Emissions of air pollutants from non-conventional sources have been on the rise in the North Texas area over the past decade. These include primary pollutants such as volatile organic compound (VOC) and oxides of nitrogen (NOx) which also act as precursors in the formation of ozone. Most of these have been attributed to a significant increase in oil and gas production activities since 2000 within the Barnett Shale region adjacent to the Dallas-Fort Worth metroplex region. In this study, air quality concentrations measured at the Denton Airport and Dallas Hinton monitoring sites operated by the Texas Commission on Environmental Quality (TCEQ) were evaluated. VOC concentration data from canister-based sampling along with continuous measurement of oxides of nitrogen (NOx), ozone (O3), particulate matter (PM2.5), and meteorological conditions at these two sites spanning from 2000 through 2014 were employed in this study. The Dallas site is located within the urban core of one of the fastest growing cities in the United States, while the Denton site is an exurban site with rural characteristics to it. The Denton Airport site was influenced by natural gas pads surrounding it while there are very few natural gas production facilities within close proximity to the Dallas Hinton site. As of 2013, there were 1362 gas pads within a 10 mile radius to the Denton Airport site but there were only 2 within a 10 mile radius to Dallas Hinton site. The Dallas site displayed higher concentrations of NOx and much lower concentrations of VOC than the Denton site. Extremely high levels of VOC measured at the Denton site corresponded with the increase in oil and gas production activities in close proximity to the monitoring site. Ethane and propane are two major contributors to the measured VOC concentration, suggesting the influence of fugitive emissions of natural gas. In Dallas, the mean and maximum values of ozone had decreased since 2000 by about 2% and 25%, respectively. Similarly NOx decreased by 50% and 18% in the mean and maximum values. However, the mean VOC value showed a 21% decrease while the maximum value increased by about 46%. In Denton, the change in percentage of ozone and NOx were similar to Dallas but the mean VOC concentration increased by about 620% while the max value increased 1960%. Source apportionment analysis confirmed the findings by identifying the production of natural gas to be the primary source of VOC emissions in Denton, while traffic sources were more influential near the Dallas site. In light of the recent proposal by EPA to revise the ozone standard, the influence of these new unconventional sources should be further evaluated.

Elemental carbon (EC), a product of incomplete combustion of fossil fuels and biomass, contributes to climate warming and poor air quality. In urban areas, diesel fuel trucks are the main source of EC emissions from mobile sources. After emission, EC is deposited to receptor surfaces via two main pathways: precipitation (wet deposition) and directly as particles (dry deposition). Urban trees may play an important role in removing EC from the atmosphere by intercepting and delivering it directly to the soil. The goal of this research was to quantify the magnitude of EC retention in leaf waxes (in-wax EC) and EC fluxes to the soil via leaf litterfall in the City of Denton, Texas. Denton is a rapidly growing urban location in the Dallas-Fort Worth metropolitan area. A foliar extraction technique was used to determine EC retention in leaf waxes. Foliar samples were collected monthly, from April through July, from pairs of Quercus stellata (post oak, n=10) and Quercus virginiana (live oak, n = 10) trees. Samples were rinsed with water and chloroform in a two-step process to determine EC retained in leaf waxes. A Sunset OC/EC aerosol analyzer was utilized to analyze the EC content of extracts filtered onto quartz-fiber filters. From April through July, leaf litter was collected bi-weekly under 35 trees (20 post oak, 15 live oak), and oven dried to determine dry weight. EC retained by tree canopies was estimated by multiplying in-wax EC by canopy leaf area index, while EC flux to soil was estimated by multiplying in-wax EC by leaf litterfall mass. This study shows that through retention of EC in leaf waxes, urban tree canopies represent important short-term sinks for soot in urban areas.

Don't Frack With Denton chronicles the ground-breaking movement to ban hydraulic fracturing in the city of Denton, Texas by combining observational location shooting with extensive sit-down interviews and carefully negotiated subject-filmmaker relationships to create a safe and comfortable space for thoughtful reflection and criticism of a complex social movement who's activities span several years and many individuals. The result is a long-form documentary that is unapologetically in solidarity with this movement's goals while simultaneously maintaining enough editorial independence and critical distance to allow the activists themselves to honestly evaluate their decision-making, tactics and interpersonal relationships in ways that will provide insight and instruction to similar movements around the country and the world.