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Spectroscopic and theoretical studies of charge-transfer complexes.Larkindale, John Peter January 1971 (has links)
No description available.
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Spectroscopic and theoretical studies of charge-transfer complexes.Larkindale, John Peter January 1971 (has links)
No description available.
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Syntheses and luminescence studies of di- and polynuclear gold(1) and copper(1) complexes, design strategies towards metalloreceptors andmixed-metal complexes張啓亮, Cheung, Kai-leung. January 2001 (has links)
published_or_final_version / Chemistry / Doctoral / Doctor of Philosophy
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The chemistry of para-tolylimidovanadium V trichloride: synthesis and characterization of dialkyldithiocarbamate and related derivatives and of bis(organophosphine)vanadium IV complexesWheeler, Dale E. January 1986 (has links)
Call number: LD2668 .T4 1986 W43 / Master of Science / Chemistry
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Resonance Raman studies of selected DI-, TRI- and tetra(isocyano) rhenium(i) diimine complexesCheng, Shun-cheung, 鄭信祥 January 2014 (has links)
published_or_final_version / Chemistry / Doctoral / Doctor of Philosophy
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Electrochemical and structural studies of one-dimensional copper charge transfer complexes.Pyrka, Gloria Jean. January 1988 (has links)
The electrochemistry of solid electrodes of charge transfer complexes of tetracyanoquinodimethane (TCNQ) and copper complexes with nitrogen containing chelates, such and dipyridylamine (dpaH), bipyridyl (bpy) and 1,10-dimethyl-2,9-phenanthroline (dmp), has been investigated with cyclic voltammetry. Pressed pellet electrodes of these complexes exhibit a broad electrochemically stable region. The oxidative and reductive breakdown reactions involve solid state reactions into the bulk electrode. These materials also act as electron mediators for glucose oxidation in glucose oxidase modified electrodes. The structure of the model compound, copper(I)(dpaH)₂Cl has been determined to have a distorted tetrahedral coordination sphere. The electrochemistry of solid electrodes of charge transfer complexes of tetrathiafulvalene (TTF) with copper chloride and copper bromide has been investigated with cyclic voltammetry. Pressed pellet electrodes do not exhibit a broad stable region, as do the TCNQ complexes. A preliminary structure of the organic part of tetramethyltetraselenafulvalene copper chloride has been determined from the solution of the Patterson function and exhibits a displacive modulation with a repeat unit of seven TMTSF molecules. (TTF)(SCN)₀ͺ₆₆ and (TTF)Cu(SCN)₂ have been investigated by infrared spectroscopy, X-ray photoelectron spectroscopy, and X-ray diffraction. (TTF)(SCN)₀ͺ₆₆ crystallized in a tetragonal space group with a disordered column of thiocyanate anions. (TTF)Cu(SCN)₂ is an insulator with a two-dimensional network of Cu(SCN)₂⁻ ions. X-ray crystal structures of four compounds prepared in association with copper complex chemistry have been determined; (1) 5,5'-dibromo-2,2'-bithiophene, (2) 3,5,5'-tribromo-2,2'-bithiophene, (3) Cu(dmp)(CN)₂ ⁻ · Bu₄N⁺ and (4) the 1:2 adduct of dimercaptosuccinic acid and dimethylformamide.
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