This thesis provides strategies for multiple vehicles to explore unknown environments in a cooperative and systematic manner. These strategies are called Simultaneous Cooperative Exploration and Networking (SCENT) strategies. As the basis for development of SCENT strategies, we first tackle the motion control and planning for one vehicle with range sensors. In particular, we develop the curve-tracking controllers for autonomous vehicles with rigidly mounted range sensors, and a provably complete exploration strategy is proposed so that one vehicle with range sensors builds a topological map of an environment. The SCENT algorithms introduced in this thesis extend the exploration strategy for one vehicle to multiple vehicles. The enabling idea of the SCENT algorithms is to construct a topological map of the environment, which is considered completely explored if the map corresponds to a complete Voronoi diagram of the environment. To achieve this, each vehicle explores its local area by incrementally expanding the already visited areas of the environment. At the same time, every vehicle deploys communication devices at selected locations and, as a result, a communication network is created concurrently with a topological map. This additional network allows the vehicles to share information in a distributed manner resulting in an efficient exploration of the workspace. The efficiency of the proposed SCENT algorithms is verified through theoretical investigations as well as experiments using mobile robots. Moreover, the resulting networks and the topological maps are used to solve coordinated multi-robot tasks, such as capturing intruders.