Methane (CH4) is one of the most important greenhouse gases after water vapor and carbon dioxide due to its high concentration and global warming potential 25 times than that of CO2 (based on a 100 year time horizon). Its atmospheric concentration has more than doubled from the preindustrial era due to anthropogenic activities such as rice cultivation, biomass burning, and fossil fuel production. However, the rate of increase of atmospheric CH4 (or the growth rate) slowed from 1980 until present. The main reason for this trend is a slowdown in the trend of CH4 sources. Measuring stable isotopes of atmospheric CH4 can constrain changes of CH4 sources. The main goal of this work is to interpret the CH4 trend from 1978-2010 in terms of its sources using measurements of CH4 mixing ratio and its isotopes. The current work presents the measurements and analysis of CH4 and its isotopes (δ13C and δD) of four air archive sample sets collected by the Oregon Graduate Institute (OGI). CH4 isotope ratios (δ13C and δD) were measured by a continuous flow isotope ratio mass spectrometer technique developed at PSU. The first set is for Cape Meares, Oregon which is the oldest and longest set and spans 1977-1999. The integrity of this sample set was evaluated by comparing between our measured CH4 mixing ratio values with those measured values by OGI and was found to be stable. Resulting CH4 seasonal cycle was evaluated from the Cape Meares data. The CH4 seasonal cycle shows a broad maximum during October-April and a minimum between July and August. The seasonal cycles of δ13C and δD have maximum values in May for δ13C and in July for δD and minimum values between September-October for δ13C and in October for δD. These results indicate a CH4 source that is more enriched January-May (e.g. biomass burning) and a source that is more depleted August-October (e.g. microbial). In addition to Cape Meares, air archive sets were analyzed from: South Pole (SPO), Samoa (SMO), Mauna Loa (MLO) 1992-1996. The presented δD measurements are unique measured values during these time periods at these stations. To obtain the long-term in isotopic CH4 from 1978-2010, other datasets of Northern Hemisphere mid-latitude sites are included with Cape Meares. These sites are Olympic Peninsula, Washington; Montaña de Oro, California; and Niwot Ridge, Colorado. The seasonal cycles of CH4 and its isotopes from the composite dataset have the same phase and amplitudes as the Cape Meares site. CH4 growth rate shows a decrease over time 1978-2010 with three main spikes in 1992, 1998, and 2003 consistent with the literature from the global trend. CH4 lifetime is estimated to 9.7 yrs. The δ13C trend in the composite data shows a slow increase from 1978-1987, a more rapid rate of change 1987-2005, and a gradual depletion during 2005-2010. The δD trend in the composite data shows a gradual increase during 1978-2001 and decrease from 2001-2005. From these results, the global CH4 emissions are estimated and show a leveling off sources 1982-2010 with two large peak anomalies in 1998 and 2003. The global average δ13C and δD of CH4 sources are estimated from measured values. The results of these calculations indicate that there is more than one source which controls the decrease in the global CH4 trend. From 1982-2001, δ13C and δD of CH4 sources becomes more depleted due to a decrease in fossil and/or biomass burning sources relative to microbial sources. From 2005-2010, δ13C of CH4 sources returns to its 1981 value. There are two significant peaks in δ13C and δD of CH4 sources in 1998 and 2003 due to the wildfire emissions in boreal areas and in Europe.

The Community Earth System Model (CESM) is a coupling of five different models which are combined to simulate the dynamic interactions between and within the Earth's atmosphere, ocean, land, land-ice, and sea-ice. In this work, the installation and testing of CESM on Portland State University's Cluster for Climate Change and Aerosol Research (CsAR) is described and documented, and two research applications of the model are performed. First, the improved treatment of cloud microphysics within recent versions of CESM's atmospheric module is applied to an examination of changes in shortwave cloud forcing (SWCF) and results are compared to output from older versions of the model. Second, the CESM model is applied to an examination of the effect that increased methane (CH4) concentrations have had on the catalytic destruction of stratospheric ozone (O3) by ozone depleting compounds (ODCs) such as chlorofluorocarbons (CFCs) and nitrous oxide (N2O).

