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Settlement of open cast mine backfill : two large scale field testsVan Wyk, Wilhelm Jacobus January 1998 (has links)
A dissertation submitted to the Faculty of Engineering, University of
Witwatersrand, in fulfillment of the requirements for the degree of
Master Science in Engineering / The Electricity Supply Commission of South Africa (Eskom) have identified open cast coal
mine backfill areas as potential disposal sites for the large volumes of coal ash produced
by their power stations. As Eskom's power stations are mainly situated in agricultural and
coal rich areas of the provinces of Mpumalanga and the Free State, the sterilisation of
substantial areas of agricultural soil and coal deposits is thus reduced.
The construction of a tailings dam or dump on uncompacted open cast mine backfill
creates various problems related to the settlement of the backfill. The scale of the
operation, the large particle size and heterogeneous nature of the backfill and its method
of placement complicates the prediction for settlement of the backfill.
Areas in excess of 74 000 ha could be subjected to opencast mining in Mpumalanga and
for future development of these areas more information regarding the magnitude and
mechanics of mine backfill settlement is required.
This dissertation describes two large scale field tests in which the settlement of mine
backfiil was studied during the construction of a test section of an ash tailings dam and
the construction of a dry ash dump. / Andrew Chakane 2019
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Hydrogeochemical modeling of the speciation and leaching of fly ash co-disposed with water, brines and organics : a case study of Sasol-Eskom coal ash disposal, South Africa.Mbugua, John Mwai. 06 December 2013 (has links)
Two coal utility plants in South Africa selected (one from Sasol and another from Eskom) for this study produce large volumes of fly ash (over 40 Mt from Eskom at Tutuka, and 3 Mt from Sasol Synfuels at Secunda annually), and brines as by-products during coal processing. Co-disposal of the brines and fly ashes has been a normal practice in these coal-utility plants for decades. Long-term management of fly ash is necessary and requires an understanding and knowledge of how the different waste materials interact with water and brines in different chemical situations. However the geochemistry of their interactions, the leaching and mobility of elements in these disposal systems has not been fully understood. This work gives insights into the chemical processes taking place in the brine-water/brines systems that govern the concentrations of major and minor elements in ash leachates under different environmental conditions. The possible presence of organic compounds (subsequently referred to as 'organics') in brines and their effects on the leaching chemistry of fly ash was also studied. Sustainability and long term impact of the co-disposal of fly ash and brines on the environment was studied through static (batch tests) modeling of the pH-dependent acid neutralization capacity (ANC) tests and columns modeling for dynamic leach tests. The modeling was based on experimental results from other Sasol-Eskom ashbrine project collaborators. Modeling results of the ANC tests were in good agreement with the reported experimental results, which revealed that the release trends of various elements (including trace, heavy elements and contaminants) contained in fly ash into solution is highly pH dependent. However Na, K, Mo and Li exhibited constant solubilisation which was independent of pH changes from all the scenarios. The presence of different constituents of brines subjected to ANC resulted to different ANC capacities ranging from 0.98 moles H⁺/Kg dry ash (of ash-organics mixed with Mg-brines) to 3.87 H⁺/Kg dry ash for those with the C(4) brines. As expected, those constituents from the cationic brines were found on the lower region of acid addition (in the order Mg-brines < Ca-brines < Na-brines) while the anionic brines were found at the upper region of acid addition (in the order S(6)-brines < Cl-brines < C(4)-brines). In the middle region of acid addition were three important scenarios: that of ash with brine, ash without brines (i.e. ash with DMW) and ash with both ASW organics and combined brines. It was from these three scenarios that a generalization of the effect of brines and organics on the ANC was inferred. The ANC of ash with demineralised water (DMW) was 2.33 mol H⁺/Kg dry ash and that of ash with ASW organics lower at 2.12 mol H⁺/Kg dry ash which was the same value as that of ash with combined brines. This indicated that brines decreased the ANC of ash by about 9.01 % and which could be attributed to the acid-base neutralization process and the dynamics of solid phase dissolutions in response to the acid addition. Both fly ashes exhibited a typical pH > 12 (suspension in demineralised water) and the predominant cation even at this high pH is Ca²⁺ (at concentration > 0.002 mmol/L). This indicates that dissolution of CaO and formation of OH⁻ species at pH > 10 contributes to acid neutralisation capacity of both fly ashes and is the greatest contributor to the acid neutralizing capacity of both fly ashes. Two broad leaching behaviours as a function of pH were observed from the three fly ash-ASW organics-brines scenarios (i) leaching of Ca, Mg, Ni and Sr follows a cationic pattern where the concentration decreases monotonically as pH increases; (ii) leaching of Al, Fe, Ti and Zn follow an amphoteric pattern where the concentration increases at acidic and alkaline pH, although Al showed some anomaly from pH 11 where the concentration decreased with the increase in pH. Al showed an amphoteric pattern in which its release increased between pH 12.8 and 11 for all the scenarios and then decreased with decrease in pH down to neutral pH of 7.
