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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
1

Investigation of the acid-catalyzed reactions of arylhydroxylamines

Hartzell, Stephen L. 03 June 2011 (has links)
AbstractEugen Bomberger's original work was concerned with the rearrangement of the substituted N-phenylhydroxylamines, but the mechanism responsible for the wide variety of products has remained unsettled.First, this investigation was concerned with a suitable synthesis for the substituted N-alkyl-N-phenylhydroxylamines. Secondly, a better understanding of the mechanism could be accomplished by the identification of the decomposition products and through a kinetic study of the rearrangement utilizing ultraviolet spectroscopy. The study was successful with the product identification of five decomposed substituted N-.phenylhydroxylamines, but numerous products, which interfered with the kinetic study, were isolated from the rearrangement and only uninterpretable kinetic data could be collected.Ball State UniversityMuncie, IN 47306

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