abstract: An exhaustive parameter study involving 133 dynamic crystallization experiments was conducted, to investigate the validity of the planetary embryo bow shock model by testing whether the cooling rates predicted by this model are consistent with the most dominant chondrule texture, porphyritic. Results show that using coarse-grained precursors and heating durations ≤ 5 minutes at peak temperature, porphyritic textures can be reproduced at cooling rates ≤ 600 K/hr, rates consistent with planetary embryo bow shocks. Porphyritic textures were found to be commonly associated with skeletal growth, which compares favorably to features in natural chondrules from Queen Alexandra Range 97008 analyzed, which show similar skeletal features. It is concluded that the experimentally reproduced porphyritic textures are consistent with those of natural chondrules. This work shows heating duration is a major determinant of chondrule texture and the work further constrains this parameter by measuring the rate of chemical dissolution of relict grains. The results provide a robust, independent constraint that porphyritic chondrules were heated at their peak temperatures for ≤ 10 minutes. This is also consistent with heating by bow shocks. The planetary embryo bow shock model therefore remains a viable chondrule mechanism for the formation of the vast majority of chondrules, and the results presented here therefore strongly suggest that large planetary embryos were present and on eccentric orbits during the first few million years of the Solar System’s history. / Dissertation/Thesis / Masters Thesis Geological Sciences 2018

The consequences of structured flows continue to be a pressing topic in relating spectral data to physical processes occurring in massive star winds. In a preceding paper, our group reported on hydrodynamic simulations of hypersonic flow past a rigid spherical clump to explore the structure of bow shocks that can form around wind clumps. Here we report on profiles of emission lines that arise from such bow shock morphologies. To compute emission line profiles, we adopt a two-component flow structure of wind and clumps using two “beta” velocity laws. While individual bow shocks tend to generate double-horned emission line profiles, a group of bow shocks can lead to line profiles with a range of shapes with blueshifted peak emission that depends on the degree of X-ray photoabsorption by the interclump wind medium, the number of clump structures in the flow, and the radial distribution of the clumps. Using the two beta law prescription, the theoretical emission measure and temperature distribution throughout the wind can be derived. The emission measure tends to be power law, and the temperature distribution is broad in terms of wind velocity. Although restricted to the case of adiabatic cooling, our models highlight the influence of bow shock effects for hot plasma temperature and emission measure distributions in stellar winds and their impact on X-ray line profile shapes. Previous models have focused on geometrical considerations of the clumps and their distribution in the wind. Our results represent the first time that the temperature distribution of wind clump structures are explicitly and self-consistently accounted for in modeling X-ray line profile shapes for massive stars.