The batch leaching simulation results from hydrogeochemical modeling also showed that mineral dissolution, precipitation and new phase formation during ash-organics-brines interactions was controlled by pH. The newly formed phases however remain in equilibrium with the ash-brines-organics mixture. Each individual mineral phase dissolution/precipitation/formation system controls the concentration and speciation of the respective constituent elements as evidenced by the log C-pH diagrams obtained from the modeled scenarios. The ash-brines-organics interactions do exhibit and affect the mineralogical chemistry of fly ash. However the extent to which these interactions occur and their effect, varies from one scenario to another, and are dependent on the amounts and type of the constituent brine components. Organics do have a significant effect on dissolution characteristics of few minerals such as calcite, mullite, kaolinite, Ni₂SiO₄, and SrSiO₃ due to complexation effect. The effect is quantitatively conspicuous for calcite mineral phase and for the formation of some new phases such as Fe(OH)₃(am)-CF and portlandite.
The composition of the liquid phase from acid neutralisation capacity experiments was successful.Hydrogeochemical modeling was used as a means to provide insights and understanding of the complex reactions taking place, speciation and mineralogical changes occurring. These changes would serve to predict future environmental scenarios when pH conditions change. In this study, an extension of the application field of PHREEQC hydrogeochemical code for modeling and simulation of equilibrium; kinetic and transport mechanisms associated with the interaction of water; and organics and brines with fly ash during their co-disposal is successfully demonstrated.
The parameters associated with these mechanisms were used as inputs into the PHREEQC program using modified Lawrence Livermore National Laboratory (LLNL) database for inorganic brines and MINTEQ.V4 database for organics, and used to model the results of ANC test data for the fly ashes. A special reference is made to two separate modeled mineralogical ash recipes from two of the South African power utility plants' fly ash systems, namely, Tutuka and Secunda. The effects of brines in the leaching of major, minor and trace elements at various pH values and the mineralogical changes associated with the intermediate and final products from the interactions of ash-brines systems under different scenarios are qualitatively and quantatively discussed. Multiphase saturation characteristics have been determined for mineral species in contact with water and brines.
