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This collection consists of a critical preface and nine essays. The preface analyzes, first, how the imagination influences the personal journey of a writer, and second, the techniques authors use, mainly form, time, and space, to enact the imagination and propel the reader into an imagined narrative. The essays explore themes of loss, mental illness, the rift between the “real” and the “imagined” life, and the intangibility of memory itself. Collection includes the essays “Into the Snow,” “No Longer a Part,” “Borderland,” “Still Wounds,” “What Stays in Las Vegas,” “Remnants,” “The Root,” “Your Father,” and “The Land Lord.”

This thesis examines the impact of the physical contamination on optical surfaces of spacecraft by an ABS/GOX thruster. Plume contamination presents a significant operational hazard for spacecraft solar arrays and thermal control surfaces can lead to decreased power production and increased spacecraft temperatures. Historically, due to the lack of a reliable, on-demand, and multiple-use ignition methodology, hybrid rockets have never been previously considered for in-space propulsion. Recent advancements in hybrid rocket technologies, have made hybrid systems feasible for in space propulsion. However, prior to this study no research had ever been performed with regard to plume contamination effects due to hybrid rockets. This paper presents the results from a set of preliminary plume contamination measurements on a prototype small spacecraft hybrid rocket system, collected under both ambient and vacuum chamber conditions.

In many drinking water systems in the United States, disinfectant is added to water as it leaves the plant to maintain a residual concentration in the distribution system. The disinfectant residual is maintained to inactivate contamination that enters the distribution system, to control biofilms, and to act as a sentinel for contamination in the distribution system. A model was developed to evaluate the potential effectiveness of the disinfectant residual at inactivating contamination. The model was used to examine contamination of a hypothetical distribution system through backpressure at a cross-connection under different operating conditions. The dilution and pathway of the hypothetical contaminant were examined as the contaminant moved through the system. Disinfection and inactivation kinetic relationships were used to model the inactivation of the contaminant in the system by the amount of disinfectant present. The model showed that both chlorine and chloramines in each decay and inactivation condition considered provided some benefit over no disinfectant at all when examining susceptible organisms. Chlorine, under medium and low decay conditions, provided the best inactivation. Where 29.8% of total node time steps received a contamination of concern in the absence of disinfectant residual, as low as 4.8% of total node time steps received a contamination of concern in the presence of disinfectant residual. Chloramines was found to persist longer in the distribution system, but resulted in much lower inactivation compared to chlorine. Disinfectant doses typical of common distribution system operation were able to reduce the impact of contamination once it entered the distribution system but, except for four cases, were unable to prevent contamination from spreading within the distribution system. Therefore, it was concluded that presence of a disinfectant residual will reduce the total number of exposure opportunities from a contamination event, but cannot be relied upon to eliminate the chance of exposure resulting from contamination. / Master of Science

The storm surge from Hurricane Ike inundated Bolivar Peninsula as well as pooled up (~4 meters above sea level) in the Galveston Bay System behind Bolivar. After the hurricane passed, this water flowed back over the peninsula for about 19 hours, causing a great deal of coastal destruction. Analysis of post-Hurricane Ike aerial photography and Lidar data revealed the development of dramatically different scour and backflow features in the beach and dune environments along Bolivar Peninsula, Texas. Using Ward's cluster analysis, the 454 identified features were grouped according to shape and size characteristics generated by an object-oriented shape analysis program. Five distinct groups of features emerged from the cluster analysis. Group 1 features were small and compact, distributed mostly in the west; Group 2 features were large and dendritic in nature, distributed where the peninsula was narrow. Group 3 features had a longshore orientation with many of them resembling piano keys, distributed in the east. Group 4 features were oriented longshore and ornate in shape. Many of them were similar in shape to Group 2 or 3 features though statistically different enough to be grouped alone; they were distributed mostly in the eastern half of the study area. Group 5 features tended to be elongated, oriented cross-shore, nonbranching, and distributed mostly in the east. At least four flow environments caused characteristic forms. The first flow environment is typified by seaward flowing water encountering a road parallel with the coastline. The water flowing over the road scours deeply on the leeward side (seaward side), denuding beach sediments down to the resistant mud layer (Groups 3 and 4). The second flow environment was caused by a geotube, which breached during the storm and channelized flow through the breaches (Groups 2 and 5). The third flow environment had a comparatively high elevation, high development, and shore-perpendicular roads (Group 2). The fourth flow environment was typified by wide beaches backed by dunes (lost in the storm) as well as flat vegetated areas. Water flowing seaward over the vegetation scoured deeply into troughs after it came off the vegetation (Groups 1, 3, and 4).

