There are three related studies within this thesis that examine the relationships between the properties of coals and the characteristics of the chars produced during rapid pyrolysis in a laboratory based Entrained Flow Reactor (EFR) which simulates the rapid rates of heating (104 to 105 °C s-1 ) typical of pulverised fuel boilers. The first study, using a suite of nine coals, investigates the influence of coal rank upon the generation of specific types of char, their respective physical and structural characteristics and their relative combustabilities. The second study, using a suite of twenty-two coals, examines various coal characterisation techniques and the correlations between those techniques and the associated char, and specifically investigates petrographic techniques as a means of characterising coal feedstock. The third study, using freshly mined coals, investigates the effects of oxidation (100°C, air) and weathering (ambient) upon standard analytical techniques and relates such changes to the physical, structural and combustion characteristics of the associated char. There is a common relationship between the elemental oxygen content of the parent coal and the generation of specific types of char for both vitrinite rich coals of differing coal rank and for the oxidised or weathered coals. There is also an inverse relationship (R 2 = 0.97) between the elemental oxygen content of a vitrinite rich coal and the proportion of cenospheres generated by pyrolysis at 1000°C using the EFR. Furthermore, the enhancement of char combustion at 1000°C (in an EFR) is related to the physical and structural characteristics of the char, i.e. the presence or absence of porosity (visible using SEM and TEM), the CO2 surface area and optical texture. A relationship exists (R2 = 0.83) between the morphology of a char (1000°C / N2) and the petrographic composition of the parent coal. The new term microlithotype, is an amalgamation of various vitrinite rich microlithotype classes that simplifies the nomenclature. A combination of calorific value, microlithotype, and coal rank (vitrinite reflectance) illustrates the influence of petrographic composition upon calorific value and also suggests a 'Province' dependency amongst the Cretaceous/Tertiary and Carboniferous coals studied. The coal properties calorific value, microlithotype, and coal rank can be related (R 2 = 0.91) to the proportion of porous chars for the Cretaceous/Tertiary suite of coals, illustrating the use of multivariate analyses when characterising coal feedstock. The effects of oxidation and weathering upon vitrinite fluorescence is also reported. The oxidation of coal at 100°C produces rims of quenched fluorescence which are not apparent within the weathered coals. Furthermore, the intensity of fluorescence at 650 nm (1650) decreases due to progressive oxidation or weathering, but decreases at a rate that is dependent upon the severity (temperature) of the conditions employed. The proposed oxidation quotient (0/Q = I65W%Romax) is a sensitive indicator of the oxidative conditions up to 100°C.

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Cleats are natural fractures in coal that serve as permeability avenues for darcy flow of gas and water to the well bore during production. Theoretically, the development of cleat and coal-seam permeability is related to the rank, type and grade of the coal concerned. The permeability of a coal seam, moreover, may change during gas production, due to either matrix shrinkage, cleat closure or both. Matrix shrinkage and cleat closure are also affected by numerous geological factors, including coal rank, desorption character and geological setting. A method integrating geochemical and petrographic analysis, reservoir engineering diagnosis, geophysical data and production characteristics has been developed, and used to determine the initial permeability of coal seam on a metre by metre scale. This overcomes the constraint of conventional well test by refining the test intervals. The effect of coal rank, grade and type on the initial permeability of coal seams was also investigated, with the special reference to the coals of the Galilee Basin. The permeability was estimated using analytical equations based on the permeability data obtained from well tests and from cleat descriptions within the seam section. This aspect of the study showed that the coal type, rank and grade strongly influence the initial permeability of individual coal seams. Increase in ash content has negative effect on cleat development and permeability. On contrast, increasing coal rank and proportion of bright coal lead to reduction in cleat spacing and increase in permeability. Twenty three core samples collected from the Qinshui Basin in China were evaluated in the laboratory to investigate the effects of coal grade, rank and type on the change in permeability during pressure depletion. The experimental factors included the coal's geochemical properties, the permeability against changing pressure, and strain with pore pressure depletion. This part of the study fund that permeability changes with pore pressure depletion in relation to coal rank, grade and type. The strain values determined by the experiments with pressure depletion were used to identify the mechanical principles associated with changes in permeability during pressure depletion in relation to the rank, grade and type of the coal concerned. A reservoir simulation study was used to investigate the effects of desorption pressure, geological setting and coal rank on the variation in permeability under in-situ conditions during coalbed methane production, based on a study in the Hedong area, Ordos Basin, China. The simulations allowed history matching of gas and water production from 12 wells with the actual well conditions specified as the model pressure. Good agreement was achieved between the model yields and the actual production data, suggesting that the changing permeability interpreted from the simulation is a realistic representation of the in-situ reservoir properties. The reservoir simulation study found that the decreases in permeability with production exceeded the increase in permeability caused by matrix shrinkage for nearly all wells in the Hedong area. The magnitude of the decrease in permeability increases as the gap between initial pressure and desorption pressure increases. The decrease in permeability is slower in the zone closest to the fault. The reservoir simulation has demonstrated that coal rank influences significantly the change in permeability during coalbed methane production.

