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Surficial geochemistry, particularly selective leach technology, has proven effective in revealing anomalous concentrations of ore indicator metals overlying zones of buried mineralization. This study focuses on the buried Zn-Cu-Au-Ag VMS deposit at McIlvenna Bay in the Flin Flon Greenstone Belt to determine whether the peat swamp at the surface contains any anomalies of ore indicator metals using simple surficial geochemical techniques. Three selective leaches were performed, ammonium acetate pH 5.0, hydroxylamine, and sodium pyrophosphate. The hydroxylamine leach, which selects for metals in the reducible phase often associated with Mn and Fe oxides, has the clearest anomaly for multiple metals observed simultaneously, at the greatest magnitude. The pyrophosphate leach, which selects for metals that are oxidizable, often associated with organics showed a clear anomaly only for Cu, despite the abundance of organic matter and its great affinity for binding metals, likely because the organic-metal complexes formed in this system are easily exchangeable and highly soluble, not allowing for the formation of clear anomalies. The use of selective leach technology on surficial soil or peat has shown to be effective for delineating ore indicator metal anomalies, giving surface projections of buried mineralization in various types of systems, as long as the dynamics of the system are well understood in order to determine the phase the metals are associated with.

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The diploma thesis analyses the impact of the presence of peat bogs on the local climate, especially on temperature, humidity regime and energetic balance. Date were collected on 2 comparable observation pots: Červené blato bog, Klenová bog. As a contrasting terrestric non-wetland ecosystem was chosen permanent grassland (TTP) in Malíkov nad Nežárkou village, in district of Jindřichův Hradec. The date were collected every hour using datalogger. During vegetation season a sample of plant biomass was taken. The expected results of the impact of bogs on climate has been proven on Červené blato bog. Klenová bog show unexpected figures collected in the altitude of 2 metres. It shows the lowest average humidity and the highest average day temperature of all observation spots. TTP show unexpected figures in the altitude of 2 meter which has been most likely caused by the presence of 2 ponds and spring.

Northern peatlands represent a significant carbon reservoir, containing approximately a third of the terrestrial carbon pool. The stability of these carbon stores is poorly understood, and processes of accumulation and degradation appear to be finely balanced. Over the last decade, it has become increasingly clear that losses of dissolved organic carbon (DOC) from peatlands can be of considerable size and this flux appears to have increased substantially over the last 20 years. Despite its significance, the chemical composition of peatland-derived DOC remains poorly understood. This study aimed to characterise dissolved organic matter (DOM) at the molecular level using a novel combination of techniques. The study site (Cors Fochno, Wales, UK) is an ombrotrophic bog on which a number of studies into carbon cycling and hydrology have been carried out, providing a useful context for this project. The size and compositions of the DOC pool was monitored over 18 months, from three banks of piezometers, sampling from depths of 15 cm to 6 m. DOM which is representative of bog runoff was also monitored. DOC concentrations varied considerably between locations, spanning an order of magnitude (11.4 to 114 mgC l-1). Several relationships between DOC concentration and environmental and physical factors were established: DOC levels near the surface of the peatland varied with temperature, those in the runoff were most affected by recent rainfall events and the apparent DOC concentration at depth was related to the hydraulic conductivity of peat at that depth. The annual flux of DOC from the site was estimated at 113 tonnes, or 17.4 gC m-2. Only a small portion of the DOC pool could be characterised by analysis of dissolved combined amino acids (DCAA) and dissolved carbohydrates (as neutral sugars). Non-protein amino acids were most abundant in runoff samples, suggesting microbial reworking of DOM on entering drainage systems. DCAA yields decreased with depth, and the DCAA pool in deeper peat layers was characterised by more hydrophobic compounds. Interpretation of semi-quantitative results from TMAH thermochemolysis GC-MS analysis suggested oxidative degradation of organic matter near the surface of the peatland and photochemical degradation where DOM entered drainage networks, and this was supported by novel interpretation of results from ultrahigh resolution mass spectrometry analysis. The deepest porewaters were dominated by nalkanes, with notable contributions from fatty acids, suggesting a plant wax source for this DOM. The highest DOC concentrations were found at intermediate depth from a site midway between the centre of the bog and the southern boundary where hydraulic conductivities were low, and DOM from these piezometers were characterised by high contributions from a suite of phenolic compounds (with mainly para-hydroxyphenyl structures). These compounds have been linked to Sphagnum species, and are known to be functionally important to the development and maintenance of the unusual chemical environment in peatlands which slows decay rates, reduces microbial activity, and allows the sequestration of the large carbon reservoir. The findings of this study highlight the dynamic nature of peatland derived DOM, both in the size of the carbon pool and its composition which change dramatically with both season and depth.