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The main goals of this study were to document the structural and functional recovery of differently restored areas, to understand better the relationship between the two, and to determine which types of measurements are best for assessing restoration success. To address these questions, an experimental system was created through topsoil removal and subsequent restoration in a blocked, completely randomized design using two levels of soil amendment (with or without 10 kg of leaf mulch per m2) and three levels of seeding treatment (no seed, a standard reclamation mix, and an alternative, wildflower dominated reclamation mix). All measurements were designed to document responses due to restoration treatment in comparison to adjacent, undisturbed, reference sites. Vegetation structure in amended sites, as measured by total vegetation cover and species richness, recovered to levels similar to references within the two years of the study. Plant community composition did not develop similarity to references in any experimental treatments. Both soil amendment and seeding type affected cellulose decomposition rates, with amended plots showing higher decomposition rates than unamended, and seeded plots exhibiting higher rates than unseeded. Enzyme activities were largely determined by soil amendment, but the reference plots consistently had higher enzymatic activity. Amended sites exhibited significant increases over time in soil respiration, reaching or surpassing the rates observed in reference areas. Methane oxidation rates were generally increased in disturbed plots compared to undisturbed references due to increased atmospheric diffusion into the soil. Amended areas exhibited depressed rates relative to unamended, and seeding level had no significant effect on methane oxidation. Over all measurements, restoration of ecosystem function was most facilitated by the addition of the soil amendment. Seeding treatment significantly altered the resultant plant community, which may have substantial, long-term consequences for succession. The inclusion of functional parameters into restoration assessment provides for better overall information concerning ecosystem performance and may add to the ability to predict long-term success of restoration efforts. / Ph. D.

Most global and regional "greenhouse gas" budgets have neglected beaver ponds, but they have been found to be relatively high emitters of methane (CH$ sb4$) (Roulet et. al., 1992). Static chambers, bubble traps, benthic chambers. piezometers, and water column and sediment profiles were used to determine the dynamics of CH$ sb4$ production, oxidation, storage, and emissions from a northern boreal beaver pond, as part of the Boreal Forest Ecosystem-Atmosphere Study (BOREAS) from May 1 to September 15, 1994. Samples were analysed by gas chromatography, and isotopic analyses were performed by mass spectrometry. / The mean flux of CH$ sb4$ from the beaver pond (155 and 320 mg CH$ sb4$ m$ sp{-2}$ d$ sp{-1}$ for vegetated and open water sites, respectively) was greater than the flux from most other northern boreal wetlands (Bubier et. al., 1995). CH$ sb4$ availability was primarily controlled by sediment temperature, and CH$ sb4$ transport was controlled by windspeed (diffusion) and atmospheric pressure (bubbles). Bubbles comprised 20 to 52% of the net annual flux comprising the remainder. A large difference in bubble flux was observed between open water (15.7 g CH$ sb4$ m$ sp{-2}$ yr$ sp{-1}$) and vegetated sites (2.9 g CH$ sb4$ m$ sp{-2}$ yr$ sp{-1}$), and isotopic analyses indicate that this difference is due, in part, to a difference in CH$ sb4$ production pathways between sites. Greater oxidation also reduced the CH$ sb4$ flux from shallow, vegetated sites. / A preliminary CH$ sb4$ budget for the BOREAS northern study area indicates that beaver ponds contribute significantly (6% to 30%) to the regional CH$ sb4$ flux. The areal extent of beaver ponds needs to be determined for inclusion in regional and global CH$ sb4$ budgets.