The modeling results indicated that several mineral phases could be controlling the species concentration in the leachates, and the ANC and column modeling results corroborated well in many aspects with the experimental results obtained from collaborating institutions (South Africa Universities and Research institutions). In addition, application of the PHREEQC model to the ash heap under different disposal systems was carried out to predict the heap leachate composition and geochemical transformations taking place in a period of time. Pore water chemical analysis, and moisture content analysis revealed that contact of the ash with water is a crucial factor in the mobilization of the contaminants with time. Maximum weathering/dissolution of the ash is observed in the top layer (1-3) m and at the point of contact with the subsurface water level which was in good agreement with the model results. The surface layer and the very lowest layers of the dump in contact with lateral flows experience the highest degree of weathering leading to depletion of species. The geophysical transformation of fly ash was also captured through the porosity change calculations and the results revealed that geochemical reactions do affect the porosity of fly ash during the weathering processes. These modelling results were in agreement with the hydraulic tests and salt leaching tests conducted during Sasol-Eskom ashbrine project in Phase I which suggested that salts captured in the ash will become mobile and leach from the fly ash over time. The data therefore indicates that ash dumps may not act as sustainable salt sinks. These findings may have some bearing on engineering decisions on fly ash reuse. From the above observations, it is apparent that release of large quantities of the salts in the ash depends on the extent of its interaction with brines being used for irrigation or with water, either through plug-in flow after a rainfall event or contact with groundwater. The results revealed effects of brine-water contact time with fly ash, the flow volume and velocity, the pH, the degree of saturation, hydrogeology and ash heap geometry as important factors that affect fly ash transformation and weathering.
Overall, the ash heap modeling enhanced the understanding of the ash-brines interactions and demonstrated that leachate composition is determined by the following factors; (i) the mass flows from the pores of fly ash, (ii) the surface dissolution of the mineral phases, (iii) the various chemical reactions involved during the ash-brine and ash-water interactions, (iv) the interactions with a gas phase (atmospheric CO₂), (v) the composition of the initial fly ash, and (vi) by the leachate flow and hydrodynamics as captured in the conceptual model. Any ash handling system should therefore be designed to take these criteria into consideration to prevent environmental contamination. The modeling results also gave indications that the ash-brine co-disposal in dry ash systems would be an unsustainable way of locking up brine salts in the long run.
In this Thesis, modeling results were used to support experimental data which further reaffirmed the important role hydrogeochemical modeling plays in liquid and solid waste management. Furthermore, hydrogeochemical modeling complements the work of analytical/environmental scientists as well as guiding the future solid waste management and engineering decisions. / Thesis (Ph.D.)-University of KwaZulu-Natal, Westville, 2012.
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Quantification of the bioccumulation potential of various chemical elements from coal fly ash using Brassia juncea and Spinacia oleracea L and its implication for phytoremediation of coal fly ash dumpsMashau, Aluwani Shiridor 18 September 2017 (has links)
MENVSC / Department of Ecology and Resource Management / South Africa is highly dependent on coal for production of electricity. The combustion of coal for electricity generation produces waste by-products which include fine ash (fly ash) and coarse ash. Fly ash (FA) is produced in large amounts while its utilization is low due to its classification as a hazardous material. Sasol produces about 7 million tons of FA, while Eskom produces about 28 million tons of coal FA annually. FA is a fine by-product from pulverized coal with detrimental effects on plants, soil or land, animals and human beings, and pollutes the air. The present investigation focuses on the examination of the chemical elements bioaccumulation and phytoremediation potential of Indian mustard (Brassica juncea) and Spinach (Spinacia Oleracea L).
X-ray fluorescence (XRF) was used to analyze the elemental composition of FA and soil, Scanning Electron Microscope (SEM) to examine the morphology, while X-ray diffraction (XRD) analysis was used to evaluate the mineralogy of FA. The concentrations of metal and non-metal species that are released from FA on contact with water at different conditions were quantified using ICP-MS. Pot culture experiment was conducted to grow Brassica juncea and Spinacia Oleracea L. using FA and soil as growth medium. Leachates from the pots were collected and analysed using ICP-MS. Plant parts from harvested Brassica juncea and Spinacia Oleracea L. were cut separately and analysed using ICP-MS for the concentrations of different metal and non-metal species in plant parts. Plant parts were also used to estimate biomass and chlorophyll content (leaves). To prepare these plant samples for analysis, the powdered plant sample (0.5 g) was digested through aqua regia (HCL:HNO3 = 3:1 (v/v)) to near dryness using hotplate and filled to 100 mL of MilliQ water. The samples were filtered and directly used to determine the chemical elements concentrations. Blanks and internal standards were used for quality assurance during analysis. Chemical elements that are present in FA and sometimes in higher concentrations are associated with detrimental effects in plants, animals and human beings, hence phytoremediation is vital. Bioconcentration factor (BCF) was used to estimate the metal species accumulation ability of the plants from the FA, FA/soil mixtures, while translocation factor (TF) was used to assess the plant species potential for phytoremediation of coal fly ash dumps. Analysis of Varience (ANOVA) was used to statistically test data using Graphpad software package. Relationship between chemical elements in soil, FA and FA+soil growth media and also different plant parts (root, stem and leaf) of B. juncea and S. Oleracea L were calculated using the t - test, ANOVA-Bartlett test, Mann-Whitney Test and Kruskal-Wallis Statistic (KW) depending on each data set.
