Philosophiae Doctor - PhD / The Platreef is a platinum group elements (PGE) deposit located in the Northern limb of the Bushveld Igneous Complex (BIC). It is a series of mafic and ultramafic sills that are overlain by rocks from the Main Zone (MZ) of the BIC. In comparison to PGE deposits (i.e., Merensky Reef and the UG-2 chromitite) occurring in the Critical Zone (CZ) of the Eastern and Western Limbs of the BIC, which are less than 1 m in thickness, the Platreef is 10 to 400 m in thickness and is comprised of a variety of rocks. PGE mineralisation in the Platreef is not confined to a specific rock type, and its distribution and styles also vary with depth and along strike. Despite the numerous researches that have been conducted, the genesis of Platreef is still poorly understood. New major and trace elements in conjunction with Sr–Nd isotope data, generated from whole-rock analyses of different Platreef rocks, were collected from four drill cores along its strike. The data were examined to determine the source of the magmas and identify the processes involved in its genesis. The study also aimed at establishing whether a genetic link exists between the Platreef magmas and the magmas that formed the Lower Zone (LZ), CZ and MZ in the Rustenburg Layered Suite (RLS) of the BIC. The petrography revealed that the Platreef in the four drill cores consists of harzburgite, olivine pyroxenite, pyroxenite, feldspathic pyroxenite and norite. Based on the textural and modal mineralogy variations, feldspathic pyroxenite was subdivided into five types (I, II, III, IV and V). The variation in the average contents of MgO, LaN/YbN and ΣREE for the Platreef rocks are consistent with the modal mineralogy from the least to the most differentiated rocks. However, the Sr–Nd isotope data of the Platreef rocks have revealed two distinct groups of samples with decreasing ɛNd2060. Group 1 consists of pyroxenite and feldspathic pyroxenite II, III and V having ɛNd2060 values that range from –8.4 to –2.9, and 87Sr/86Sr2060 values from 0.707281 to 0.712106. The Platreef rocks of group 2 consist of olivine pyroxenite and feldspathic pyroxenite Type I with ɛNd2060 ranging from –12.6 to –10.8, and 87Sr/86Sr2060 ranging from 0.707545 to 0.710042. In comparison to the LZ, CZ and MZ rocks, which have ɛNd values ranging from –8.5 to –5.1, and 87Sr/86Sr ranging from 0.704400 to 0.709671, Platreef pyroxenite of group 1 have lower negative ɛNd2060 values (from –3.8 to –2.9) and higher 87Sr/86Sr2060 values from 0.709177 to 0.710492, whereas feldspathic pyroxenite of group 1 have overlapping ɛNd2060 values (from –8.4 to –4.9) but also higher 87Sr/86Sr2060 values (from 0.707281 to 0.712106). Instead, the Platreef olivine pyroxenite and feldspathic pyroxenite in group 2 highly negative ɛNd2060 values and overlapping 87Sr/86Sr2060 values. It is therefore suggested that the Platreef magmas derived from the partial melting of an heterogeneous mantle source comprising depleted mantle melts and both metasomatized slightly unradiogenic Nd enriched melts and highly unradiogenic Nd enriched melts from the subcontinental lithospheric mantle. These magmas ascended via the continental crust using different paths and interacted with rocks of different Sr–Nd isotopic compositions which resulted in the formation the hybrid magmas. The study speculates that sulphide saturation in the Platreef magmas was reached in the staging chambers at depth, and the varying styles of the PGE mineralisation in the Platreef rocks are the result of the varying degree of partial melting of the heterogeneous source for their magmas. In conlusion, this study suggests that the genesis of the Platreef is much more complex and should be considered very much independent from processes involved in the genesis of the RLS in the Eastern and Western Limbs of BIC in agreement with earlier studies. / NRF Inkaba ye Africa Iphakade / 2020-08-31

The Bushveld Igneous Complex (BIC) is the largest layered mafic intrusion in the world and contains the largest known deposits of vanadium, chromium and Platinum group elements on the planet, as well as large deposits of iron, nickel, copper, tin and fluorite. To aid and improve our understanding of the tectonics that prevailed during the emplacement of the Bushveld Complex relevant data can still be extracted from the metamorphic aureole of the Complex, not the least among which are accurate determinations of pressure conditions during peak metamorphism. A relatively large number of geothermobarometric investigations have been performed on the Bushveld Complex aureole. The summation of all the thermobarometric studies on the Bushveld Complex aureole produces a dataset with largely divergent pressure-estimates, ranging from 1.5 kbar to 5.5 kbar. This