The wakes behind a variety ofaxisymmenic bodies were investigated with flow visualization and hot-wire measurements. The main objective of this study was to correlate changes in the time-averaged features of the wake with changes in the characteristics of the coherent large-scale structure resulting from changing the solidity of the wake generator or by introducing periodic disturbances to force the wake. The use of an axisymmenic probe holder permitted instantaneous decomposition of the axialvelocity field into temporal and azimuthal Fourier modes. Increases in the body solidity resulted in nearly proportional increases in the size of the mean wake boundary. For the non-shedding (low body solidity) wakes, flow visualization shows that the amplitude of discernible large-scale structure is small in comparison to the wake diameter, and there is no evidence of a recirculation region. For the shedding wakes, flow visualization reveals large-scale structure with amplitude that is comparable in size to the wake diameter, and a recirculation region is observed that oscillates in axial extent Fourier analysis of velocity measurements discloses that the temporal scale of the coherent large-scale structure for a non-shedding wake decreases in value with downstream distance while the corresponding scale for a shedding wake is constant Significant changes in the both the time-averaged features of the wake and in the large-scale structure usually occurred only when the forcing frequency was near the natural shedding frequency (within ± 25%). Those time-averaged features changed by forcing include the drag, the mean- and variance-profile shapes, and the size of the wake. The mean profile was observed to change from a regular shape to that which resembles a variance profile. Forcing results in a number of peaks being present in 2-D spectra plots, most of which are the result of non-linear interactions of the forcing wave with the natural shedding frequency. The flow visualization reveals that those peaks which are harmonics or subharmonics of the forcing frequency may be more prominent than the forcing frequency if they are closer to the natural shedding frequency of the unforced wake.

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No description available.

Published Article / A stream flow at an outlet of a catchment can be entirely a base flow or direct flow or a combination of both. The base flow component of a stream is mainly contributed from the ground water storage which often is an open aquifer whereas the direct flow component is mainly the result of a direct response of a rainfall event. The Upper Modder river basin catchment is considered to be the origin of the Modder River which supplies water to Rustfontein Dam, situated at the outlet of the C52A with an area of 928 km2. Nine years of daily stream flow showed a continuous none zero discharge throughout the year. During the rainy season the discharge of the stream increases significantly. Thus, it is necessary to separate the direct and base flow of the stream in order to understand the important component that is more likely to be affected by different land use changes in a catchment. The Modder river daily mean flow at the inlet of Rustfontein dam (in Central South Africa) was analysed using four base flow separation methods, the Nathan & McMahon (N&M), the Chapman, Smakhtin & Watkins (S&W) method and the frequency duration analysis. All the methods gave higher percentage of the low flow component, except for the S&W method which underestimated it. The N&M filtering equation gave base flow components greater than 66% in 1999 and increased to 84% in 2007 while the Chapman equation revealed 65% and 74% in 1999 and 2007, respectively. Similarly, the frequency duration analysis gave 62% in 1999 and increased to 79% in 2007. The frequency duration analysis gave up to 13% lower percentage than the N&M (1990) filtering equation. The nine year base flow averages are 69%, 69% and 75% for frequency duration analysis, Chapman (1999) and N&M (1990) filtering equations, respectively. The result revealed that the Modder River is largely supplied by the ground water discharge. The result seemed to concur with the fact that for a semi-arid catchment such as the Modder river basin, with an average annual runoff coefficient of approximately 6%, the contribution of annual rainfall to direct runoff is very minimal.

