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Stereoselective hydroaminations of unactivated alkenes are rare as this represents a very challenging synthetic transformation. The most efficient examples occur in biased intramolecular systems and highly enantioselective intermolecular examples are rare, which is consistent with the forcing conditions required to catalyze the reactions. This limited reactivity also accounts for the lack of highly diastereoselective hydroamination variants. Recently our group has shown that intermolecular Cope-Type hydroamination of unactivated alkenes can be achieved using simple aldehydes as catalysts. The aldehyde promotes pre-association of the two reaction partners, inducing temporary intramolecularity resulting in a remarkably facile hydroamination event. This thesis will present the development of two reactions: intermolecular enantioselective Cope-type hydroamination and intermolecular diastereoselective Cope-type hydroamination of allylic amines.

Bibliography : leaves 200-206. / iv, 206 leaves ; 30 cm. / Title page, contents and abstract only. The complete thesis in print form is available from the University Library. / Covers the asymmetric synthesis of 2-arylpropanoic acids including ketoprofen, ibuprofen, ximoprofen. / Thesis (Ph.D.)--University of Adelaide, Dept. of Chemistry, 1995

Bibliography: leaves 213-218. / v, 218 leaves ; 30 cm. / Title page, contents and abstract only. The complete thesis in print form is available from the University Library. / Thesis (Ph.D.)--University of Adelaide, Dept. of Organic Chemistry, 1993

Thesis (Ph.D.)--University of Wollongong, 2003. / Typescript. Includes bibliographical references: leaf 214-222.

Diss. Stockholm : Handelshögskolan, 2006.

Thesis (Ph. D.)--Michigan State University. Dept. of Chemistry, 2008. / Title from PDF t.p. (viewed on Mar. 30, 2009) Includes bibliographical references (p. 375-386). Also issued in print.

Thesis (Ph.D.)--University of Wollongong, 2004. / Typescript. Includes bibliographical references: leaf 236-249.

Thesis (M.S.)--West Virginia University, 2007. / Title from document title page. Document formatted into pages; contains x, 67 p. : ill. (some col.). Includes abstract. Includes bibliographical references (p. 37-38).

Thesis (M.S. in Modeling, Virtual Environments and Simulation (MOVES))--Naval Postgraduate School, September 2009. / Thesis Advisor(s): Sanchez, Paul J. ; Second Reader: Kline, Jeffrey E. "September 2009." Author(s) subject terms: Agent Based Simulation, Asymmetric Warfare, Data Farming, Design of Experiments, Evolving Design, MANA, Modeling and Simulation, Naval Swarm Defense, Robust Design, Regression Analysis, Simulation Experiments and Efficient Design Center, Taguchi Method Description based on title screen as viewed on November 03, 2009. DTIC Descriptor (s): Frigates, Theater Level Operations, Defense Systems, Experimental Design, Confined Environments, Asymmetry, Statistical Analysis, Sea Water, Small Ships, Threats, Survivability, Weapons, Theses DTIC Identifier (s): SSTR (Stability Security Transition and Reconstruction), Asymmetric Warfare, Mana Includes bibliographical references (p. 125-132). Also available in print.