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Cholic acid based new chiral auxiliaries: development and applicationsMathivanan, P. 09 1900 (has links)
The thesis entitled Cholic Acid Bused New Chiral Auxiliaries: Development And Applications has been divided into three chapters. Chapter-I describes the synthesis of chiral auxiliaries (1.3) from cholic acid and Diets-Alder reactions on the corresponding a,B- unsaturated ester derivatives. Chapter-I1 deals with the asymmetric dihydroxylation of a,B unsaturated esters of steroidal alcohols (1-3). Chapter-HI describes asymmetric hydride reduction, hydrogenation and allylation of a-keto esters of cholic acid derivatives (1-3).
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