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This study extends the methodology for the delineation of capture zones to base flow contribution areas for stream reaches under the assumption of constant average annual base flow in the stream. The methodology is applied to the Alder Creek watershed in southwestern Ontario, using three different numerical models. The three numerical models chosen for this research were Visual Modflow, Watflow and HydroGeoSphere. Capture zones were delineated for three different stream segments with reverse particle tracking and reverse transport. The modelling results showed that capture zones delineated for streams are sensitive to the discretization scheme and the different processes considered (i.e. unsaturated zone, surface flow). It is impossible to predict the size, shape and direction of the capture zones delineated based on the model selected. Also, capture zones for different stream segments will reach steady-state at different times. In addition, capture zones are highly sensitive to differences in hydraulic conductivity due to calibration. It was found that finite element based integrated groundwater - surface water models such as HydroGeoSphere are advantageous for the delineation of capture zones for streams. Capture zones created for streams are subject to greater uncertainty than capture zones created for extraction wells. This is because the hydraulic gradients for natural features are very small compared to those for wells. Therefore, numerical and calibration errors can be the same order of magnitude as the gradients that are being modelled. Because of this greater uncertainty, it is recommended that particle tracking and reverse transport always be used together when delineating capture zones for stream reaches. It is uncertain which probability contour to choose when the capture zone is delineated by reverse transport alone. The reverse particle tracks help choose the appropriate probability contour to represent the stream capture zone.

This study extends the methodology for the delineation of capture zones to base flow contribution areas for stream reaches under the assumption of constant average annual base flow in the stream. The methodology is applied to the Alder Creek watershed in southwestern Ontario, using three different numerical models. The three numerical models chosen for this research were Visual Modflow, Watflow and HydroGeoSphere. Capture zones were delineated for three different stream segments with reverse particle tracking and reverse transport. The modelling results showed that capture zones delineated for streams are sensitive to the discretization scheme and the different processes considered (i.e. unsaturated zone, surface flow). It is impossible to predict the size, shape and direction of the capture zones delineated based on the model selected. Also, capture zones for different stream segments will reach steady-state at different times. In addition, capture zones are highly sensitive to differences in hydraulic conductivity due to calibration. It was found that finite element based integrated groundwater - surface water models such as HydroGeoSphere are advantageous for the delineation of capture zones for streams. Capture zones created for streams are subject to greater uncertainty than capture zones created for extraction wells. This is because the hydraulic gradients for natural features are very small compared to those for wells. Therefore, numerical and calibration errors can be the same order of magnitude as the gradients that are being modelled. Because of this greater uncertainty, it is recommended that particle tracking and reverse transport always be used together when delineating capture zones for stream reaches. It is uncertain which probability contour to choose when the capture zone is delineated by reverse transport alone. The reverse particle tracks help choose the appropriate probability contour to represent the stream capture zone.