study’s main aim was to produce new thermobarometric data for the Eastern Bushveld Complex aureole. To this ends metapelites from the aureole were sampled between Lydenburg and somewhat northwest of Penge. Polished thin-sections were produced for a number of samples and studied under microscope. After XRF analyses were performed on a refined number of samples, pseudosections for these samples were produced using Perplex. Electron microprobe analyses were used to analyze mineral chemistries of five samples and the resultant data used to construct isopleths for these samples in Perplex. The isopleth data was then used to scrutinize and, where possible, refine PT-estimates. The principal results obtained from mineral equilibrium modeling were the pseudosections and isopleths of samples DY09-54 and DY09-56. These samples’ cumulate results suggest that the metapelites of their sampling locality, which lies roughly ~36 km northwest of Penge, reached 530-565 ºC and 2230-2960 bar during peak metamorphism. Modelled isopleths of MnO/(MnO+CaO+FeO+MgO) suggest that these estimates be refined to 550 ± 5 ºC and 2650 ± 20 bar. These pressure estimates agree well with the majority of barometric studies in the literature that post-date the nineteen-eighties. The pressure estimates of 2230-2960 bar suggest that DY09-54 and DY09-56 were at a crustal depth of 7.9-10.4 km during peak metamorphism, assuming that a roughly 1.5 km thick load of rock, mainly of the Rooiberg Group and/or the Lebowa Granite Suite, were situated above the Rustenburg Layered Suite and at the top of the pile that overlay the samples. In such a case the Rustenburg Layered Suite’s contribution to the load would have represented a 4.2-6.7 km thick pile of these mafic rocks and, assuming that the load of Pretoria Group strata in the floor to the Complex had a thickness of 2350 m, the base of the Rustenburg Layered Suite would have been at a crustal depth of 5.6-8.0 km during peak metamorphism and directly above samples DY09-54 and DY09-56. Modelled palaeogeotherms together with the peak-metamorphic crustal depths estimated for samples DY09-54 and DY09-56 suggest that at peak metamorphism the samples’ temperatures had been elevated by no less than 320-355 °C, assuming that no thermal metamorphic effect was active on the samples just prior to the intrusion of the Bushveld Complex. Copyright / Dissertation (MSc)--University of Pretoria, 2012. / Geology / unrestricted

Thesis (M. Sc.(Geography)) -- University of Limpopo, 2019 / Global production of Platinum Group Metals (PGMs) is dominated by South Africa due to its large economic resources base in the Bushveld Igneous Complex (BIC). PGMs are used in a wide range of high technology applications worldwide including medicinal, industrial and commercial purposes, and its contribution to the Gross Domestic Product (GDP) and creating jobs for many. In an area where mining activities dominate, there are likely to be problems that need effective environmental management approaches, which can be facilitated through legislations. Marula Platinum Mine (MPM) is located in Limpopo province BIC which has the second largest number of mining productivity in South Africa. Environmental legislations have been put in place by the South African government in order to avoid or minimise the footprints caused by PGM mining. This study looked at environmental compliance with solid waste management practices by Marula Platinum Mine (MPM) as guided by Mineral and Petroleum and Resource Development Act (MPRDA) and National Environmental Management Act (NEMA) as well as the environmental impacts of MPM in the surrounding communities. Both primary (questionnaires, field observations and key informant interviews) and secondary (NEMA, MPRDA, journals, reports, pamphlets, internet and books) data was used to address the objectives of the study. Descriptive method and Statistical Package for Social Sciences (SPSS) version 25 were used for the analysis of data. The key research results revealed that MPM was compliant with 65% and 21% partially compliant with solid waste management practices. Only 14% of information on solid waste management practices could not be accessed because MPM is still operational. MPM had also had negative footprints on the surrounding villages such as dust generation and cracks on walls and floors on houses of community members, strikes and increase in the usage of substance abuse. Recommendations of the study are that MPM should address challenges that hinder environmental compliance so as to be 100% compliant with MPRDA and NEMA regulations. MPM should also provide other mitigation measures for blasting of explosives to reduce dust generation and problems of cracks on houses of surrounding village members.