screen of research.pdf file viewed on (February 28, 2007) Vita. Includes bibliographical references.

published_or_final_version / abstract / Physics / Master / Master of Philosophy

Thesis (M. Phil.)--University of Hong Kong, 2007. / Title proper from title frame. Also available in printed format.