published_or_final_version / Mechanical Engineering / Master / Master of Philosophy

Hong Kong is vulnerable to energy and economic security due to the heavy dependence on imported fossil fuels. Waste has also been a major environmental management problem due to the amount of rubbish produced every year but lacking the technology and capital to manage different types properly. The objective of the dissertation is to study the feasibility of the use of biofuel in Hong Kong by recycling local waste. Current government policies in Hong Kong and overseas are being investigated on the appropriateness for domestic use. Literature reviews and stakeholders’ questionnaires are accounted to analyse the adaptability and popularity of the biodiesel application. The methodology of the dissertation is to firstly examine literature reviews regarding biodiesel’s environmental aspect, technical efficiencies, economic aspect, government incentives and tax constraints. The consensus outcome of these researches advocated high popularity of biodiesel consumption and production in Europe and U.S. due to lower environmental impact, equivalent output efficiency and strong government support. Their successful implementation is a good example to improvise biodiesel domestically in Hong Kong. Secondly, interviews were conducted with Hong Kong’s limited stakeholders. Respondents such as Hong Kong International Airport, Hong Kong Jockey Club, Fairwood Fastfood MTR Maritime Square were interviewed as these participants have been the pioneers in Hong Kong by recycling waste into biodiesel. On the production side, two out of three bio-refineries in Hong Kong provided their business sustainability and feasibility comments to pursue a long term goal. The limitation on responses might be focused solely on a few peer groups, and not the appropriate stakeholders with proper sampling size. However, the results are concurrent that biodiesel is one of the best alternative energy in Hong Kong. The dissertation draws positive results based on the following factors. Biodiesel can diminish the tremendous cost on waste management and landfill dumping. Using local food waste and industrial wastes from restaurants and food factories as feedstock to produce biodiesel is positive. This will also minimise the heavy reliance on imported fossil fuels to diversify energy sources. Refuelling of biodiesel fuel can be performed in any gas stations with the use of the existing infrastructure without any further requirement of new investment. Nonetheless, in order to facilitate the use of biodiesel, incentives programmes initiated by Hong Kong Government and the biofuel producers have to coherently promote this alternative fuel. The conclusion states that Hong Kong is completely feasible to adopt the use of biodiesel in medium to heavy sized vehicles and vessels in the commercial sector. The environmental benefit of Hong Kong using biodiesel stood out compared to other form of renewable energy. / published_or_final_version / Environmental Management / Master / Master of Science in Environmental Management

The scarcity of fossil fuel and its environmental impact have shifted the world focus on green innovations At a time when the use of fossil fuel means increasing energy scarcity and an environmental crisis in the world in which we live, we need green innovations now more than ever. Growing attention has been drawn to the use of biofuels, such as bioethanol and biodiesel, which have gradually come to make up part of the total energy supply. Uncertainties about the environmental and ecological aspects of the production and consumption of biofuel still exist despite its rapid development. A life cycle analysis (LCA) evaluates the two principal functional parameters 1) energy efficiency and 2) Greenhouse Gas (GHG) balance of different feedstocks for biodiesel production from the cradle to the grave. By accounting a life cycle analysis stage by stage, we can ascertain the change in GHG emissions and energy demand that result from the various uses of feedstocks for the production of biodiesel. In this thesis, various life cycle analysis models are reviewed and evaluated with emphasis on specific biofuels. Different LCA models depend on different LCA calculation under different situations, including GREET, LEM, SimaPro, etc. The software SimaPro was used to compare the life cycle GHG emissions and energy demand from conventional petroleum fuels and several hydro-processed renewable green diesels. A consistent methodology was used for selected fuel pathways to facilitate relatively equitable comparisons. The building of life cycle flow tree in SimaPro combined the input and output with an emphasis on the following stages 1) raw material farming and acquisition, 2)liquid fuel production, 3)transport, 4)refueling, 5)liquid fuel conversion to biodiesel and 6) end uses. Consistent impact assessment methods were chosen for simulation, equitable comparisons and comprehensive analysis of selected fuel pathways for the calculation of Global Warming Potential (GWP) and Cumulative Energy Demand (CED). However, the results of the entire lifetime estimates vary dramatically in production chains, which make it difficult to take a holistic view about energy intake and yields, economic costs and values, environmental impacts and their benefits. Apart from the diversity in system boundaries and life cycle inventories, a variance in terminologies and the limitations of interdisciplinary communication are the main factors that affect the quality of the results. / published_or_final_version / Mechanical Engineering / Master / Master of Philosophy

This study presents an experimental investigation into the effects of running biodiesel fuel blends on conventional diesel engines. Bio fuels provide a way to produce fuels without redesigning any of the engine technology present today, yet allowing for green house emissions to decrease. Bio-diesel is one of these types of emerging bio-fuels, which has an immediate alternative fuel aspect to it, while providing a decrease in green house emissions, as well as a solution to recycling used Waste Vegetable Oils which are other wise disposed. This study shows how by blending bio-diesel with petroleum diesel at intervals of B5, B10, B15, and B20 decrease green house emissions can significantly while maintaining similar performance output and efficiency with respect to 100% petroleum diesel. / by Sergio Bastiani. / Thesis (M.S.C.S.)--Florida Atlantic University, 2008. / Includes bibliography. / Electronic reproduction. Boca Raton, Fla., 2008. Mode of access: World Wide Web.