High-intensity pyrolysis, rapid heating in an inert gas atmosphere at up to 20 atm pressure, of 6 Australian coals was examined to gain further insight into high-intensity processes such as Integrated Gasification Combined Cycles (IGCC). Experiments focussed on pyrolysis in a specially developed Wire Mesh Reactor (WMR). The particle temperature lagged that of the mesh by 0.2 seconds at a heating rate of 100??~C s -1 and was predicted by modelling. This is part of the reason the volatile yield (VY) results for 10 s hold-time at ???b1.7 wt% daf of coal, is much more reproducible than 1 s hold-time experiments at ???b4.2 wt% daf of coal. Four coals of the same rank did not behave identically when heated. Three of the coals had a pyrolysis VY the same as the proximate VM when heated to 100??~C at 1 atm but the fourth, higher inertinite coal had a 1 atm pyrolysis VY 90% of its proximate VM. All four coals of similar rank had a significant decrease in VY, between 10 and 20 wt% daf of coal, with pressure increasing from 1 to 20 atm. The two lower rank coals showed less decrease in VY with increasing pressure than the higher rank and higher inertinite coals. The lower decrease in VY with increased pressure was mostly attributed to the lower inertinite levels for both the coals of similar rank and VM, and the coals of lower rank. Char characteristics examined focussed on pore Surface Area (SA). For high intensity WMR and Drop Tube Furnace (DTF) pyrolysis experiments CO2 SA for char from a particular coal was similar but the BET SA different. This was due to the char in the WMR experiments having longer to form larger pores determined by BET N2 SA. Both the N2 and CO2 SA was more than an order of magnitude greater than for low intensity pyrolysis char. This highlights that the WMR can be used to attain char with similar CO2 SA characteristics as other high intensity pyrolysis experiments and to provide a more meaningful insight into char reactivity than low intensity chars do.

Integrated gasification combined cycle is an advanced electricity generation technology, based on coal gasification. Wider deployment requires further research into the components of the process, including coal gasification. The coal gasification reactions are the slowest step in the gasifier and therefore determine size and operating conditions. Understanding the rate of the gasification reactions at high temperatures is crucial for accurate design and optimisation of the gasification process. While the rates have been measured at low temperature, limited data exist at the high temperatures and pressures relevant to entrained flow gasifiers. As the reactions are solid gas reactions, at high temperature they depend on both reaction rate and gas diffusion rate, which complicates the extrapolation of low temperature data. High temperature data measured thus far is only applicable to certain coals, as the gasification rates were not related to char properties. The aim of this thesis was to measure the high temperature gasification rates of three coal char samples and interpret the results in terms of the char morphology and intrinsic reactivity. The results showed that the gasification rate depended on both intrinsic reaction rate and diffusion rate under the experimental conditions. The majority of the char particles were very swollen, with high porosity and thin walls, whereas the conventional analysis approach assumes porous spherical particles. The effectiveness factor approach was modified to incorporate flat-plate geometry, and used to extract the intrinsic reaction rate from the gasification rate data, which showed that the intrinsic reaction rate could be extrapolated to higher temperatures. The application of the effectiveness factor for estimating the gasification rate was demonstrated, and the modified approach was found to give a better estimation of char gasification rate at high temperature. Accurate measurement of char wall thickness and porosity was identified for potential improvement of the approach. Char conversion in a pilot-scale entrained flow gasifier was then explained in terms of char reaction rate, char morphology and reaction temperature, which showed the need for the development of more accurate models of char conversion in gasifiers, to which the work in this thesis can be applied.

Bibliography: leaves 234-252. / xxiv, 254 leaves : ill. (some col.) ; 30 cm. / Title page, contents and abstract only. The complete thesis in print form is available from the University Library. / The devolution times of seven coals were determined by measuring the centre temperature response for single particles held stationary in a bench scale atmospheric fluidised-bed reactor. / Thesis (Ph.D.)--University of Adelaide, Dept. of Chemical Engineering, 2000

Thesis (Ph. D.)--University of Washington, 1989. / Vita. Includes bibliographical references.

Thesis (M.S.)--West Virginia University, 2007. / Title from document title page. Document formatted into pages; contains vii, 66 p. : ill. (some col.). Includes abstract. Includes bibliographical references (p. 55-57).

Thesis (M.S.)--Ohio University, August, 1982. / Title from PDF t.p.