The focus of this report is the derivation of the Bogoliubov-de Gennes equations for superconductors from a tight-binding model, restricting ourselves to the case of s-wave superconductors.

Recent developments in the study of Majorana fermions through braid theory have shown that there exists a set of interchanges that allow for the realization of true quantum computation. Alongside these developments there have been studies of topological superconductivity which show the existence of states that exhibit non-Abelian exchange statistics. Motivated by these developments we study the differences between Abelian and non-Abelian topological phase in the vortex state through the Bogoliubov de-Gennes (BdG) formalism. Due to our interests in low-energy states we first implement computationally efficient algorithms for calculating the mean fields and computing eigenpairs in an arbitrary energy window. We have shown that these algorithms adequately reproduce results obtained from a variety of other techniques and show that these algorithms retain spatial inhomogeneity information. Our results show topological superconductivity and vortex states can coexist; providing a means to realize zero-energy bound states, the number of which corresponds to the topological phase. With the use of our methods we present results contrasting the differences between Abelian and non-Abelian topological phase. Our calculations show that an increase in Zeeman field affects numerous parameters within topological superconductors. It causes the order parameter to become more sensitive to temperature variations in addition to a reduced rate of recovery to the bulk value from a vortex core. The increased field suppresses spin-up local density of states (LDOS) in close proximity to the vortex core for low-energy states. Further, it narrows the spectral gap at the lattice centre. Both energy spectrum and LDOS calculations confirm that trivial topological phase have no zero-energy bound states, Abelian phases have an even number, while non-Abelian phases have an odd number.

<p>The pi-striped, <em>d</em>-wave superconducting (SC) state, which is a type of pair density wave wherein the SC order is spatially modulated, has recently been shown to generate the key ingredients for quantum oscillations consistent with experimental observations (Zelli <em>et al.</em>, 2011, 2012). This was accomplished with a phenomenological approach using non-self-consistent Bogoliubov-de Gennes (BdG) theory. The objective of this thesis is to explore two aspects of this approach: the addition of a charge density wave (CDW) order to the previous non-self-consistent calculations, and an attempt at stabilizing the pi-striped state in fully self-consistent BdG theory. It was found that the CDW order had a minimal effect on the Fermi surface characteristics of the pi-striped state, but that a sufficiently strong CDW degrades the Landau levels which are essential for the formation of quantum oscillations. The self-consistent mean-field calculations were unable to stabilize the pi-striped state under a range of modifications to the Hamiltonian. Free energy calculations with the modulated SC order treated as a parameter demonstrate that the pi-striped state is always less energetically favourable than the normal state for the scenarios which were considered. The results of this study constitute a basis for future, more comprehensive studies, using the BdG approach, of the stability of possible pi-striped SC phases.</p> / Master of Science (MSc)