by Ho Kai Wing Kevin. / Thesis (M.Phil.)--Chinese University of Hong Kong, 1994. / Includes bibliographical references (leaves 94-98). / ABSTRACT --- p.iv / ACKNOWLEDGEMENTS --- p.vi / Chapter CHAPTER ONE: --- INTRODUCTION --- p.1 / Chapter 1.1 --- Basic Co-NMR Theory --- p.1 / Chapter 1.2 --- Method Employed --- p.5 / Chapter 1.2.1 --- Solvent Dependent Studies on Cobalt(III) complexes using 59Co NMR Spectroscopy --- p.5 / Chapter 1.2.2 --- Relationship between δiso and NQCC of Cobalt(III) Complexes in Solid --- p.7 / Chapter 1.3 --- Donor Acceptor Interactions --- p.8 / Chapter 1.4 --- Objectives of this Thesis --- p.10 / Chapter CHAPTER TWO: --- EXPERIMENTAL --- p.11 / Chapter 2.1 --- Synthesis --- p.11 / Chapter 2.2 --- NMR Measurements --- p.13 / Chapter 2.2.1 --- 59Co NMR Measurements --- p.13 / Chapter 2.2.2 --- 13c NMR Measurements (T1 Measurements) --- p.14 / Chapter 2.3 --- Viscosity Measurements --- p.15 / Chapter 2.4 --- UV-Vis Spectral Measurements --- p.15 / Chapter CHAPTER THREE --- 59Co NMR STUDY OF MAGNETIC COBALT(III) COMPLEXES --- p.16 / Chapter 3.1 --- Solvent-Dependent Studies of Cobalt(III) Complexes --- p.16 / Chapter 3.1.1 --- "Study of [Co(en)3]Cl3 and cis, trans-[Co(en)2(N3)2]NO3" --- p.17 / Chapter 3.1.2 --- Study of trans- [Co(en)2(NH3)2]Cl3 and trans- [Co(en)2(N02)2]NO3 --- p.29 / Chapter 3.1.3 --- "Study of trans- Na[Co(acac)2 (N02)2],trans- [Co(acac)2(N02)(NH3)] and trans-[Co(acac)2(NH3)2]I" --- p.36 / Chapter 3.1.4 --- Summary --- p.48 / Chapter 3.2 --- "Simultaneous Determination of CSA, ic, and NQCC of Cobalt(III) complexes in Different Solvents" --- p.49 / Chapter 3.2.1 --- Method --- p.49 / Chapter 3.2.2 --- "Study of trans- Na[Co(acac)2(N02)2],trans- [Co(acac)2(N02)(NH3)] and trans-[Co(acac)2(NH3)2]I and trans-[Co(acac)2(MeNH2)2]I" --- p.52 / Chapter 3.2.3 --- Study of trans- [Co(en)2(N〇2)2]N03 and trans- [Co(en)2(NCS)2]NCS --- p.58 / Chapter 3.2.4 --- Study of trans- [Co(en)2(NH3)2]Cl3 and trans- [Co(en)2(N3)2]NO3 --- p.63 / Chapter 3.2.5 --- Summary --- p.68 / Chapter 3.3 --- Resolution of the d-d Electronic Transition Energies in Cobalt Complexes and its Application to the Donor-Acceptor Interactionsin Cobalt Complexes - Application of Equation 3.3.1 --- p.70 / Chapter 3.3.1 --- Method --- p.70 / Chapter 3.3.2 --- "Study of trans- [Co(en)2(N02)2]N03,trans- [Co(en)2(NCS)2]NCS, trans- [Co(en)2(N3)2]N03 and trans- [Co(en)2(NH3)2]Cl3" --- p.72 / Chapter 3.3.3 --- "Study of trans- Na[Co(acac)2(NO2)2],trans- [Co(acac)2(N02)(NH3)] and trans-[Co(acac)2(NH3)2]I" --- p.86 / Chapter CHAPTER FOUR --- CONCLUSION AND FUTURE WORKS --- p.92 / REFERENCES --- p.94

by Zhou ping. / Thesis (Ph.D.)--Chinese University of Hong Kong, 1997. / Includes bibliographical references (p. 160-170). / Electronic reproduction. Hong Kong : Chinese University of Hong Kong, [2012] System requirements: Adobe Acrobat Reader. Available via World Wide Web. / Mode of access: World Wide Web.