Inducer performance is investigated for a variety of inducer geometries operating at multiple flow conditions using computational fluid dynamics. Inducers are used as a first stage in turbopumps to minimize cavitation and allow the pump to operate at lower inlet head conditions. The formation of inlet flow recirculation or backflow in the inducer occurs at low flow conditions and can lead to instabilities and cavitation-induced head breakdown. Backflow formation is often attributed to tip leakage flow. The performance of an inducer with and without tip clearance is examined. Removing the tip clearance eliminates tip leakage flow; however, backflow is still observed. Analysis suggests that blade inlet diffusion, not tip leakage flow, is the fundamental mechanism leading to the formation of backflow. Performance improvements in turbopump systems pumping cold water have been obtained through implementation of a recirculation channel called a stability control device (SCD). However, many inducers actually pump cryogenic fluids, such as liquid hydrogen. To determine the real world effects of SCD implementation, inducer performance at on and off design flow coefficients with and without an SCD were modeled with liquid hydrogen as the working fluid. Relevant thermodynamic effects present in liquid hydrogen at cryogenic temperatures are considered. The results reveal that the SCD yields marginal changes in the head coefficient. However, a stabilizing effect occurs at all considered flow coefficients, where a reduction in backflow occurs over much of the pump operational range. This occurs due to the SCD maintaining consistent, low incidence angles at the inducer leading edge.The final consideration of this work is the acceleration of an inducer from rest to the operating rotational rate. Rapid acceleration of rocket engine turbopumps during start-up imparts significant transient effects to the resulting flow field, causing pump performance to vary widely when compared to quasi-steady operation. A method to simulate turbopump start-up using CFD is developed and presented. The defined outlet pressure is modified based on the difference between simulation inlet pressure and target inlet pressure of a previous simulation. This process is repeated until simulation inlet pressure is essentially constant during start-up. Using this novel simulation method, the performance of a centrifugal turbopump during start-up is simulated. Analysis suggests this simulation method provides a reasonable prediction of cavitation formation and inducer performance.

