Coastal karst aquifers are important water resources, often providing the only source of freshwater to coastal communities for agriculture, industrial usage and human consumption. In order to implement management strategies and preventative measures for future perseveration of this resource, it is imperative to understand how coastal groundwater conditions are controlled by the interaction of freshwater/seawater on local and regional scales, but also over recent and past time periods. However, there is a limited resource of published hydrological data on recent aquifer conditions. In the Yucatán Peninsula and other anchialine environments, this lack of information inhibits the understanding of the spatial and temporal interaction of the meteoric and marine water masses. Documenting how the aquifer is responding to forcing mechanisms such as large precipitation events, seasonal cycles and short-term sea level rise (e.g. storm surge) will assist in understanding modern aquifer condition but also the interpretation of paleo-records. Utilization of water level and salinity sensors in strategic positions in the aquifer demonstrate that meteoric water mass salinity varies over wet and dry seasons with the movement of the halocline, but also on a short-term basis though large rainfall events. Salinity in the meteoric water mass is influenced by mixing with the marine water mass during intense precipitation events associated with Hurricane Ingrid (2013), Tropical Storm Hanna (2014) and a series of unnamed events in 2015. During wet periods, induced flow from increase precipitation causes turbulent mixing with the marine water mass, increasing salinity in the upper meteoric lens. On the contrary, during dry periods, mixing is reduced, therefore making the meteoric lens less saline. This contemporary understanding of meteoric/marine water mass dynamics can be applied to developing and calibrating the geochemical record of calcite rafts, calcite precipitation at the air-water interface of cave pools, as a hydrological proxy for aquifer conditions. Our monitoring of calcite raft formation, deposition and geochemistry shows that raft accumulations (e.g., raft piles/cones) can offer a good paleoenvironmental archive of changing hydrological conditions. Based on a 2-year observational record, results indicate that calcite raft precipitation/formation occurs continuously but with only minor biases with intense rainfall events altering supersaturation conditions in the surface waters. Testing the use of calcite rafts in sediment cores from Hoyo Negro show that geochemical analyses (87Sr/86Sr, δ18O, δ13C, Sr/Ca and Cl/Ca) show that meteoric water mass salinity varied during the Holocene (~ 8.5 Ka – present) likely due to changing rainfall and or cave passage geomorphology, which is coherent with other independent climate records. Prior to this study, calcite rafts have never been considered a paleo-hydrological archive for aquifer conditions, however, the consistency and cross-validation with independent records demonstrates great potential for future paleohydrological reconstructions. / Thesis / Doctor of Philosophy (PhD)

The disintegration of the Classic Maya throughout the Terminal Classic (750-900 C.E.) is a complex loss of human population that has presented many questions about climate change and its impact on humanity. With droughts proposed as a prominent cause, understanding the quality and availability of groundwater resources at the time is pivotal to further determining the spatial and temporal distributions of population deterioration. The Yucatan aquifer consists of karstic cave systems, with a small number of inland lakes, which have previously been termed closed to the aquifer. It is important to understand how both of these types of water bodies react to long- and short-term forcing mechanisms such drying climate, sea-level rise and precipitation events. Using a variety of spatial and temporal records to determine aquifer evolution, changes and connectivity throughout the Holocene it will further understanding of how the aquifer reacts to changes in climate and the implications this may have had on the Classic Maya. Four sediment cores from Pac Chen Lake and two sediment cores from Carwash Cenote were collected to investigate Holocene paleoclimatic trends on the Yucatan Peninsula in Mexico. Records of past climate, groundwater conditions and flooding history at both sites were determined through microfossil and micro X-Ray fluorescence data. In Pac Chen Lake, elevation and timing of flooding of the lake coincided with sea-level rise. Using Ti, Fe and K records to determine wet vs dry conditions, dry periods through the terminal classic coincided with other paleoclimate records, but with no evidence of draw-down within the lake. Both of these observations imply connection of the lake to the aquifer. The Cl record from Carwash was used alongside a core from the Yax Chen cave system to observe spatial and temporal potability of the aquifer. An overall freshening trend in the coastal groundwater occurred throughout the Holocene. The largest amount of this freshening transpired through the Terminal Classic. At this time, populations inland were experiencing deterioration, while coastal populations along the coast continued to survive. Comparing Cl records at various depths and distances from the coast proved that Cl is impacted by proximity to the halocline. / Thesis / Master of Science (MSc)