The relationship between vegetation change and rehabilitation management is investigated at a severely degraded cut-over lowland raised mire on the Wales/England border, managed by Natural England and The Countryside Council for Wales. Positive responses are confirmed 11 years after rehabilitation commenced, identifying trends towards raised mire as well as bog pool vegetation and water table thresholds associated with these trends have been established. A landscape-scale vegetation survey was carried out three times over 9 years. Species abundance was correlated with average seasonal water table height, time since rehabilitation, cutting type and survey year. Key species maps for the time series confirmed positive vegetation response, but slower than stipulated in the site management plan. There was a clear increase in the target peat-forming species (Sphagnum cuspidatum, Eriophorum angustifolium and E. vaginatum) as a direct response to rehabilitation and correlating positively with a high water table. Permanent quadrat vegetation monitoring was carried out three times at five-year intervals. Uncut areas and areas of recent commercial cuttings were rehabilitated earliest having significant increases in target mire species without the loss of other mire species from excess inundation. In the recent commercial cutting areas, a successional trend was identified, from a low water table to a fluctuating water table characterised by Molinia caerulea-rich vegetation, followed by a transition to stable, inundated conditions supporting Sphagnum cuspidatum/Eriophorum spp pool vegetation. A second successional trend, associated with the achievement of a near-surface, stable water table, saw the development of raised mire vegetation including Sphagna other than S. cuspidatum. This latter trend was primarily found in the uncut areas of the site but was also found to a lesser extent in recently cut-over areas where it was preceded by a fluctuating water table with a Calluna vulgaris- Molinia caerulea vegetation. A new survey related water table residence time calculated from hydrology data with vegetation for each quadrat. Analysis identified a mire pool vegetation type correlated with shallow, above surface flooding. A diverse mire vegetation type was also found which correlated with the water table staying within the upper 10cm of peat. The minimum threshold for establishment of Sphagnum species was found to be an average water table level within the range of 5.1 to 10cm below the peat surface. Higher cover of Sphagnum species was related to shallow flooding – suggesting that these conditions would be most efficient in re-establishing mire vegetation. 3 A base-line vegetation monitoring survey on an area immediately following deforestation and damming identified a subtle but positive response of the mire vegetation to management within one year.

This dissertation presents the results of late Holocene insect fossil analysis from six raised bogs in the Irish Midlands. A distribution and taphonomic study was performed on a sequence of samples across a 1-km transect from the lagg (margin) to the dome (centre) of Ballykean Bog, County Offaly, Ireland. The purpose of this study was to detect any patterns in the taphonomy of the insect fossil assemblages, through the development of the bog and across ancient bog surfaces. This study also investigated how vegetation changes and taphonomy influence beetle assemblages from different locations across the bog surface and to test whether fossil assemblages reflect these changes. The insect faunal assemblages from the transect did not show any clear spatial or temporal patterns in fossil abundance or taxonomic diversity. However, the study demonstrated the benefit of the analysis of multiple sampling points in a bog. Multiple sampling site analysis appears to be critical in the development of a comprehensive reconstruction of key intervals of peat deposition and in providing a greater understanding of the local bog surface habitats. Insect fossil records were analysed across six raised bogs as part of a multi-proxy environmental archaeology project focusing on seven trackways, a wooden platform and a habitation structure. The archaeology dates from the early Bronze Age (1569±9 BC) at Kinnegad Bog to the Christian period (AD 900 to 1160) at Lullymore Bog. This study demonstrates that insect records associated with the minor structures, such as trackways and platforms, contained less diverse assemblages comprising of mainly generalist taxa. In comparison, the major habitation structure at Ballykean Bog had a strong anthropogenic signal. While the reasons behind the construction of the trackways and platforms remains unsolved on the basis of the multi-proxy environmental analysis, it was possible to suggest reasons for their construction based on structure directionality and historical context.

Dendrochronological investigations on subfossil European ash (Fraxinus excelsior L.) wood found in two bogs of Western Lithuania are presented. Radiocarbon dating has revealed that Fraxinus grew in the Middle and Late Holocene, from approximately 4700 BC to 1500 BC. It is proposed that the growth of Fraxinus at these bogs was limited by differing hydrological regimes. Rising soil water levels induced a long decline in radial growth followed by a sharp reduction (up to 51%) in ring widths before the trees died. Until now, forest history in Lithuania was mostly based on results from palynological studies. This research demonstrates the potential of using dendrochronology to extend the distribution record of Fraxinus in the Baltic region during different periods of the Holocene.

Environmental degradation is a serious problem in Lesotho, Africa. The majority of studies dealing with soil loss and gully erosion have mainly focused on the mechanics of the erosion. However, mountain watersheds are sensitive and vulnerable to degradation and in so being, have large inherent environmental implications. Gully erosion diversifies the micro-topographical and hydrological environment. The severe changes and eventual system degradation incurred as a result of gullying has rarely been quantified. This paper specifically highlights mire phytogeographic responses to valley head degradation at selected sites in eastern Lesotho by comparing patterns observed in gullied mires to those seen in other non-gullied mires. Soil and vegetation belt transects are set up across five mires (2 gullied) in the highlands of eastern Lesotho. The response of many of the plant species to the overall environmental gradient was asymmetrical and unimodal in pattern. The spatial distribution of the soil’s physical properties, topography and vegetation community patterns were found to reflect the spatial mosaic of the soil moisture gradient. The negative impact that gullying has on the ecohydrological regime of the valley heads is evident and is allowing for shrub encroachment. Both the wetland and dryland vegetation communities correlate strongly with the changes in the surface soil moisture gradient. Gully erosion is clearly a threshold phenomenon. Continued grassland degradation, accelerated soil erosion and subsequent gullying of the wetlands will lead to plant and animal diversity loss, decreased livestock productivity, sediment-laden water and shortened dam life-span.