The present work provides charge state fractions that may be used to generate TEAMS relative sensitivity factors for impurities in semiconductor materials.

Porphyrins derivatized with electron donating and electron withdrawing groups can be used for artificial photosynthesis. Four new compounds, two electron donors and two electron acceptors, have been synthesized for prospective porphyrin linkages.

Thesis (Ph. D.)--University of Washington, 2003. / Vita. Includes bibliographical references (p. 76-82).

A Charge-Exchange Recombination Spectroscopy (CXRS) diagnostic has been installed on Alcator C-Mod to study the transport of light impurities in plasma. The system provides spatially (1 cm) and temporally (12.5 msec) resolved measurements of the impurity density, temperature and flow velocities of the particular impurity. Two optical arrays: poloidal (19 channels) and toroidal (10 channels), collect the light emitted from excited impurity ion populated by charge exchange process from the Diagnostic Neutral Beam (DNB) particle. The attention of this dissertation is focused on the B⁴⁺ (n = 7 [-->] 6) spectral line emitted by B⁴⁺ ion formed in the following charge exchange reaction (H⁰ + B⁵⁺ [-->] H+ + B⁴⁺*). A complex spectral model was developed to simulate emission. The high magnetic fields of C-Mod result in broad Zeeman patterns which must be taken into account for the interpretation of the line shift and broadening in terms of impurity ion velocity and temperature. After the spectral line fitting and careful identification of the charge exchange component, the calculated Doppler broadening and shifts of the spectral line profile yield information on the ion temperature and rotation. Together with the calculation of the beam density, the absolute calibration of the CXRS optical system provides us with B⁵⁺ density measurement capabilities. One of the main objectives of this work was to use the acquired impurity density, temperature and flow velocity profiles to investigate plasma transport behavior and infer the radial electric field E[subscript R] from plasma force balance equation. The focus here was placed on the region of the Internal Transport Barrier (ITB) formation 0.35 < p < 0.8. Radial electric field E[subscript R] is readily calculated in the region of the ITB foot using measured B⁵⁺ profiles. ExB velocity shearing turbulence stabilization are believed to play an important role in the physics of the ITB formation. The computed E[subscript R] profiles demonstrated the large difference between the H-mode and ITB discharges. Linear gyrokinetic stability analysis (GS2) demonstrated that shearing rate w[subscript ExB] prevails over the linear Ion Temperature Gradient (ITG) growth rates [gamma subscript max] in the region where ITB forms. / text

Access to abstract restricted until 12/14/2015. / Access to thesis restricted until 12/14/2015. / Department of Chemistry

Thesis (Ph. D.)--University of Washington, 2007. / Vita. Includes bibliographical references (p. 169-185).

Thesis (Ph. D.)--University of Nevada, Reno, 2007. / Includes bibliographical references (leaves 95-99). Library also has microfilm. Ann Arbor, Mich. : ProQuest Information and Learning Company, [2008]. 1 microfilm reel ; 35 mm. Online version available on the World Wide Web.

Thesis (Ph. D.)--Ohio State University, 2008. / Title from first page of PDF file. Includes bibliographical references (p. 272-288).

Thesis (Ph. D.)--University of Texas at Austin, 2008. / Vita. Includes bibliographical references.

Thesis (Ph. D.)--West Virginia University, 2002. / Title from document title page. Document formatted into pages; contains xv, 217 p. : ill. (some col.). Includes abstract. Includes bibliographical references (p. 213-217).