Thesis (Master of Engineering in Chemical Engineering)--Cape Peninsula University of Technology, 2018. / The production of biodiesel is an energy and water intensive process. The wastewater that is produced during this process is high in concentrations of COD, BOD, FOG and various other contaminants. Since it contains low levels of nutrients, it is difficult to degrade using natural processes such as conventional activated sludge wastewater treatment. The discharge of untreated biodiesel wastewater also raises serious environmental concern. It interferes when remediated with biological processes and results in additional costs during the production of biodiesel when penalties and fines are applied. Conventional treatment processes are not capable of treating contaminants and pollutants in biodiesel to satisfactory concentrations and hence advanced treatment processes are necessary. In this research, a lab scale integrated treatment process was used to investigate the successful reduction of contaminants, in particular COD, BOD and FOG. The integrated treatment process used in this study consisted of three consecutive steps; acidification, electrochemical oxidation and adsorption using chitosan as an adsorbent. The electrochemical oxidation process with IrO2-Ta2O5/Ti anodes was applied to treat biodiesel wastewater. Different operating conditions were tested to establish favourable conditions. The current density applied as well as the concentration of NaCl as the supporting electrolyte greatly affected the process. A NaCl concentration of 0.08M was deemed sufficient, whereas a current density of 1 mA/cm² showed superior performance compared to lower or higher current densities. Adsorption of pollutants in biodiesel wastewater was investigated using Chitosan as the adsorbent. Various chitosan concentrations, initial pH of the wastewater and repetitive adsorption stages were investigated. It was discovered that all three operating conditions greatly affect the performance of the process. The three consecutive adsorption stages using a chitosan concentration of 4.5 g/L at a pH of 2 resulted in the highest pollutant removal. It was observed that the integrated treatment process could reduce COD, BOD and FOG levels by 94%, 86% and 95% respectively. This concludes that the treated effluent complies with local industrial effluent discharge standards, which could be disposed safely without further treatment.

Mobile source emissions are a major contributor to global and local air pollution. Governments and regulatory agencies have been increasing the stringency of regulations in the transportation sector for the last ten years to help curb transportation sector air pollution. The need for regulations has been emphasized by scientific research on the impacts from ambient pollution, especially research on the effect of particulate matter on human health. The particulate emissions from diesel vehicles, diesel particulate matter (DPM) is considered a known or probable carcinogen in various countries and increased exposure to DPM is linked to increased cardiovascular health problems in humans. The toxicity of vehicle emissions and diesel particulate emissions in particular, in conjunction with an increased awareness of potential petroleum fuel shortages, international conflict over petroleum fuel sources and climate change science, have all contributed to the increase of biodiesel use as an additive to or replacement for petroleum fuel. The goal of this research is to determine how this increased use of biodiesel in the particular emission testing setup impacts urban air quality. To determine if biodiesel use contributes to a health or climate benefit, both the size range and general composition were investigated using a comprehensive comparison of the particulate component of the emissions in real time. The emissions from various biodiesel and diesel mixtures from a common diesel passenger vehicle were measured with a cavity ring-down transmissometer (CRDT) coupled with a condensation particle counter, a SMPS, a nephelometer, NOx, CO, CO2, and O3 measurements. From these data, key emission factors for several biodiesel and diesel fuel mixtures were developed. This approach reduces sampling artifacts and allows for the determination of optical properties, particle number concentration, and size distributions, along with several important gas phase species' concentrations. Findings indicate that biodiesel additions to diesel fuel do not necessarily have an air quality benefit for particulate emissions in this emission testing scenario. The often cited linear decrease in particulate emissions with increasing biodiesel content was not observed. Mixtures with half diesel and half biodiesel tended to have the highest particulate emissions in all size ranges. Mixtures with more than 50% biodiesel had slightly lower calculated mass for light absorbing carbon, but this reduction in mass is most likely a result of a shift in the size of the emission particles to a smaller size range, not a reduction in the total number of particles. Evaluation of the extensive optical properties from this experimental set-up indicates that biodiesel additions to diesel fuel has an impact on emission particle extinction in both visible and near-IR wavelengths. The B99 mixture had the smallest emission factor for extinction at 532 nm and at 1064 nm. For the extinction at 532 nm, the trend was not linear and the emission factor peaked at the B50 mixture. Results from intensive properties indicate that emissions from B5 and B25 mixtures have Ångström exponents close to 1, typical for black carbon emissions. The mixtures with a larger fraction of biodiesel have Ångström exponent values closer to 2, indicating more absorbing organic matter and/or smaller particle size in the emissions. Additional experimental testing should be completed to determine the application of these results and emission factors to other diesel vehicles or types of diesel and biodiesel fuel mixtures.