In this thesis, we proposed a precoding scheme for semi-blind channel estimation in amplify-and-forward (AF) multipath two-way relay networks (TWRN), where two terminals exchange their information through multi-relays. The precoding scheme, which diminishes computational complexity of semi-blind channel estimator, is used to distinguish received signal at both terminals from multi-relays. By applying a non-redundant linear precoding scheme at multi-relays, we proposed a semi-blind channel estimation to estimate the channel impulse response (CIR) of direct link and the cascaded source-relay-terminal links. Firstly, semi-blind channel estimation adopts least-square (LS) estimation to find the CIR of direct link between both terminals using a smaller number of training symbols. Secondly, the CIR of the cascaded source-relay-terminal links are obtained through second-order statistics (SOS) of received signals at both terminals. Consequently, the proposed scheme can effectively reduce the computational complexity and enhance the spectral efficiency in overall system. Simulation results corroborate the effectiveness of the proposed scheme.