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Synthesis and characterization of heterometallic metal organic frameworksChou, Cheng-Tsung 10 January 2013
Synthesis and characterization of heterometallic metal organic frameworks
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Olefin metathesis for metal incorporation and ligand exchange reactions for the preparation of new ruthenium compounds and materialsSchuehler Sherwood, Danielle E. January 2009 (has links)
Thesis (Ph. D.)--Syracuse University, 2009. / "Publication number: AAT 3381593."
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Hydroxyl radical reaction and lanthanide ion complexation kinetics of DTPACullen, Thomas Donovan 22 November 2013 (has links)
No description available.
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Self-Assembly of Functionalized Supramolecular StructuresYoung, Michael Christopher 14 November 2014 (has links)
<p>Enzymes are capable of exquisite selectivity in catalysis chemical reactions because of a well-evolved mechanism that binds substrates in internal active sites based on size and shape complementarity. The cavities of these enzymes are decorated with organic or inorganic groups which can promote reactivity once the substrate is non-covalently bound. Synthetic molecular hosts to date have been able to bind to substrates in a similar, biomimetic fashion, but functionalized molecular hosts are still virtually unknown. </p><p> One convenient way to prepare molecular hosts is by the self-assembly of organic coordinating ligands with suitable metal salts. The reversible dative bonds holding these cage structures together allow incorrect products to break apart and reform, favoring creation of the most thermodynamically stable product. This leads to discrete, solution phase cages that can function as cavity-containing hosts. Some of these hosts have shown efficacy as catalysts for pericyclic reactions due to favorable transition states of the bound substrates. These cages, however, fail to orient reactive functional groups into their interiors. Truly biomimetic cages will require modifying traditional self-assembled targets to incorporate these reactive functionalities. </p><p> This work explores the self-assembly of metal-organic cages displaying covalent modifications on their interior. Incorporation of unreactive and poorly reactive groups was found to have a significant impact on the outcome of the self-assembly process. Cages with endohedral alcoholic functionality were found to have different binding properties than unfunctionalized analogs. Cages with introverted alcohol groups were also exploited for their ability to self-catalyze reactions <i>on the interior</i> of the hosts. The metal vertices themselves could also be used as functional groups, and showed the ability to sense neutral analytes in hybrid dative/hydrogen bonded self-assemblies. </p>
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Development of Catalytic Methods for the Synthesis of Phosphine Oxides and for the Oxidation of WaterBloomfield, Aaron James 26 June 2014 (has links)
<p> The first part of this thesis is a story about the design and optimization of synthetic methodology for the preparation of complex secondary and tertiary phosphine oxides. A scalable, single-step, acid-catalyzed addition-rearrangement cascade that couples aldehydes with primary phosphines to give racemic unsymmetrical secondary phosphine oxides (SPOs) was developed based on the observations and hypotheses reported in a collection of papers published in the early 1960s. Most of this work was reported in a communication published in Organometallics (<i>Organometallics</i>, <b>2010</b>, <i>29</i>, 4193-4195).</p><p> A general method for kinetic resolution of racemic SPOs by asymmetric catalytic arylation was the next target, but this required a catalyst and conditions that would operate at room temperature. After finding that a Xantphos-Pd complex suited this purpose, and demonstrating broad utility and stereospecific coupling, an optically active analog of Xantphos was designed and synthesized. When combined with palladium, this "Slantphos" catalyzed the arylation of racemic SPOs, with modest stereoenrichment. Much of this work was reported in a communication published in Organic Letters (<i>Org. Lett.</i>, <b> 2012</b>, <i>14</i>, 4370-4373).</p><p> The second part of this dissertation details the discovery of a novel class of materials, some of which are highly active catalysts for the electrochemical oxidation of water. The most active of these catalysts was selected for detailed electrochemical studies in several different electrolytes. At pH 7, borate was found to be superior. Several studies were also undertaken to characterize the material before and after catalysis, but the structure remains undetermined. Most of this work was reported in a full paper published in the New Journal of Chemistry (published online January 15, 2014).</p>
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Synthesis, characterization, and reactivity of titanium-ligand multiply bonded complexes supported by sterically encumbering beta-diketiminate and PNP pincer-type ligandsBailey, Brad Cameron. January 2007 (has links)
Thesis (Ph. D.)--Indiana University, Dept. of Chemistry, 2007. / Source: Dissertation Abstracts International, Volume: 68-09, Section: B, page: 5940. Adviser: Daniel J. Mindiola. Title from dissertation home page (viewed May 12, 2008).
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Structural supramolecular assemblies of spheres and tubes /Heaven, Michael William. Unknown Date (has links)
Thesis (Ph. D.)--University of Missouri - Columbia, 2006. / (UMI)AAI3242738. Adviser: Jerry L. Atwood. Source: Dissertation Abstracts International, Volume: 67-11, Section: B, page: 6405.
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Rhodium-catalyzed carbocyclization reactions for the synthesis of five- and six-membered ringsSawyer, James R. January 2008 (has links)
Thesis (Ph.D.)--Indiana University, Dept. of Chemistry, 2008. / Title from PDF t.p. (viewed on May 13, 2009). Source: Dissertation Abstracts International, Volume: 69-08, Section: B, page: 4763. Adviser: P. Andrew Evans.
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Manipulation of the ligand sphere of ruthenium metathesis catalysts for the synthesis of organometallic molecular wiresBolton, Sarah L. January 2008 (has links)
Thesis (Ph. D.)--Syracuse University, 2008. / "Publication number AAT 3333562."
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Small molecule activation using transfer hydrogenation catalysts /Heiden, Zachariah Matthew, January 2008 (has links)
Thesis (Ph. D.)--University of Illinois at Urbana-Champaign, 2008. / Source: Dissertation Abstracts International, Volume: 69-11, Section: B, page: 6790. Adviser: Thomas B. Rauchfuss. Includes bibliographical references. Available on microfilm from Pro Quest Information and Learning.
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