Additive manufacturing (AM) is a rapidly growing and evolving form of product development that has the potential to revolutionize both the industrial and academic spheres. For example, AM offers much greater freedom of design while producing significantly less waste than most traditional manufacturing techniques such as injection and blow molding. Filament-based material extrusion AM, commonly referred to as fused filament fabrication (FFF), is one of the most well-known AM modalities using a polymeric feedstock; however, several obstacles currently prohibit widespread use of this manufacturing technique to produce end-use products, which will be discussed in this dissertation. Specifically, a severely limited material catalog restricts tailored product development and the variety of applications. Additionally, poor interlayer adhesion results in anisotropic mechanical properties which can lead to failure, an issue not often observed in traditional manufacturing techniques. A review of the current state of the art research in the field of FFF, focusing on the multiphysics-based modeling of the system and exploring some empirically determined relationships, is presented herein to provide a more thorough understanding of FFF and its complexities. This review further guides the work discussed in this dissertation. The primary focus of this dissertation is to expand the fundamental understanding of the FFF process, which has proven difficult to measure directly. On this size scale, introduction of measurement devices such as thermocouples and pressure transducers can significantly alter the behavior of the process or require major changes to the geometry of the system, leading to spurious measurements, incorrect outcomes, and/or conclusions. Therefore, the research presented in this dissertation focuses on the development and validation of predictive models based on first principles approaches that can provide information leading to the optimization of printing parameters and exploration of novel and/or modified materials without an exhaustive and inefficient trial-and-error process. The first potential issue a novel material may experience in FFF is an inability to extrude from the heated nozzle. Prior to this work, no efforts were focused on the molten material inside the liquefier and its propensity to flow in the reverse direction through the annular region between the filament and the nozzle wall, referred to as annular backflow. The study presented in this dissertation explores this phenomenon, determining its cause and sensitivity to processing parameters and material properties. A dimensionless number, named the "Flow Identification Number" or FIN, is defined that can predict the propensity to backflow based on the material's shear thinning behavior, the filament diameter, the nozzle diameter, and the filament feed rate and subsequent pressure inside the nozzle. An analysis of the FIN suggested that the backflow potential of a given material is most sensitive to the filament diameter and its shear thinning behavior (power law index). The predictive model and FIN were explored using three materials with significantly different onsets of shear thinning. The experiments validated both the backflow model and a previously derived buckling model, leading to the development of a rapid screening technique to efficiently estimate the extrudability of a material in FFF. Following extrusion from the nozzle, the temperature profile of the deposited filament will determine nearly all of the mechanical properties of the printed part as well as the geometry of the individual roads and layers because of its temperature dependent viscoelastic behavior. Therefore, to better understand the influence of the temperature profile on the evolution of the road geometry and subsequent interlayer bonding, a three-dimensional finite element heat transfer analysis was developed. The focus of this study is the high use temperature engineering thermoplastic polymer polyetherimide, specifically Ultem™ 1010, which had not been studied in prior modeling analyses but presents significant challenges in terms of large thermal gradients and challenging AM machine requirements. Through this analysis, it was discovered that convective cooling dominated the heat transfer (on the desktop FFF scale) producing a significant cross-sectional temperature gradient, whereas the gradient along the axis was observed to be significantly smaller. However, these results highlighted a primary limitation in computer modeling based on computational time requirements. This study, utilizing a well-defined three-dimensional model based on a geometry measured empirically, produced results describing 0.5 s of printing time in the printing process and elucidated great details in the road shape and thermal profile, but required more than a week of computation time, suggesting a need for to modify the modeling approach while still accurately capturing the physics of the FFF layer deposition process. The determination of the extensive time required to converge the three-dimensional model, as well as the identification of a relative lack of axial thermal transfer, led to the development of a two-dimensional, cross-sectional heat transfer analysis based on a finite difference approach. This analysis was coupled with a diffusion model and a stress development model to estimate the recovery of the bulk strength and warping potential of a printed part, respectively. Through this analysis, it was determined that a deposited road may remain above Tg for 2-10 s, depending on the layer time, or time required for the nozzle to pass a specific point in the x-y plane between each layer. The predicted strength recovery was significantly overestimated, leading to the discovery of the extreme sensitivity of the predictive models to the relaxation time of a material, particularly at long layer times. When the deposited filament has enough time to attain an equilibrium temperature, small changes in the relaxation time of the material resulted in significant changes in the predicted healing results. These results highlight the need for exact estimations of the material parameters to accurately predict the properties of the final print. / Doctor of Philosophy / Additive manufacturing (AM), particularly filament-based material extrusion additive manufacturing, commonly known as fused filament fabrication (FFF), has recently become the subject of much study with the goal of utilizing it to produce parts tailored to specific purposes quickly and cheaply. AM is especially suited to this purpose due to its ability to produce highly complex parts with the ability to change design very easily. Furthermore, AM typically produces less waste than many traditional manufacturing techniques due to the process building a part layer by layer rather than removing unneeded material from a larger piece, resulting in a cheaper process. These freedoms make AM, and FFF in particular, highly prized among industrial producers. However, numerous challenges prevent the adoption of FFF by these companies. Particularly, a lack of available material options and anisotropic material properties lead to issues when attempting to produce a part targeted for use in a specific field. FFF is primarily commercially limited to two materials: polylactic acid (PLA) and acrylonitrile-butadiene-styrene (ABS) with a few other materials available in more specialized fields. However, essentially all these materials are limited to low use temperatures (less than 300 °C) and are primarily amorphous or with nearly negligible amounts of crystallinity. This severely limits the ability to tailor a printed part to a specific purpose and restricts the use of printed parts to applications requiring very low strengths. This is one reason why FFF, and most types of AM, is limited to the prototyping field rather than end-use applications. The other reason, anisotropic mechanical properties, is caused by the building methodology of AM. Creating a part layer by layer naturally introduces potential areas of weakness at the joining of the layers. If bulk properties are not recovered, the interlayer bond acts as a stress concentrator under load and will break before the bulk material. The work presented in this dissertation proposes methods to better understand the FFF system in order to address these two issues, leading to the optimization of the printing process and ability to expand the material catalog, particularly in the direction of high use temperature materials. The research discussed herein attempts to develop predictive models that may allow exploration into the FFF system which can be difficult to do experimentally, and by predicting the properties of a printed part, the models can guide future experimentation in FFF without the need for an extensive trial-and-error process. The work presented in this dissertation includes exploring the flow phenomena inside the FFF nozzle to determine extrudability as well as two-dimension and three-dimension heat transfer models with the goal of describing the viscoelastic, flow, diffusion, and stress development phenomena present in FFF.

A computational model is developed to investigate fundamental flow physics and transport phenomena of evaporating wavy-laminar falling liquid films of water and black liquor. The computational model is formulated from first principles based on the conservation laws for mass, momentum, energy and species in addition to a phase transport equation for capturing interface deformation and evolution. Free surface waves are generated by monochromatic perturbation of velocity. Continuum models for interfacial evaporation define source terms for liquid vaporization and species enrichment in the conservation laws. A phenomenological crystallization model is derived to account for species depletion due to salt precipitation during black liquor falling film evaporation. Using highly resolved numerical grids on parallel computers, the computational model is implemented to analyze the dynamics of capillary separation eddies in low Reynolds number falling films, investigate the dominant mechanisms of heat transfer enhancement in falling films at moderately high Reynolds numbers and study the fundamental wave structures and wave induced transport in black liquor falling films on flat and cylindrical walls. From simulation results, a theory based on the dynamics of wavefront streamwise pressure gradient is proposed to explain interfacial waves interaction that give rise to multiple backflow regions in films dominated by solitary-capillary waves. The study shows that the mechanism of heat transfer enhancement in moderately high Reynolds number films follows from relatively lower conduction thermal resistance and higher crosswise convective transport at newly formed intermediate wavefronts. Interfacial phenomena such as wave-breaking and vapor entrainment observed in black liquor falling films is explained in terms of a mechanistic theory based on evolution of secondary instabilities and large amplitude wave force imbalances.

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