Carbon dioxide (CO2) and methane (CH4) fluxes from the soil surface, and concentrations within the soil profile, were measured between June 1998 and Sept. 1999 at four adjacent forest plantations and an old field in Nepean, Ontario. The objectives of this study were to quantify seasonal CO2 and CH4 fluxes from the soil surface and within the soil profile to determine the effect of soil moisture and temperature, and forest age and species on the exchange, and establish a chronosequence of organic carbon accumulation in the forest plantations and the old field soils. / Dynamic and static chamber techniques were used to measure surface fluxes of CO2 and CH4, respectively, and soil gas concentrations were sampled with probes. In the old field and forest plantations, surface soil CO2 flux ranged from 2.9 to 27 g CO2 m-2 d-1 and 2.0 to 39 g CO2 m -2 d-1 respectively. Significant differences due to age and species of plantation were observed. Seasonal variations in CO2 efflux from the soil surface and within the soil profile were related to variation in soil temperature and moisture. Uptake of CH4 was observed at all sites and there was no significant differences in flux due to vegetation type or age. Maximum rate of CH4 consumption was 6.3 mg CH4 m-2 d-1. Methane uptake was positively related to soil moisture conditions. / The carbon content of the soil increased in all sites following the establishment of vegetation on sandy parent material. Carbon content was greatest in the upper soil profile. Rates of carbon accumulation ranged from 109 to 426 g m-2 y-1. Soil carbon increased with increasing age of plantation during the first 30 years following the establishment of vegetation on parent material, but declined as the forest plantation matured.

A climate controlled, dynamic chamber was used to measure carbon dioxide (CO$ sb2$) and methane (CH$ sb4$) exchange on an ombrotrophic peatland. The study periods were July to early November 1995, and early May to July 1996. Five sample sites, showing ecological and hydrological contrast, were investigated. Measurements of Net Ecosystem Exchange showed peak photosynthetic capacity (GP$ sb{ max})$ ranging from 0.52 $ pm$ 0.04 mg C m$ sp{-2}$ s$ sp{-1}$ (June 1996) to 0.03 $ pm$ 0.02 mg C m$ sp{-2}$ s$ sp{-1}$ (early November 1995). Dark respiration measurements ranged from $-$0.21 $ pm$.02 mg C m$ sp{-2}$ s$ sp{-1}$ (June 1996) to $-$0.02 $ pm$.01 mg C m$ sp{-2}$ s$ sp{-1}$ (late May 1996), and showed significant relationships to soil temperature at all sites. Site average methane measurements ranged from 29-72 mg m$ sp{-2}$ d$ sp{-1}$, and showed a strong relationship to water table on a seasonal basis, but a poor correlation to simultaneous NEE. Modelled Net Ecosystem Productivity (NEP) among sites ranged from 17.1 to 115 gC over the entire study period. The CO$ sb2$ exchanges in late spring and early fall made a large contribution to the figure due to the imbalance in the photosynthetic and dark respiration components of the carbon budget. No discernible relationship was found between seasonal NEP and methane release. The results suggest a large importance of the extreme ends of the growing season in an analysis of the carbon budget of peatlands, periods hitherto little investigated. They also suggest that NEP/methane connections may be restricted in their significance to mainly flooded mires.

Although the dynamics of methane (CH4) emission from croplands and wetlands have been fairly well investigated, the contribution of trees to global methane emission and the mechanisms of tree transport are relatively unknown. Methane emissions from the common wetland tree species Populus trichocarpa (black cottonwood) native to the Pacific Northwest were measured under hydroponic conditions in order to separate plant transport mechanisms from the influence of soil processes. Roots were exposed to methane enriched water and canopy emissions of methane were measured using a canopy enclosure. Methane accumulation in the canopy was generally linear and the average canopy methane flux was 3.0 ± 2.6 μg CH4 min-1. Flux magnitudes from stem experiments scaled to the area of the main tree stem are comparable to whole-canopy flux values, indicating that the majority of methane emitted from the tree leaves through the stem. Samples for stable carbon isotope composition were taken during the canopy experiments. Compared to the isotopic composition of root water methane, canopy methane was depleted in 13C on average by 8.6 ± 3.3 permil; this indicates that methane moving through the tree is not following a purely bulk flow pathway (where no depletion would occur), but is instead subject to at least one fractionating mechanism. When temperature was varied, the flux at the coolest temperature was significantly different from the higher flux at the warmest temperature (p-value less than 0.02). The calculated Q10 for methane flux was 2.4, which indicates a positive feedback with temperature increase. Analysis of δ13C values of emitted CH4 in the temperature experiments shows increasing depletion with cooler temperatures and lower flux. This indicates that not only does the magnitude of flux vary with temperature, but the actual dominant transport mechanism changes as well.