The physicochemical characterization of coal fly ash showed that FA from Grootvlei power station can be classified as class F with an alkaline pH level of 10.62. It showed that particle morphology of this FA had a lower degree of sphericity with irregular agglomerations of many particles while there were dominant spherical particles and smaller sharp needle like particles. It is also an alumino-silicate material as confirmed by the high SiO2 and Al2O3 content, while soil leachates had an average/neutral pH of 7.22 with very high amounts of Si. In both soil and FA, elements that were expected to be readily available to plants included Ca, Si, K, Ba, Mo, Na, Al, Mg, Sr and non-essential elements (Si, Ba, Na, Al, Sr), which, if uptaken by plants’ roots can have negative impacts in plants. Physicochemical analysis of soil, FA and FA+soil leachates showed that the alkalinity of the FA changed over time and there was also a decrease in the EC due to dissolution
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of soluble major oxides, which was promoted by continuous water irrigation. The soil and FA+soil growth media showed similar results. Chemical elements like B, Mn, Fe and Ba were occurring at higher concentrations in leachates for most weeks in the pot culture experiments. However, it was observed that in the eleventh week of leachate collection all these chemical elements decreased to very low concentrations. This suggest that these chemical elements can be reduced over time as plants are being irrigated which is either due to uptake by plants or washed off with water. Statistically, there was a significant difference for different chemical elements of leachates from different growth media for each plant species (B. juncea and S. Olearcea L.).
The overall growth rate shows that S. Oleracea L was better than that of B. juncea especially in the FA media over time, while the biomass of the two plant species showed similar results. After all, even though S. Oleracea L had carotenoid content below detection limits, it had higher chlorophyll b than B. juncea for all growth media in general. But, statistically there was no significant difference between the two plant species in terms of growth rate and biomass; even between the plant parts denoting similar growth performance for the two plant species under study. The bioaccumulation potential of the two plant species showed that chemical elements such as Fe, Mn, Ba, Zn and B were highly accumulated by the different parts of the plants. However, the chemical elements such as of Mo, Ni, Cu, and Cr showed the least concentrations. This trend was similar for all growth media and both plant species but this changes over time for different growth media and plant species as increasing and decreasing trends can be noticed. This led to no significant difference between plant species and also growth media, statistically.
High BCF values of Fe, Mn, Ba, Zn and B were observed in the different parts of the plants for both plant species. However, Mo, Ni, Cu, and Cr had BCF values less than 1 for most growth media over time. BCF values in plant parts differed with time, growth media and plant species. Translocation of chemical elements shows that the B. juncea plant proved to be an effective phytoremediation plant species since it is effective in translocation of many chemical elements for different growth media to shoots while S. Oleracea L failed to translocate most chemical elements from stem to leaves although it translocated some from root to shoots. Hence, it can be concluded from the study that both species can be used in phytoremediation of coal fly ash dumps but with B. juncea being the most effective accumulator and translocator of many chemical elements. However, it can be recommended that chelating agents like ethylene diamine tetra acetic acid (EDTA) be introduced to solubilize chemical elements from growth media matrix into growth media solution to facilitate the quick transport of chemical elements into xylem, and increase
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