This thesis discusses aspects of a novel solar concentrating photovoltaic / thermal (PV/T) collector that has been designed to produce both electricity and hot water. The motivation for the development of the Combined Heat and Power Solar (CHAPS) collector is twofold: in the short term, to produce photovoltaic power and solar hot water at a cost which is competitive with other renewable energy technologies, and in the longer term, at a cost which is lower than possible with current technologies. To the author’s knowledge, the CHAPS collector is the first PV/T system using a reflective linear concentrator with a concentration ratio in the range 20-40x. The work contained in this thesis is a thorough study of all facets of the CHAPS collector, through a combination of theoretical and experimental investigation. A theoretical discussion of the concept of ‘energy value’ is presented, with the aim of developing methodologies that could be used in optimisation studies to compare the value of electrical and thermal energy. Three approaches are discussed; thermodynamic methods, using second law concepts of energy usefulness; economic valuation of the hot water and electricity through levelised energy costs; and environmental valuation, based on the greenhouse gas emissions associated with the generation of hot water and electricity. It is proposed that the value of electrical energy and thermal energy is best compared using a simple ratio. Experimental measurement of the thermal and electrical efficiency of a CHAPS receiver was carried out for a range of operating temperatures and fluid flow rates. The effectiveness of internal fins incorporated to augment heat transfer was examined. The glass surface temperature was measured using an infrared camera, to assist in the calculation of thermal losses, and to help determine the extent of radiation absorbed in the cover materials. FEA analysis, using the software package Strand7, examines the conductive heat transfer within the receiver body to obtain a temperature profile under operating conditions. Electrical efficiency is not only affected by temperature, but by non-uniformities in the radiation flux profile. Highly non-uniform illumination across the cells was found to reduce the efficiency by about 10% relative. The radiation flux profile longitudinal to the receivers was measured by a custom-built flux scanning device. The results show significant fluctuations in the flux profile and, at worst, the minimum flux intensity is as much as 27% lower than the median. A single cell with low flux intensity limits the current and performance of all cells in series, causing a significant drop in overall output. Therefore, a detailed understanding of the causes of flux non-uniformities is essential for the design of a single-axis tracking PV trough concentrator. Simulation of the flux profile was carried out using the ray tracing software Opticad, and good agreement was achieved between the simulated and measured results. The ray tracing allows the effect of the receiver supports, the gap between mirrors and the mirror shape imperfections to be examined individually. A detailed analytical model simulating the CHAPS collector was developed in the TRNSYS simulation environment. The accuracy of the new component was tested against measured data, with acceptable results. A system model was created to demonstrate how sub components of the collector, such as the insulation thickness and the conductivity of the tape bonding the cells to the receiver, can be examined as part of a long term simulation.