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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
1

Freestanding graphite cathode with graphene additive for aluminum dual-ion batteries

Rosvall, Adam January 2023 (has links)
In today’s fast adjustment to renewable energy, new battery technologies are needed to meetthe ever-growing demands of energy storage. Cheaper and easier to produce materials areneeded, as well as materials with a lower environmental impact. One new and interestingtechnology is the dual-ion battery, and more specifically the aluminum dual-ion battery. Thisbattery uses cheap and abundant aluminum together with a graphitic cathode to work. However,a lot of research today uses expensive and sophisticated cathode materials to make this type ofbattery work. Therefore, this thesis focuses on creating a cheap and easy to produce graphitecathode material through the phase inversion method for the use in aluminum dual-ionbatteries, that is also freestanding for better energy density. Graphene is also used as anadditive to improve the electrical conductivity of the material, and the material is later tested in afull cell with the typical ionc liquid electrolyte EMImCL/AlCl4.Through phase inversion, a freestanding graphite cathode is produced with 8 wt% PVDF binderand 0.4 wt% graphene. The material has a porous structure and an enhanced electricalconductivity with the graphene added. Through CV cycling and symmetric Al-Al tests the batteryreactions are shown to work. However, when cycling the cell with a constant current there areproblems, probably coming from some sort of soft shorting or side reactions. It is revealed thatapart from the expected reactions, Ni dissolution from the contact tabs also takes place, andmay cause problems. Further tests are needed to validate if this material works. However,because no new active materials have been introduced to the battery chemistry, it is reasonableto believe that the battery will work with some small changes.Tek nisk-naturvetensk apliga fak ulteten, Upps ala universitet. Utgiv nings ort U pps al a/Vis by . H andledare: Anwar Ahniy az , Äm nesgranskar e: D aniel Brandell, Ex aminator: Lena Klintberg

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