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The Diploma thesis deals with the verification of Jominy end-quench test when analysis of hardenability of aluminium alloys is considered. The problem was solved experimentally, by developing end-quench curves of selected grades of aluminium alloys. Degree of hardenability of alloy is hardness after complete strengthening heat treatment. Samples of aluminium alloys commonly used for aircraft structures were prepared and then subjected to end-quench tests in various quenchants. On the basis of performed experiments, suitability of Jominy end-quench test for comparison of hardenability of alloys was found. Part of the thesis deals with the creation of equivalent cooling rate diagrams using the developed end-quench curves.

M. Tech. Metallurgical Engineering / Titanium and its alloys exhibit poor tribological characteristics. The poor resistance to sliding wear of Ti6Al4V alloy makes it susceptible to severe wear at the surface during sliding contact. This could cause galling and seizing during sliding contact. Ti6Al4V alloy also have poor corrosion resistance under critical conditions. Some problems with Ti6Al4V MMCs produced by laser cladding technique in most cases is poor bonding as a result of wetting properties between the ceramic and metal powders for reinforcement. Occurrence of porosity is another factor which can reduce the mechanical properties of MMCs. Occurrence of agglomerates is also a concern due to poor mixing of reinforcement powders. This project is aimed at investigating the effect of laser cladding of titanium alloy substrate with zirconium (Zr), titanium carbide (TiC), titanium (Ti) reinforcement additions. The effect of combination of these powders using various fractions and variable cladding parameters on the substrate will be investigated.

High entropy alloys (HEAs) is a concept wherein alloys are constructed with five or more elements mixed in equal proportions; these are also known as multi-principle elements (MPEs) or complex concentrated alloys (CCAs). This PhD thesis dissertation presents research conducted to develop precipitation-hardenable high entropy alloys using a much-studied fcc-based equi-atomic quaternary alloy (CoCrFeNi). Minor additions of aluminium make the alloy amenable for precipitating ordered intermetallic phases in an fcc matrix. Aluminum also affects grain growth kinetics and Hall-Petch hardenability. The use of a combinatorial approach for assessing composition-microstructure-property relationships in high entropy alloys, or more broadly in complex concentrated alloys; using laser deposited compositionally graded AlxCrCuFeNi2 (0 < x < 1.5) complex concentrated alloys as a candidate system. The composition gradient has been achieved from CrCuFeNi2 to Al1.5CrCuFeNi2 over a length of ~25 mm, deposited using the laser engineered net shaping process from a blend of elemental powders. With increasing Al content, there was a gradual change from an fcc-based microstructure (including the ordered L12 phase) to a bcc-based microstructure (including the ordered B2 phase), accompanied with a progressive increase in microhardness. Based on this combinatorial assessment, two promising fcc-based precipitation strengthened systems have been identified; Al0.3CuCrFeNi2 and Al0.3CoCrFeNi, and both compositions were subsequently thermo-mechanically processed via conventional techniques. The phase stability and mechanical properties of these alloys have been investigated and will be presented. Additionally, the activation energy for grain growth as a function of Al content in these complex alloys has also been investigated. Change in fcc grain growth kinetic was studied as a function of aluminum; the apparent activation energy for grain growth increases by about three times going from Al0.1CoCrFeNi (3% Al (at%)) to Al0.3CoCrFeNi. (7% Al (at%)). Furthermore, Al addition leads to the precipitation of highly refined ordered L12 (γ′) and B2 precipitates in Al0.3CoCrFeNi. A detailed investigation of precipitation of the ordered phases in Al0.3CoCrFeNi and their thermal stability is done using atom probe tomography (APT), transmission electron microscopy (TEM) and Synchrotron X-ray in situ and ex situ analyses. The alloy strengthened via grain boundary strengthening following the Hall-Petch relationship offers a large increment of strength with small variation in grain size. Tensile strength of the Al0.3CoFeNi is increased by 50% on precipitation fine-scale γ′ precipitates. Furthermore, precipitation of bcc based ordered phase B2 in Al0.3CoCrFeNi can further strengthen the alloy. Fine-tuning the microstructure by thermo-mechanical treatments achieved a wide range of mechanical properties in the same alloy. The Al0.3CoCrFeNi HEA exhibited ultimate tensile strength (UTS) of ~250 MPa and ductility of ~65%; a UTS of ~1100 MPa and ductility of ~30%; and a UTS of 1850 MPa and a ductility of 5% after various thermo-mechanical treatments. Grain sizes, precipitates type and size scales manipulated in the alloy result in different strength ductility combinations. Henceforth, the alloy presents a fertile ground for development by grain boundary strengthening and precipitation strengthening, and offers very high activation energy of grain growth aptly suitable for high-temperature applications.