>Magister Scientiae - MSc / The present study investigated the application of a multi-method approach to determine groundwater-surface water (GW-SW) interactions to quantify and characterize the quality of water resources in a fractured rock aquifer system in upper catchment of the Berg River (G10A). Demonstrating methods for improved understanding of groundwater and surface water interactions is important for informing development of strategies that ensure effective utilization and management of water resources. Applying a single method to inform innovative strategies for water resources has proved futile. The current study shows how the use of several methods can provide the basis for devising practical strategies for water resource utilization and management. The three methods were applied as follows: First, the base flow separation was used whereby the Chapman and Lynne & Hollick digital filter algorithms were applied to time-series streamflow data from four stream gauging stations in the catchment. The computation from algorithms on three sites (gauging stations) showed that the mean Base Flow Index (BFI) value ranged between 7%-8% for the 2012-2014 periods. This means that discharges from subsurface water storages dominate stream flows throughout the study period. Secondly, the quality of groundwater and surface water was sampled using standard methods. Piper Diagrams generated on Aquachem™ software and radial charts were used to identify the predominant hydrochemical facies. Results showed that Na-Cl was the predominant GW and SW water-type. This means that both GW and SW are mainly influenced by recharging surface water as well as interaction occurring between the rock matrices and infiltrating water. Multivariate statistical analyses were used to evaluate the factors controlling GW and SW chemistry in the upper Berg River catchment and the results showed that GW and SW are influenced by natural processes. Two main factors (a. & b.) were extracted which explained 71.8% of the variation in both GW and SW physicochemical parameters. These factors include water-rock interactions and the recharge of surface water. Cluster Analysis extracted four major clusters that grouped sites with similar physicochemical characteristics together. Finally, differential stream gauging was applied to a 600m reach above the Berg River Dam. Three 200m sub-reaches were used to compute differences in flows between sub-reaches. Stream flow at each sub-reach was estimated using mass balance equations with electrical conductivity measurements during instant salt tracer injection tests. Results indicated that during both the wet season (high flow) dry season (low flow), the river continuously lost water to the subsurface. This was demonstrated by the 0.91m³/s and 2.24m³/s decrease in stream flow along the 600m reach. Dry season flow decreases were less than wet season flow decreases, indicated by markedly lower flow loss in respect to the wet season. This confirms results of the analysis of base flow separation, which indicated that discharges from subsurface storages dominate stream flows during low flow periods. The differential stream gauging approach did not provide distinct points along the selected stream reach where GW-SW interaction occurred; rather it provided a holistic representation of seasonal flow variations along the selected reach. This study showed that upper Berg River catchment is dependent on discharges from subsurface water storages to maintain dry season flows. Furthermore, this study showed that infiltration of surface water and discharge of subsurface water transfers the respective chemical signature of the contributor, meaning that the transfer of water of suitable quality will reduce contamination in the receiving water body (i.e. surface water). Transfer of water between subsurface and surface water contributed an average of 8% of the gauged flows in the catchment between 2012 and 2014, suggesting that the groundwater recharge process dominates this catchment.

Combining geochemical data with physical data produces a powerful method for understanding sources and fluxes of waters to river systems. This study highlights this for river systems in regions of complex hydrogeology, shown here through the identification and quantification of base-flow sources to the Verde River and its tributaries within the middle Verde River watershed. Specifically, geochemical tracers (major solutes, stable and radioactive isotopes) characterize the principal aquifers (C, Redwall-Muav, and Verde Formation) and provide a conceptual understanding of the hydrologic connection between them. For the surface-water system, PCA is utilized to identify potential base-flow sources to the Verde River on a several-kilometer scale. Solute mixing diagrams then provide relative inputs of these sources, and when combined with stream discharge, allow for quantification of water sources. The results of this study provide an improved conceptual model that reveals the complexity of groundwater-surface water exchanges in this river basin.

In recent years, photoredox catalysis emerged as a privileged tool for small molecules activation via single-electron transfer mechanisms. Despite their ubiquity as reagents in organic synthesis, the use of boronic acid derivatives to generate carbon-centred radicals remains elusive. This dissertation explores the utilisation of photoredox catalysis to generate carbon radicals from boronic acid derivatives and subsequently engage them in C–C cross-coupling reactions. In the first chapter, an introduction to photoredox catalysis and organoboron reagents is provided, as well as a discussion on the key mechanistic aspects of photoredox catalysed C–C cross-coupling reactions. The second chapter presents our initial coupling strategy and how it evolved in understanding that pinacol boronic ester species can be used as a source of carbon radicals via single-electron oxidation from a photoredox catalyst. Coordination of the boronic esters with Lewis basic species was identified as a fundamental activating interaction. The synthetic utility of this discovery was highlighted by performing a wide range of photoredox catalysed arylations of pinacol boronic esters. The third chapter builds on our mechanistic understanding to identify a set of Lewis base catalysts that conveniently activates boronic esters and acids towards single-electron oxidation. The usefulness of this improved set of conditions was demonstrated by alkylating a wide range of boronic acid derivatives. The fourth chapter describes the application of this methodology in synthesising four active pharmaceutical ingredients from the GABA family. An emphasis was made on developing an efficient flow process and “transition metal free” conditions to survey the attractiveness of the method for the pharmaceutical industry. Finally, the fifth chapter describes the experimental procedures relevant to the results described in chapters 2 to 4.