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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
1

A multi -transition study of the cyclic molecule cyclopropenylidene C(3)H(2) in the galaxy

Madden, Suzanne C 01 January 1990 (has links)
We report results of multi-transition observations and modeling of the hydrocarbon ring molecule cyclopropenylidene (C$\sb3$H$\sb2$). From a survey of the 1$\sb{10}$-1$\sb{01}$ (18 GHz) and 2$\sb{12}$-1$\sb{01}$ (85 GHz) transitions in the Galaxy, we have found C$\sb3$H$\sb2$ present in a variety of sources including cold, dark clouds, giant molecular clouds, the envelope of a carbon star, and diffuse clouds. Up to 10 transitions of C$\sb3$H$\sb2$ ranging in wavelength from 1.3 cm to 1.3 mm were observed in the dark clouds L1498, L134N, B335 and toward several positions in TMC-1. The Large Velocity Gradient (LVG) approximation was used to model the observations. Optical depth values of C$\sb3$H$\sb2$, estimated from C$\sp{13}$C$\sb2$H$\sb2$ observations, are necessary to constrain the results since the range in excitation energies of the observed C$\sb3$H$\sb2$ transitions does not contrast sufficiently. The molecular hydrogen density in TMC-1 is estimated to be 3.7 $\times$ 10$\sp4$ cm$\sp{-3}$, while the fractional abundance of C${\sb3}$H$\sb2$ relative to H$\sb2$ is 5.7 $\times$ 10$\sp{-9}$. Previous estimates assuming LTE conditions overestimate the abundance of C$\sb3$H$\sb2$. The abundance in the ridge component in Orion is estimated to be approximately 8 $\times$ 10$\sp{-10}$ cm $\sp{-2}$. Gas phase chemical models can reproduce the high C$\sb3$H$\sb2$ abundance found in dark clouds under assumptions such as steady state conditions with (C) / (O) / $>$ 1.0, conditions of earlier evolutionary time, or 'optimistic' rate coefficients. However, large deuteration ratios (0.05 to 0.15) create difficulties for gas phase models.

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