Thesis (M.S.)--Ohio State University. / Bibliography: leaves 104-112. Available online via OhioLINK's ETD Center

Anorogenic alkaline ring-type complexes form within continental plate settings. Alkaline magmatism is derived from the upper mantle, in which mantle metasomatism plays an important part, as well as from partial melting of the lower crust. Radial and concentric fractures develop during the ascent of alkaline magma. Extrusion of basic and felsic magma takes place along these fractures with felsic volcanics building-up central volcanoes. As a result of emptying of the magma chamber, the superstructure of the volcano collapses and a caldera is formed. During the caldera stage syenitic and granitic material are intruded into ring fractures. Alkaline ring-type complexes may be classified as (i) alkaline qranite and syenite-type and (ii) carbonatite and undersaturated-type. These ring-type complexes occur as distinct igneous provinces. Some major provinces occur in Brazil, Corsica, Namibia, Nigeria, Norway, Saudi-Arabia and Sudan. In Namibia the Damaraland igneous province is of Mesozoic aqe and it contains 15 alkaline ring-type complexes . These complexes are situated along north-eastern trends which correspond to transform directions of the South Atlantic. During the opening of the South Atlantic (Gondwana breakup) Pan-African age lineaments were reactivated which allowed emplacement of anorogenic alkaline magmatism. A zonation of alkaline granite and syenitetype in the west and carbonatite and undersaturated-type ring-complexes in the east correlates with down- and upwarp axes parallel to the line of Gondwana fragmentation. Alkali- and H⁺-metasomatism is related to the alkaline and syenite-type whereas alkali metasomatism (fenitization) is associated with carbonatite and undersaturated-type ring-complexes. Sn, W and Ta mineralization is associated with alkaline granites of some of the alkaline granite and syenite-type ring-complexes. Fe, F, PO₄ , Nb, Th, REE, Sr, Zn and Pb mineralization is associated with carbonatite complexes. Potential exists for: (i) porphyry Cu-Mo and epithermal-type (Au, Ag, Pt-metals, base metals) mineralization in the alkaline granite and syenite-type ring-complexes and (ii) disseminated Cu, Au, Aq and Pt-metals in carbonatite and undersaturated-type ring-complexes

No description available.

Three gneissose alkaline granitoid intrusives at Ngoye, Bulls Run and Wangu are described. They are located within the Nkomo Nappe of the Tugela Terrane, near the northern margin of the Natal Metamorphic Province. The Ngoye Complex comprises alkaline granites, with minor syenite and monzodiorite phases. According to modal am geochemical criteria the Ngoye granites range from peraluminous (muscovite-bearing), through metaluminous (biotite- and/or hornblende-bearing), to peralkaline (riebeckite-, aegirine- and magnetite-bearing). The granites are A-types according to their modal and geochemical characteristics. Rb-Sr isotopic data for the hornblende granites indicate an age of 1063 ± 17 Ma and the initial ratio (R๐ = 0.7025) provides evidence for derivation from a mantle source. Plotting of the Ngoye geochemistry on tectonic-discrimination diagrams suggests intrusion into rifted continental crust. It is concluded that the gneissose Ngoye granites constitute a deformed central complex, similar to anorogenic complexes in Nigeria and the Sudan. The Bulls Run Complex is situated 30 km west of the Ngoye Complex. A concentric outcrop pattern has been mapped, according to which an envelope of silica-saturated biotite-muscovite syenite surrounds a core of nepheline-bearing syenites. Minor intrusive phases include biotite-rich dykes, sovite carbonatite sheets, silica-oversaturated microsyenite dykes and feldspathic ijolite. The outer envelope of muscovite-rich syenite is interpreted as fenitised pelitic country rock. An alkali-lamprophyre origin is suggested for the biotite-rich dykes. Geochemically the syenites are predominantly miaskitic, apart from the microsyenite dykes which are mildly peralkaline. Rb-Sr isotopic data for the nepheline syenites indicate an age of 1138 ± 45 Ma (Ro = 0.70322). Carbonate separates from the carbonatites provide a similar low initial ratio (Ra = 0.70319) which supports a comagmatic mantle origin. A comparison is drawn between the Bulls Run Complex and miaskitic nepheline syenite gneisses in the mid-Proterozoic Grenville Province of canada. From this, it is suggested that the Bulls Run Complex is pretectonic and was intruded into the rifted passive margin of a continent. The Wangu Granite Gneiss is situated 3 km southwest of the Bulls Run Complex. The granites are fine grained and contain aegirine-augite and/or magnetite, and classify as alkali-feldspar granite. Peralkaline chemistry is characteristic of the Wangu granites, with trace-elenent contents indicating a distinct A-type signature. Biotite-rich mafic dykes intrude the southern part of the Wangu outcrop and, on the basis of major- and trace-element signatures, are suggested to be metamorphosed volatile-rich alkaline lamprophyres similar to those at Bulls Run. Geochemical similarities between the Wangu granites and certain comendites from the Kenya Rift are noted. It is suggested that the Wangu granites were emplaced as high-level dykes, within rifted continental crust. It is proposed that the Ngoye, Bulls Run and Wangu intrusives be united as the Nkwaleni Suite. Comparison of the Tugela Terrane with the Grenville Province reveals many similarities, particularly their mid- to late-Proterozoic age and the occurrence of pre-tectonic anorogenic continental magmatism. It is concluded that, unlike the current model which would have the Tugela Terrane as obducted ophiolite, these new data indicate that the Tugela Terrane is a metamorphosed continental rift system. / Thesis (Ph.D.)-University of Durban-Westville, 1991.

