Thesis (Ph. D.)--West Virginia University, 2009. / Title from document title page. Document formatted into pages; contains xx, 148 p. : ill. (some col.). Includes abstract. Includes bibliographical references (p. 136-141).

Thesis (Ph. D.)--University of Missouri-Columbia, 1999. / Typescript. Vita. Includes bibliographical references. Also available on the Internet.

Thesis (M.S)--Ohio University, March, 2005. / Includes bibliographical references (p. 132-134)

Thesis (M.S)--Ohio University, March, 2005. / Title from PDF t.p. Includes bibliographical references (p. 132-134)

>Magister Scientiae - MSc / Energy production from coal comes with an environmental cost because of the toxic waste produced during coal combustion such as coal ash and brine which are potential water and soil pollutants. Coal ash and brine contain toxic elements which can leach and contaminate soils and ground water if not properly disposed. This study investigated the mobility of species in coal fly ash co-disposed with brine at Sasol Secunda power station in order to establish if the ash dam could act as a salt sink. The ash was dumped as a slurry with 5:1 brine/ash ratio and the dam was in operation for 20 years. It was hypothesized that the disposed Secunda fly ash was capable of leaching toxic metal elements into the surrounding soils and ground water and therefore could not be used as a long term sustainable salt sink. Weathered fly ash samples were collected along a 51 m depth core at the Secunda ash dam by drilling and sampling the ash at 1.5 m depth intervals. A fresh fly ash sample was collected from the hoppers in the ash collection system at the power station. Characterization of both Secunda fresh ash and Secunda weathered ash core samples was done using X-ray diffraction (XRD) for mineralogy, X-ray fluorescence (XRF) for chemical composition and scanning electron microscopy (SEM) for morphology. Analysis of extracted pore water and moisture content determination of Secunda fresh ash and Secunda weathered ash core samples was done in order to evaluate the physico-chemical properties of the fly ash. The chemical partitioning and mobility of metal species in the ash dam was evaluated using the sequential extraction procedure. The XRD spectra revealed quartz, mullite and calcite as the dominant mineral phases in the weathered Secunda ash core samples while Secunda fresh ash contained quartz, mullite and lime. The major oxides identified by XRF analysis for both Secunda fresh ash and Secunda weathered ash include: SiO₂, Al₂O₃, CaO, Fe₂O₃, MgO, Na₂O, TiO₂ and K₂O. The minor oxides identified for both Secunda fresh ash and Secunda weathered ash were P₂O₅, SO₃ and MnO. The trace elements identified for both Secunda fresh ash and Secunda weathered ash were As, Ba, Ce, Co, Nb, Ni, Pb, Rb, Sr, V, Y, Zr and Th. However, U was detected in some of the Secunda weathered ash samples but not in Secunda fresh ash. Both Secunda fresh ash and Secunda weathered ash was classified as class F based on the sum of the oxides of silicon, aluminium and iron by mass and the CaO content as reported by XRF analysis, and further classified as sialic and ferrocalsialic type highlighting the significant levels of Si, Al, Ca and Fe in the fly ash based on XRF analysis. The XRF analysis further showed that brine codisposal on the ash may have been responsible for the slight enrichment of some species such as Na, SO₄²⁻, Mg, K and V in the disposed Secunda weathered fly ash. However, there was no significant accumulation of these species in the disposed fly ash despite continuous addition of an estimated 117.65 billion litres of brine over the 20 year period that the dam existed. Furthermore, Secunda ash dam showed an overall total salt capture capacity of only -0.01 weight %, a strong indication that the ash dam was incapable of holding salts and would release elements to the environment over time. The scanning electron microscopy (SEM) analysis revealed spherical particles with smooth outer surfaces for Secunda fresh ash while Secunda ash core samples consisted of agglomerated, irregular particles appearing to be encrusted, etched and corroded showing that weathering and leaching had occurred in the ash dam. A decrease in pH, electrical conductivity (EC) and total dissolved solids (TDS) was observed in Secunda ash core samples compared to Secunda fresh ash. While Secunda fresh ash (n = 3) had a pH of 12.38 ± 0.15, EC value of 4.98 ± 0.03 mS/cm and TDS value of 2.68 ± 0.03 g/L, the pH of Secunda ash core (n = 35) was 10.04 ± 0.50, the EC value was 1.08 ± 0.14 mS/cm and the TDS value was 0.64 ± 0.08 g/L. The lower pH in the ash dam created an environment conducive to the release of species through leaching, while the lower EC and TDS in the ash dam implied the loss of ionic species from the ash which resulted from leaching. The moisture content (MC) analysis indicated that Secunda ash dam was very damp with an average MC of 54.2 ± 12.66 % for Secunda ash core creating favourable conditions for leaching of species in the ash dam while Secunda fresh ash had MC of 1.8 ± 0.11 %. The bottom of Secunda ash dam appeared water logged which could cause slumping of the dam. The sequential extraction procedure revealed that the major and trace elements contained in both Secunda fresh fly ash and Secunda weathered fly ash could leach upon exposure to different environmental conditions. The elements showed partitioning between five geochemical phases i.e. water soluble fraction, exchangeable fraction, carbonate fraction, Fe & Mn fraction and residual fraction. The labile phases consisted of the water soluble fraction, exchangeable fraction and carbonate fraction. The % leached out in the labile phases was expressed as a fraction of each element‟s total content e.g. Si (6.15 %) meant that 6.15 % of the total amount of Si in the ash was released in the labile phases. Na was the most labile among the major elements in the ash dam while Si and Al which form the major aluminosilicate ash matrix also showed significant lability. The % leached out in the labile phases for these major elements was as follows: for Secunda fresh ash: Si (6.15 %), Al (7.84 %), Na (11.31 %); for weathered Secunda ash core samples (n = 35): Si (7.53 %), Al (8.12 %), Na (11.63 %). This study showed that the fly ash generated at Sasol Secunda power station could not be used as a long term sustainable salt sink. The wet disposal method used at Sasol Secunda power station poses a high risk of groundwater contamination due to the high liquid to solid ratio used to transport the ash for disposal, which may lead to rapid dissolution of all the soluble components in the fly ash. The large volumes of brine that pass through Secunda ash dam in the wet ash handling system present a greater environmental concern than the dry ash handling system which involves small amounts of brine entering the ash dump.

