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No description available.

The reactivity of the [(Phen)Cr(CO)_3] intermediate with phosphines and phosphites (L) has been investigated through ligand-competition studies. This intermediate possesses virtually no ability to discriminate among L. The agreement between reactivity data for the thermal and photochemically-generated intermediates indicates that the same intermediate is produced via each process. Pulsed laser flash photolysis of (n^2-NP)M(CO)_4 (I) (M = Cr, Mo; NP = 1-diethylamino-2-diphenylphosphinoethane) in the absence and presence of P (OPr-i)_3 (L) in 1,2-dichloroethane and chlorobenzene induces unimolecular ring-opening to afford [(n^1-NP)M(CO)_4] (II), in which the bidentate ligand is coordinated through P. Reaction of this intermediate takes place through competitive ring-reclosure and attack at (II) by L to afford (I) and cis-(n^1-NP) (L)M(CO)_4.

A series of studies were initiated to investigate growth responses of Kentucky bluegrass (Poa praetensis L.) and creeping bentgrass (Agrostis palustris Huds.) to foliar applications of two plant growth regulators (PGR) and/or chelated Fe (Na Fe diethylene triamine pentaacetate). Environmental variables considered were N levels, soil moisture regimes, and saline irrigations. The two materials investigated for PGR properties were a commercial product called Roots (a cold-water extract of seaweed and peat humus fortified with "intermediate metabolites" and thiamine) and the systemic fungicide propiconazole, trade name: (Banner) and chemical name: [1- {(2-(2,4-dichlorophenyl)-4-propyl-l,3-dioxolan-2yl}methyl-l H-1,2,4-triazole]. Fortified seaweed extract (FSE) was applied at 9.3 L/ha, and propiconazole (PPC) was applied at 0.93 L a.i/ha. Each was applied alone or in conjunction with chelated Fe at 0.11 kg a.i/ha. Kentucky bluegrass foliage height, root and shoot dry weight, and several foliar nutrients increased following PGR treatments when grown under either limited soil moisture or saline irrigation. Foliar applications of PGR and/or chelated Fe to creeping bentgrass reduced wilting and evapotranspiration, and increased leaf water status, root strength, and shoot dry matter at two levels of N during and after drought stress. / Ph. D.