Thesis (M.S.)--Ohio State University, 1986. / Includes bibliographical references (leaves 141-146). Available online via OhioLINK's ETD Center

The Kuboos-Bremen Igneous Province comprises a linear zone of alkaline complexes that intrude Proterozoic and Pan-African rocks and trends in a northeast direction from the northwest of the Cape Province in South Africa into southern Namibia. Of the three most southerly complexes in Namibia. two comprise silicate rocks ranging from nepheline syenite to alkali-granite and are called the Grootpenseiland and Marinkas Kwela Complexes (GPC and MKC). The Marinkas Kwela Carbonatite Complex is the third and most northerly of the complexes. Isotopic age determinations on a number of rock types from both the silicate complexes yield ages around 520Ma and are consistent with published Pan-African ages for the Province. Each silicate complex shows a migrating locus of intrusion from Siundersaturated rocks in the southwest to Si-oversaturated rocks in the northeast. The complexes overlap in outcrop. The rocks are moderately to highly felsiC and none reflects primary magma compositions. The Si-undersaturated rocks from both complexes include side-wall cumulates formed from magmas that fractionated alkali-feldspar, clinopyroxene and amphibole. Foyaites also occur in the MKC and have a compositional range reflecting alkali-feldspar fractionation and, probably, some interaction with dolomite country rocks. Major and trace element data suggest that critically saturated alkali syenites occurring in both complexes evolved via protracted feldspar fractionation, and that critically saturated alkali-feldspar syenite occurring only in the GPC is a cumulate. The two rock types cannot be related genetically. Of the SI-oversaturated rocks in both complexes, those in the compositional range monzonite to granite were intruded before alkali-granites. Compositional diversity amongst the former reflects fractionation of feldspar and of mafic phases, but that process cannot genetically link the rocks to the alkali-granites. Isotopic compositions of Sr and Nd indicate that the silicate magmas were derived from an upper mantle source region characterised by low time-integrated Rb/Sr ratios and high time-Integrated Sm/Nd ratios, However, the evidence of Sr and 0 isotopic data is that the Si-oversaturated melts possibly interacted with a crustal component. presumably the Proterowlc rocks of the Namaqua Metamorphic Province. This interaction may explain the occurrence of apparently co-genetic rock series that evolved on opposite sides of the feldspar join in Petrogeny's Residua System. The Marinkas Kwela Carbonatite Complex was emplaced before the final intrusive phases of the MKC and exhibits unusually pronounced late-stage enrichment in manganese. The earliest intrusive rocks in the complex were nepheline syenites which were fenitised by later intrusions of sôvites. Although the commonly occurring magmatic sequence of sôvite-beforsite-ferrocarbonatite is observed at Marinkas Kwela, sôvites do not appear to have been parental to beforsites. Removal of apatite and early crystallisation of magnetite distinguish magnetite-rich beforsite from co-genetic apatite-rich beforsite. Two further magmatic sequences. the first from apatite-rich beforsite through ferrocarbonatite to Mn-rich ferrocarbonatite (high Fe/Mn) and the second from magnetite-rich beforsite to Mn-rich ferrocarbonatite (low Fe/Mn). reflect fractionation of dolomite and of dolomite+magnetite respectively.

Thesis (M.S.)--University of Rhode Island, 1974. / Includes bibliographical references.

Six alkalinity and oxidation classes of fresh igneous rocks were correlated with trace elements in rock chip samples from temporally and spatially associated ore deposits. Learning vector quantization and back-propagation artificial neural networks correctly classified 100 percent of whole rock oxides and 99 percent of mineralized samples; discriminant analysis correctly classified 96 and 83 percent, respectively. The high degree of correlation between chemistries of igneous rocks and related mineralization implies genetic links between magmatic processes or sources and the ore deposits studied. The petrochemical classification was evaluated by assigning 43 deposits to classes defined on eight variation diagrams, training neural networks to classify analyses of 569 igneous and 887 mineralized samples, and testing the networks on their ability to classify new data. Whole rock analyses were obtained from mining districts in which trace element geochemistry was also available. Half the data was eliminated using five alteration filter graphs. The K₂O and Fe₂O₃/FeO versus SiO₂ diagrams and iron mineralogy best defined alkalinity and oxidation classes. Neural networks trained with 90, 80, 70, or 50 percent of the samples correctly classified 81 to 100 percent of randomly withheld data. SiO₂/K₂O ratios of alkali-calcic igneous rocks are 14-20 and of calc-alkalic 20-30. Fe₂O₃/FeO ratios are >0.8 with abundant magnetite and sphene for oxidized, 0.5-1.2 with magnetite, sphene, and rare ilmenite for weakly oxidized, and <0.6 with ilmenite only in reduced subclasses. Lead-zinc-silver deposits as at Tombstone and Tintic are related to oxidized alkali-calcic igneous rocks. Polymetallic lead-zinc-copper-tin-silver deposits, such as Santa Eulalia and Tempiute, Nevada, are associated with weakly oxidized alkali-calcic rocks. Tin-silver deposits of Llallagua and Potosi are correlated with reduced alkali-calcic intrusives. Porphyry copper deposits as at Ray and Sierrita are connected with oxidized calc-alkalic plutons. Gold-rich porphyry copper deposits, such as Copper Canyon and Morenci are linked to weakly oxidized calc-alkalic plutons. Disseminated gold deposits, such as Chimney Creek, Nevada, are temporally and chemically correlated with reduced calc-alkalic igneous rocks, although physical connections between plutons and Carlin-type deposits remain unconfirmed. Magma series classification and neural networks have profound applications and implications to exploration, alteration and zoning studies, and metallogenesis.

Thesis (M.S.)--University of Hawaii at Manoa, 2004. / Includes bibliographical references (leaves 159-185). Also available via World Wide Web.

Thesis (M.S.)--University of Georgia, 2001. / Includes bibliographical references (leaves 74-78). Also available in electronic format via Internet.