It was once thought that molecules in the interstellar medium (ISM) would be destroyed in the harsh surroundings and conditions of space, and therefore unobservable by radio techniques. However, it is now understood that the chemistry of the ISM is vast and complex. The question still remains as to just how complex is this chemistry. Much is clearly still not understood. This dissertation presents work on the study of metal compounds and cations in the circumstellar envelopes of oxygen- and carbon-rich asymptotic giant branch (AGB) and supergiant stars. Laboratory studies were also conducted on several transition metal compounds of interstellar interest, some with high spin and orbital angular momentum states. Work has been completed to confirm the detection of the debated metal cyanide KCN in the carbon-rich AGB star IRC+10216. KCN joins the list as the fifth interstellar metal cyanide/isocyanide detected in this source. In addition, preliminary results on the search for TiO are presented towards the oxygen-rich supergiant star, VY CMa. To further understand the evolutionary processes of carbon- and oxygen-rich stars, a survey of HCO⁺ was taken towards the carbon star IRC+10216, the oxygen-rich AGBs TX Cam, IK Tau, and W Hya and the oxygen-rich supergiant NML Cyg. While HCO⁺ was detected towards all of these sources, the results vary. The outflow of NML Cyg proves to be asymmetric and further study is necessary. The emission from W Hya is significantly narrower than the other sources. The abundances of HCO⁺ in circumstellar gas increases inversely with mass-loss rate and ion-molecule chemistry appears to influence the chemistry of evolved circumstellar envelopes. To understand species in space with more confidence, a laboratory search for several 3d transition metal species of astrochemical interest was conducted in the laboratory: HZnCl (X¹∑⁺), ZnO (X¹∑⁺ and a³Πᵢ), ZnCl (X²∑⁺), TiS (X³Δᵣ) and CrS (X⁵Πᵣ). All of the molecules have been observed for the first time with high resolution gas phase rotational spectroscopy and the work on ZnO was the first gas-phase study of this molecule. Synthesis of the species required exotic production methods, including use of a DC discharge to produce all zinc species. By studying the rotational spectra, rest frequencies were determined that will be beneficial for future astronomical searches.

Millimeter wave studies of molecules in circumstellar envelopes and a planetary nebula have been conducted. Using the Submillimeter Telescope (SMT) of the Arizona Radio Observatory (ARO) on Mt. Graham, a comparative spectral survey from 215-285 GHz was carried out of the carbon-rich asymptotic giant branch star IRC +10216 and the oxygen-rich supergiant VY Canis Majoris. A total of 858 emission lines were observed in both objects, arising from 40 different molecules. In VY Canis Majoris, AlO, AlOH, and PO were detected for the first time in interstellar space. In IRC +10216, PH3 was detected for the first time beyond the solar system, and C3O, and CH2NH were found for the first time in a circumstellar envelope. Additionally, in the evolved planetary nebula, the Helix, H2CO, C2H, and cyclic-C3H2 were observed using the SMT and the Kitt Peak 12 m telescopes. The presence of these three molecules in the Helix suggests that relatively complex chemistry occurs in planetary nebulae, despite the harsh ultraviolet field. Overall, the research on molecules in circumstellar and planetary nebulae furthers our understanding of the nature of the material that is fed back into the interstellar medium from evolved stars. Besides telescope work, laboratory research was also conducted - the rotational spectrum of ZnCl was measured and its bond length and rotational constants were determined. Lastly, in partial fulfillment of a graduate certificate in entrepreneurial chemistry, the commercial applications of terahertz spectroscopy were explored through literature research.

The brightness and proximity of many classical Be stars makes them perfect laboratories for studying the physics of astrophysical disks. They are also among the most popular targets for optical/IR interferometers, which are able to fully resolve their circumstellar disks, to which much of the recent progress in our understanding of these enigmatic objects is owed. The current consensus is that classical Be stars eject material from the stellar surface into Keplerian orbits, thus forming a disk, whose subsequent evolution is governed by turbulent viscosity, which is the basis of the so-called viscous decretion disk (VDD) model. Among the main results of the present work is arguably the best-constrained model of a particular Be star β CMi. The VDD predictions were confronted also with radio observations, which allowed for the first determination of the physical extent of a Be disk. This result subsequently led to the detection of a binary companion, which is truncating the disk by tidal forces. Extending the sample to include five more targets led to revealing a similar outer disk structure in all of them. The range of explanations includes the most plausible scenario, in which the truncation of Be disks by (unseen) companions is much more common than previously thought.

In recent years, it has been shown that microlensing is a powerful tool for examining the atmospheres of stars in the Galactic bulge and Magellanic Clouds. The high gradient of magnification across the source during both small impact parameter events and caustic crossings offers a unique opportunity for determining the surface brightness profile of the source. Furthermore, models indicate that these events can also provide an appreciable polarization signal: arising from differential magnification across the otherwise symmetric source. Earlier work has addressed the signal from a scattering photosphere for both point mass lenses and caustic crossings. In a previous paper, polarimetric variations from point lensing of a circumstellar envelope were considered, as would be suitable for an extended envelope around a red giant. In this work, we examine the polarization in the context of caustic crossing events, the scenario that represents the most easily accessible situation for actually observing a polarization signal in Galactic microlensing. Furthermore, we present an analysis of the effectiveness of using the polarimetric data to determine the envelope properties, illustrating the potential of employing polarimetry in addition to photometry and spectroscopy with microlensing follow-up campaigns.

This paper examines line profile evolution due to the linear expansion of circumstellar material obsverved during a microlensing event. This work extends our previous papers on emission line profile evolution from radial and azimuthal flow during point mass lens events and fold caustic crossings. Both “flavours” of microlensing were shown to provide effective diagnostics of bulk motion in circumstellar envelopes. In this work a different genre of flow is studied, namely linear homologous expansion, for both point mass lenses and fold caustic crossings. Linear expansion is of particular relevance to the effects of microlensing on supernovae at cosmological distances. We derive line profiles and equivalent widths for the illustrative cases of pure resonance and pure recombination lines, modelled under the Sobolev approximation. The efficacy of microlensing as a diagnostic probe of the stellar environs is demonstrated and discussed