The gasification of carbonaceous fuel materials offers significant potential for the production of both energy and chemical products. Advancement of gasification technologies may be expedited through the use of computational fluid dynamics, as virtual reactor design offers a low cost method for system prototyping. To that end, a series of numerical studies were conducted to identify a computational modeling strategy for the simulation of coal gasification in fluidized bed reactors. The efforts set forth by this work first involved the development of a validatable hydrodynamic modeling strategy for the simulation of sand and coal fluidization. Those fluidization models were then applied to systems at elevated temperatures and polydisperse systems that featured a complex material injection geometry, for which no experimental data exists. A method for establishing similitude between 2-D and 3-D multiphase systems that feature non-symmetric material injection were then delineated and numerically tested. Following the development of the hydrodynamic modeling strategy, simulations of coal gasification were conducted using three different chemistry models. Simulated results were compared to experimental outcomes in an effort to assess the validity of each gasification chemistry model. The chemistry model that exhibited the highest degree of agreement with the experimental findings was then further analyzed identify areas of potential improvement. / Ph. D.

For a given coal gasification atmosphere, the reactions between fired alumina-chromia solid solution refractories and alkali (sodium and potassium) with and without sulfur at varying alkali concentrations were thermodynamically calculated using the SOLGASMIX-PV computer program and the results were experimentally confirmed. In addition, the kinetics of alkali diffusion into the refractory were experimentally determined as a function of time and temperature. The results, both experimental and theoretical, show formation of alkali-aluminate (Na₂O⋅Al₂O₃, K₂O⋅Al₂O₃) and β-alumina (Na₂O⋅11Al₂O₃, K₂O⋅11A₂O₃) compounds with formation of several metastable alkali compounds in a coal gasification environment. Sulfur did not appear to affect the reaction products. Alkali distribution into the alumina-chrome refractory is rapid and the formation of the Na₂O⋅Al₂O/K₂O⋅Al₂O₃ compounds cause large volume expansion from the reaction surface which causes poor thermal shock resistance and eventual refractory failure. The hot face of an alumina-chrome refractory in service in an alkali environment will be prone to failure by alkali attack. / Master of Science

An experimental test system was designed to simulate the operating conditions found in nonslagging coal gasifiers. The reaction products that form when refractory linings in coal gasifiers are exposed to alkali impurities (sodium or potassium) were experimentally determined. Analysis of selected physical and chemical properties of the reaction products, which typically form between the alkali and the refractory will lead to a better understanding of the mechanisms behind refractory failures associated with alkali attack. The reaction products sodium aluminate (Na₂O·Al₂O₃), N₂C₃A₅ (2Na₂O·3CaO·5A1₂O₃), nepheline (Na₂0·Al₂0₃·2SiO₂), potassium aluminate, (K₂Oâ·Al₂0₃), and kaliophilite (K₂O·Al₂0₃·2Si0₂) were synthesized and their solubility in water and coefficients of linear thermal expansion were: measured. Of the compounds tested, the formation of potassium aluminate would be the most detrimental to the gasifier lining. The linear thermal expansion of potassium aluminate was 2.05% from room temperature to 800°C, which was twice as large as the other compounds. Potassium aluminate also possessed the highest solubility in water which was 8.893/L at 90°C. / Master of Science

Three monolithic refractories (a 90+ wt.% alumina Castable, a 50+ wt.% alumina castable, and a 90+ wt.% alumina phosphate-bonded ramming mix) doped with up to 2.0 wt.% Fe and 2.0 Fe wt.% Fe₂O₃ were tested for CO disintegration in a 100 hr. test similar to. ASTM C-288. The effects of CO₂, NH₃, H₂, H₂S, and H₂O on CO disintegration were observed. Prefired samples of all three refractories were found to be susceptible to disintegration in a CO atmosphere when 0.5 wt.% Fe or more was added. Castables doped with up to 2.0 Fe wt.% Fe₂O₃ were not affected by CO, while the ramming mix doped with 1.5 Fe wt.% Fe₂O₃ or more was. H₂ and H₂O proved most effective in retarding CO disintegration in all three refractories. CO₂, H₂S, and NH₃, in descending order, also retarded CO disintegration in both castables. The retarding effect of up to 15% CO₂ in CO is questionable for the ramming mix. NH3 did not slow CO disintegration in this refractory and H₂S actually accelerated the disintegration process. The effect of gas pressure is also found to be especially important, for it greatly accelerates CO disintegration in all three monoliths and appears to be a more significant factor than the disintegration~inhibiting gases. An optimum iron-impurity size range, neither a maximum nor a minimum, for which CO disintegration resistance was greatest was also found for the 90+ wt.% alumina castable. / Master of Science

Call number: LD2668 .T4 1979 U57 / Master of Science